Synthesis, crystal structure and magnetic properties of Tm8S11
Identifieur interne : 003469 ( Istex/Curation ); précédent : 003468; suivant : 003470Synthesis, crystal structure and magnetic properties of Tm8S11
Auteurs : Y. Zhang [États-Unis] ; H. F. Franzen [États-Unis] ; B. Harbrecht [Allemagne]Source :
- Journal of The Less-Common Metals [ 0022-5088 ] ; 1990.
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Abstract
Abstract: The title compound was prepared by high temperature techniques. An X-ray diffraction study of a single crystal has identified a new structure type with composition Tm8S11, space group Cmcm; Z = 4;a = 3.7486(4), b = 12.6160(8), c = 34.932(3) Å. The coordination for Tm atoms is distorted octahedra, distorted trigonal prisms or capped trigonal prisms. These types of coordination are quite common for rare-earth chalcogenides. The magnetic susceptibility measurements show that all Tm atoms in Tm8S11 have a valence of +3 and there are eight delocalized electrons per cell.
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DOI: 10.1016/0022-5088(90)90373-R
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<term>Crystal data</term>
<term>Magnetic susceptibilities</term>
<term>Prism</term>
<term>Space group cmcm</term>
<term>Structure determination</term>
<term>Structure type</term>
<term>Sulfur atoms</term>
<term>Susceptibility</term>
<term>Temperature dependence</term>
<term>Thermal parameters</term>
<term>Thulium</term>
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<term>Trigonal prisms</term>
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<front><div type="abstract" xml:lang="en">Abstract: The title compound was prepared by high temperature techniques. An X-ray diffraction study of a single crystal has identified a new structure type with composition Tm8S11, space group Cmcm; Z = 4;a = 3.7486(4), b = 12.6160(8), c = 34.932(3) Å. The coordination for Tm atoms is distorted octahedra, distorted trigonal prisms or capped trigonal prisms. These types of coordination are quite common for rare-earth chalcogenides. The magnetic susceptibility measurements show that all Tm atoms in Tm8S11 have a valence of +3 and there are eight delocalized electrons per cell.</div>
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