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Enhancement of ultraviolet upconversion in Yb3+ and Tm3+ codoped amorphous fluoride film prepared by pulsed laser deposition

Identifieur interne : 001B92 ( Main/Curation ); précédent : 001B91; suivant : 001B93

Enhancement of ultraviolet upconversion in Yb3+ and Tm3+ codoped amorphous fluoride film prepared by pulsed laser deposition

Auteurs : Guanshi Qin [République populaire de Chine] ; Weiping Qin ; Changfeng Wu ; Shihua Huang ; Jisen Zhang ; Shaozhe Lu ; Dan Zhao ; Huangqing Liu

Source :

RBID : Pascal:03-0162931

Descripteurs français

English descriptors

Abstract

Zn0.3Al0.25Pb0.3Li0.098Yb0.1Tm0.002F2.354 amorphous fluoride film was prepared by pulsed laser deposition. Ultraviolet and blue up-conversion emissions were observed under infrared excitation at 978 nm. In comparison with the upconversion of the target, the ultraviolet emissions are enhanced greatly. The enhancement is attributed to a decrease of the Judd-Ofelt parameter Ω2 induced by pulsed laser deposition, which precludes the transition rate from 3F2 to 3F4 and enhances the energy transfer process and populates the 1D2 level: 3F23H6(Tm3+):3H41D2(Tm3+). © 2003 American Institute of Physics.

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Pascal:03-0162931

Le document en format XML

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<title xml:lang="en" level="a">Enhancement of ultraviolet upconversion in Yb
<sup>3+</sup>
and Tm
<sup>3+</sup>
codoped amorphous fluoride film prepared by pulsed laser deposition</title>
<author>
<name sortKey="Qin, Guanshi" sort="Qin, Guanshi" uniqKey="Qin G" first="Guanshi" last="Qin">Guanshi Qin</name>
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<s1>Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130021, China</s1>
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<country xml:lang="fr">République populaire de Chine</country>
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<name sortKey="Huang, Shihua" sort="Huang, Shihua" uniqKey="Huang S" first="Shihua" last="Huang">Shihua Huang</name>
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<name sortKey="Zhang, Jisen" sort="Zhang, Jisen" uniqKey="Zhang J" first="Jisen" last="Zhang">Jisen Zhang</name>
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<name sortKey="Lu, Shaozhe" sort="Lu, Shaozhe" uniqKey="Lu S" first="Shaozhe" last="Lu">Shaozhe Lu</name>
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<name sortKey="Zhao, Dan" sort="Zhao, Dan" uniqKey="Zhao D" first="Dan" last="Zhao">Dan Zhao</name>
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<title xml:lang="en" level="a">Enhancement of ultraviolet upconversion in Yb
<sup>3+</sup>
and Tm
<sup>3+</sup>
codoped amorphous fluoride film prepared by pulsed laser deposition</title>
<author>
<name sortKey="Qin, Guanshi" sort="Qin, Guanshi" uniqKey="Qin G" first="Guanshi" last="Qin">Guanshi Qin</name>
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<s1>Key Laboratory of Excited State Processes, Chinese Academy of Sciences, Changchun 130021, China</s1>
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<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea>Key Laboratory of Excited State Processes, Chinese Academy of Sciences, Changchun 130021</wicri:regionArea>
<placeName>
<settlement type="city">Changchun</settlement>
<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
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</affiliation>
<affiliation wicri:level="1">
<inist:fA14 i1="02">
<s1>Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130021, China</s1>
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<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea>Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130021</wicri:regionArea>
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<settlement type="city">Changchun</settlement>
<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
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</author>
<author>
<name sortKey="Qin, Weiping" sort="Qin, Weiping" uniqKey="Qin W" first="Weiping" last="Qin">Weiping Qin</name>
</author>
<author>
<name sortKey="Wu, Changfeng" sort="Wu, Changfeng" uniqKey="Wu C" first="Changfeng" last="Wu">Changfeng Wu</name>
</author>
<author>
<name sortKey="Huang, Shihua" sort="Huang, Shihua" uniqKey="Huang S" first="Shihua" last="Huang">Shihua Huang</name>
</author>
<author>
<name sortKey="Zhang, Jisen" sort="Zhang, Jisen" uniqKey="Zhang J" first="Jisen" last="Zhang">Jisen Zhang</name>
</author>
<author>
<name sortKey="Lu, Shaozhe" sort="Lu, Shaozhe" uniqKey="Lu S" first="Shaozhe" last="Lu">Shaozhe Lu</name>
</author>
<author>
<name sortKey="Zhao, Dan" sort="Zhao, Dan" uniqKey="Zhao D" first="Dan" last="Zhao">Dan Zhao</name>
</author>
<author>
<name sortKey="Liu, Huangqing" sort="Liu, Huangqing" uniqKey="Liu H" first="Huangqing" last="Liu">Huangqing Liu</name>
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<title level="j" type="main">Journal of applied physics</title>
<title level="j" type="abbreviated">J. appl. phys.</title>
<idno type="ISSN">0021-8979</idno>
<imprint>
<date when="2003-04-01">2003-04-01</date>
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<title level="j" type="main">Journal of applied physics</title>
<title level="j" type="abbreviated">J. appl. phys.</title>
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<keywords scheme="KwdEn" xml:lang="en">
<term>Aluminium compounds</term>
<term>Amorphous state</term>
<term>Experimental study</term>
<term>Fluorescence</term>
<term>Impurity states</term>
<term>Judd-Ofelt theory</term>
<term>Lead compounds</term>
<term>Lithium compounds</term>
<term>Optical films</term>
<term>Optical wavelength conversion</term>
<term>Photoluminescence</term>
<term>Thin films</term>
<term>Thulium</term>
<term>Ytterbium</term>
<term>Zinc compounds</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>7855H</term>
<term>7866N</term>
<term>7155H</term>
<term>7860</term>
<term>4265K</term>
<term>6143E</term>
<term>6855</term>
<term>4279W</term>
<term>Etude expérimentale</term>
<term>Zinc composé</term>
<term>Aluminium composé</term>
<term>Plomb composé</term>
<term>Lithium composé</term>
<term>Ytterbium</term>
<term>Thulium</term>
<term>Fluorescence</term>
<term>Photoluminescence</term>
<term>Etat impureté</term>
<term>Conversion longueur onde optique</term>
<term>Etat amorphe</term>
<term>Couche mince</term>
<term>Film optique</term>
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<front>
<div type="abstract" xml:lang="en">Zn
<sub>0.3</sub>
Al
<sub>0.25</sub>
Pb
<sub>0.3</sub>
Li
<sub>0.098</sub>
Yb
<sub>0.1</sub>
Tm
<sub>0.002</sub>
F
<sub>2.354</sub>
amorphous fluoride film was prepared by pulsed laser deposition. Ultraviolet and blue up-conversion emissions were observed under infrared excitation at 978 nm. In comparison with the upconversion of the target, the ultraviolet emissions are enhanced greatly. The enhancement is attributed to a decrease of the Judd-Ofelt parameter Ω
<sub>2</sub>
induced by pulsed laser deposition, which precludes the transition rate from
<sup>3</sup>
F
<sub>2</sub>
to
<sup>3</sup>
F
<sub>4</sub>
and enhances the energy transfer process and populates the
<sup>1</sup>
D
<sub>2</sub>
level:
<sup>3</sup>
F
<sub>2</sub>
<sup>3</sup>
H
<sub>6</sub>
(Tm
<sup>3+</sup>
):
<sup>3</sup>
H
<sub>4</sub>
<sup>1</sup>
D
<sub>2</sub>
(Tm
<sup>3+</sup>
). © 2003 American Institute of Physics.</div>
</front>
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