Energy Transition between Yb3+-Tm3+-Gd3+ in Gd3+, Yb3+and Tm3+ Co-doped Fluoride Nanocrystals
Identifieur interne : 000B65 ( Main/Curation ); précédent : 000B64; suivant : 000B66Energy Transition between Yb3+-Tm3+-Gd3+ in Gd3+, Yb3+and Tm3+ Co-doped Fluoride Nanocrystals
Auteurs : JISEN ZHANG [République populaire de Chine] ; CHUNYAN CAO [République populaire de Chine] ; SHAOZHE LU [République populaire de Chine] ; Wei-Ping Qin [République populaire de Chine]Source :
- Journal of luminescence [ 0022-2313 ] ; 2011.
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- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
YF3: 20%Gd3+, 20%Yb3+, 0.5%TM3+ nanocrystal has been synthesized by a hydrothermal method. The upconversion (UC) emission and energy transfer progresses between Gd3+-Yb3+-Tm3+ under a 980-nm continuous wave semiconductor laser diode excitation have been explored. The experimental results show that the violet and ultraviolet (UV) enhancement with Tm3+ upconversion emission occurs in the nanocrystal, and in the same time the UC emissions of Gd3+ from 6D9/2, 6IJ, 6P5/2, and 6P7/2 states to the ground state 8S7/2 are obtained, too. The dynamic analysis implies that, under 980-nm excitation, the nanocrystal dimension plays a key role in the efficient energy transfer processes between Gd3+-Yb3+-Tm3u based on the energy matching conditions.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Energy Transition between Yb<sup>3+</sup>
-Tm<sup>3+</sup>
-Gd<sup>3+</sup>
in Gd<sup>3+</sup>
, Yb<sup>3+</sup>
and Tm<sup>3+</sup>
Co-doped Fluoride Nanocrystals</title>
<author><name sortKey="Jisen Zhang" sort="Jisen Zhang" uniqKey="Jisen Zhang" last="Jisen Zhang">JISEN ZHANG</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Changchun Institute of Optics. Fine Mechanics and Physics, Chinese Academy of Sciences 3888 gnanhu Road</s1>
<s2>Changchun 130033</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<placeName><settlement type="city">Changchun</settlement>
<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
</placeName>
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<author><name sortKey="Chunyan Cao" sort="Chunyan Cao" uniqKey="Chunyan Cao" last="Chunyan Cao">CHUNYAN CAO</name>
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<s2>Changchun 130033</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
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<country>République populaire de Chine</country>
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<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
</placeName>
</affiliation>
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<author><name sortKey="Shaozhe Lu" sort="Shaozhe Lu" uniqKey="Shaozhe Lu" last="Shaozhe Lu">SHAOZHE LU</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Changchun Institute of Optics. Fine Mechanics and Physics, Chinese Academy of Sciences 3888 gnanhu Road</s1>
<s2>Changchun 130033</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>République populaire de Chine</country>
<placeName><settlement type="city">Changchun</settlement>
<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Qin, Wei Ping" sort="Qin, Wei Ping" uniqKey="Qin W" first="Wei-Ping" last="Qin">Wei-Ping Qin</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering of Jilin University 2699 qianjin Street</s1>
<s2>Changchun 130012</s2>
<s3>CHN</s3>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<placeName><settlement type="city">Changchun</settlement>
<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Energy Transition between Yb<sup>3+</sup>
-Tm<sup>3+</sup>
-Gd<sup>3+</sup>
in Gd<sup>3+</sup>
, Yb<sup>3+</sup>
and Tm<sup>3+</sup>
Co-doped Fluoride Nanocrystals</title>
<author><name sortKey="Jisen Zhang" sort="Jisen Zhang" uniqKey="Jisen Zhang" last="Jisen Zhang">JISEN ZHANG</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Changchun Institute of Optics. Fine Mechanics and Physics, Chinese Academy of Sciences 3888 gnanhu Road</s1>
<s2>Changchun 130033</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<placeName><settlement type="city">Changchun</settlement>
<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Chunyan Cao" sort="Chunyan Cao" uniqKey="Chunyan Cao" last="Chunyan Cao">CHUNYAN CAO</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Changchun Institute of Optics. Fine Mechanics and Physics, Chinese Academy of Sciences 3888 gnanhu Road</s1>
<s2>Changchun 130033</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<placeName><settlement type="city">Changchun</settlement>
<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Shaozhe Lu" sort="Shaozhe Lu" uniqKey="Shaozhe Lu" last="Shaozhe Lu">SHAOZHE LU</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Changchun Institute of Optics. Fine Mechanics and Physics, Chinese Academy of Sciences 3888 gnanhu Road</s1>
<s2>Changchun 130033</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<placeName><settlement type="city">Changchun</settlement>
<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Qin, Wei Ping" sort="Qin, Wei Ping" uniqKey="Qin W" first="Wei-Ping" last="Qin">Wei-Ping Qin</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering of Jilin University 2699 qianjin Street</s1>
<s2>Changchun 130012</s2>
<s3>CHN</s3>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<placeName><settlement type="city">Changchun</settlement>
<region type="province">Jilin</region>
<region type="groupement">Dongbei</region>
</placeName>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Journal of luminescence</title>
<title level="j" type="abbreviated">J. lumin.</title>
<idno type="ISSN">0022-2313</idno>
<imprint><date when="2011">2011</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Journal of luminescence</title>
<title level="j" type="abbreviated">J. lumin.</title>
<idno type="ISSN">0022-2313</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Binary compounds</term>
<term>Codoping</term>
<term>Doped materials</term>
<term>Excitation energy transfer</term>
<term>Gadolinium additions</term>
<term>Hydrothermal growth</term>
<term>Nanocrystal</term>
<term>Nanostructured materials</term>
<term>Optical frequency conversion</term>
<term>Semiconductor materials</term>
<term>Thulium additions</term>
<term>Upconversion</term>
<term>Ytterbium additions</term>
<term>Yttrium fluoride</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Conversion fréquence optique</term>
<term>Transfert énergie excitation</term>
<term>Méthode hydrothermale</term>
<term>Nanocristal</term>
<term>Matériau dopé</term>
<term>Nanomatériau</term>
<term>Codopage</term>
<term>Addition gadolinium</term>
<term>Fluorure d'yttrium</term>
<term>Composé binaire</term>
<term>Semiconducteur</term>
<term>Addition ytterbium</term>
<term>Addition thulium</term>
<term>YF3</term>
<term>8107B</term>
<term>Upconversion</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">YF<sub>3</sub>
: 20%Gd<sup>3+</sup>
, 20%Yb<sup>3+</sup>
, 0.5%TM<sup>3+</sup>
nanocrystal has been synthesized by a hydrothermal method. The upconversion (UC) emission and energy transfer progresses between Gd<sup>3+</sup>
-Yb<sup>3+</sup>
-Tm<sup>3+</sup>
under a 980-nm continuous wave semiconductor laser diode excitation have been explored. The experimental results show that the violet and ultraviolet (UV) enhancement with Tm<sup>3+</sup>
upconversion emission occurs in the nanocrystal, and in the same time the UC emissions of Gd<sup>3+</sup>
from <sup>6</sup>
D<sub>9/2</sub>
, <sup>6</sup>
I<sub>J</sub>
, <sup>6</sup>
P<sub>5/2</sub>
, and <sup>6</sup>
P<sub>7/2</sub>
states to the ground state <sup>8</sup>
S<sub>7/2</sub>
are obtained, too. The dynamic analysis implies that, under 980-nm excitation, the nanocrystal dimension plays a key role in the efficient energy transfer processes between Gd<sup>3+</sup>
-Yb<sup>3+</sup>
-Tm<sup>3u</sup>
based on the energy matching conditions.</div>
</front>
</TEI>
</record>
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