ThuliumV1, Istex, Curation, bibRecord, 003375

Encapsulation of Erbium(III) and Thulium(III) Nanocomplexes Containing 18- and 20-Membered Dioxa Tetraaza Macryclic Ligands Within the Framework of Zeolite

Identifieur interne : 003375 ( Istex/Curation ); précédent : 003374; suivant : 003376

Encapsulation of Erbium(III) and Thulium(III) Nanocomplexes Containing 18- and 20-Membered Dioxa Tetraaza Macryclic Ligands Within the Framework of Zeolite

Auteurs : Mohammad Yousefi [Iran] ; Masoud Salavati-Niasari [Iran]

Source :

High Temperature Materials and Processes [ 0334-6455 ] ; 2012-12-14.

RBID : ISTEX:EB160C903205AA442D7FEC3E0DE3E36954D88189

Descripteurs français

Wicri :
- topic : éthanol, Méthanol.

English descriptors

Abstract

Zeolite framework stabilized erbium(III) and thulium(III) complex nanoparticles was prepared for the first time by using a two step procedure: the ion exchange of Ln3+ (Ln: Er and Tm) with the extra framework Na+ ions in zeolite-Y, the template synthesis of 2,6-diformyl-4-methylphenol with different diamines. Analysis of the data indicated that the Ln(III) complexes has been encapsulated within the nanocavity of zeolite Y and exhibit different property from those of the free complexes, which can arise from distortions caused by steric effects due to the presence of sodium cations, or from interactions with the zeolite matrix.

Url:

https://api.istex.fr/document/EB160C903205AA442D7FEC3E0DE3E36954D88189/fulltext/pdf

DOI: 10.1515/htmp-2012-0001

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Le document en format XML

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<author><name sortKey="Yousefi, Mohammad" sort="Yousefi, Mohammad" uniqKey="Yousefi M" first="Mohammad" last="Yousefi">Mohammad Yousefi</name>
<affiliation wicri:level="1"><mods:affiliation>Islamic Azad university, Shahre Rey Branch, Tehran, Islamic Republic of Iran</mods:affiliation>
<country xml:lang="fr">Iran</country>
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<author><name sortKey="Salavati Niasari, Masoud" sort="Salavati Niasari, Masoud" uniqKey="Salavati Niasari M" first="Masoud" last="Salavati-Niasari">Masoud Salavati-Niasari</name>
<affiliation wicri:level="1"><mods:affiliation>Institute of Nano Science and Nano Technology, University of Kashan, Kashan, I.R. Iran</mods:affiliation>
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<author><name sortKey="Yousefi, Mohammad" sort="Yousefi, Mohammad" uniqKey="Yousefi M" first="Mohammad" last="Yousefi">Mohammad Yousefi</name>
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<author><name sortKey="Salavati Niasari, Masoud" sort="Salavati Niasari, Masoud" uniqKey="Salavati Niasari M" first="Masoud" last="Salavati-Niasari">Masoud Salavati-Niasari</name>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Absolute ethanol</term>
<term>Analytical data</term>
<term>Cation</term>
<term>Chem</term>
<term>Complex nanoparticles</term>
<term>Dehydration temperature</term>
<term>Diamine</term>
<term>Dioxa</term>
<term>Direct titration</term>
<term>Elemental analysis</term>
<term>Encapsulated</term>
<term>Encapsulation</term>
<term>Ethanol</term>
<term>External surface</term>
<term>Ionic radii</term>
<term>Islamic azad university</term>
<term>Lanthanide</term>
<term>Lanthanide complexes</term>
<term>Lanthanide contents</term>
<term>Ligand</term>
<term>Lnl1</term>
<term>Macrocyclic</term>
<term>Macrocyclic schiff base</term>
<term>Magnetic stirrer</term>
<term>Metal ions</term>
<term>Methanol</term>
<term>Molar conductivities</term>
<term>Molar ratio</term>
<term>Monolayer equivalent area</term>
<term>Nano science</term>
<term>Nano technology</term>
<term>Nanoparticles</term>
<term>Nanoparticles encapsulated</term>
<term>Neat complexes</term>
<term>Oxygen donors</term>
<term>Perchlorate</term>
<term>Perchlorate anions</term>
<term>Pore volume</term>
<term>Relative intensities</term>
<term>Room temperature</term>
<term>Schiff</term>
<term>Small cations</term>
<term>Surface area</term>
<term>Template synthesis</term>
<term>Tetraaza</term>
<term>Tetraaza dioxa macrocyclic</term>
<term>Tetraaza dioxa macrocyclic complexes</term>
<term>Transition metal complexes</term>
<term>Unit cell formula</term>
<term>Zeolite</term>
<term>Zeolite framework</term>
<term>Zeolite matrix</term>
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<term>Analytical data</term>
<term>Cation</term>
<term>Chem</term>
<term>Complex nanoparticles</term>
<term>Dehydration temperature</term>
<term>Diamine</term>
<term>Dioxa</term>
<term>Direct titration</term>
<term>Elemental analysis</term>
<term>Encapsulated</term>
<term>Encapsulation</term>
<term>Ethanol</term>
<term>External surface</term>
<term>Ionic radii</term>
<term>Islamic azad university</term>
<term>Lanthanide</term>
<term>Lanthanide complexes</term>
<term>Lanthanide contents</term>
<term>Ligand</term>
<term>Lnl1</term>
<term>Macrocyclic</term>
<term>Macrocyclic schiff base</term>
<term>Magnetic stirrer</term>
<term>Metal ions</term>
<term>Methanol</term>
<term>Molar conductivities</term>
<term>Molar ratio</term>
<term>Monolayer equivalent area</term>
<term>Nano science</term>
<term>Nano technology</term>
<term>Nanoparticles</term>
<term>Nanoparticles encapsulated</term>
<term>Neat complexes</term>
<term>Oxygen donors</term>
<term>Perchlorate</term>
<term>Perchlorate anions</term>
<term>Pore volume</term>
<term>Relative intensities</term>
<term>Room temperature</term>
<term>Schiff</term>
<term>Small cations</term>
<term>Surface area</term>
<term>Template synthesis</term>
<term>Tetraaza</term>
<term>Tetraaza dioxa macrocyclic</term>
<term>Tetraaza dioxa macrocyclic complexes</term>
<term>Transition metal complexes</term>
<term>Unit cell formula</term>
<term>Zeolite</term>
<term>Zeolite framework</term>
<term>Zeolite matrix</term>
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<term>Méthanol</term>
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<front><div type="abstract" xml:lang="en">Zeolite framework stabilized erbium(III) and thulium(III) complex nanoparticles was prepared for the first time by using a two step procedure: the ion exchange of Ln3+ (Ln: Er and Tm) with the extra framework Na+ ions in zeolite-Y, the template synthesis of 2,6-diformyl-4-methylphenol with different diamines. Analysis of the data indicated that the Ln(III) complexes has been encapsulated within the nanocavity of zeolite Y and exhibit different property from those of the free complexes, which can arise from distortions caused by steric effects due to the presence of sodium cations, or from interactions with the zeolite matrix.</div>
</front>
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Encapsulation of Erbium(III) and Thulium(III) Nanocomplexes Containing 18- and 20-Membered Dioxa Tetraaza Macryclic Ligands Within the Framework of Zeolite

Encapsulation of Erbium(III) and Thulium(III) Nanocomplexes Containing 18- and 20-Membered Dioxa Tetraaza Macryclic Ligands Within the Framework of Zeolite

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri