The Aldol Reaction of Silyl Enol Ethers with Aldehydes in Aqueous Media
Identifieur interne : 002958 ( Istex/Curation ); précédent : 002957; suivant : 002959The Aldol Reaction of Silyl Enol Ethers with Aldehydes in Aqueous Media
Auteurs : Sh Kobayashi [Japon] ; Iwao Hachiya [Japon]Source :
- Tetrahedron Letters [ 0040-4039 ] ; 1992.
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Abstract
Abstract: The aldol reaction of silyl enol ethers with aldehydes is successfully carried out in aqueous media by using a lanthanide trifluoromethanesulfonate as a catalyst. Water soluble aldehydes are applicable and the catalyst can be recovered and reused in this reaction.
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DOI: 10.1016/S0040-4039(00)91691-5
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<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title>The Aldol Reaction of Silyl Enol Ethers with Aldehydes in Aqueous Media</title><author><name sortKey="Kobayashi, Sh" sort="Kobayashi, Sh" uniqKey="Kobayashi S" first="Sh" last="Kobayashi">Sh Kobayashi</name><affiliation wicri:level="1"><mods:affiliation>Department of Applied Chemistry, Faculty of Science, Science University of Tokyo (SUT), Kagurazaka, Shinjuku-ku, Tokyo 162 Japan</mods:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Applied Chemistry, Faculty of Science, Science University of Tokyo (SUT), Kagurazaka, Shinjuku-ku</wicri:regionArea></affiliation></author><author><name sortKey="Hachiya, Iwao" sort="Hachiya, Iwao" uniqKey="Hachiya I" first="Iwao" last="Hachiya">Iwao Hachiya</name><affiliation wicri:level="1"><mods:affiliation>Department of Applied Chemistry, Faculty of Science, Science University of Tokyo (SUT), Kagurazaka, Shinjuku-ku, Tokyo 162 Japan</mods:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Applied Chemistry, Faculty of Science, Science University of Tokyo (SUT), Kagurazaka, Shinjuku-ku</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:BB9F10F2FA11ED1BF94FD0489EFD0733B5599899</idno><date when="1992" year="1992">1992</date><idno type="doi">10.1016/S0040-4039(00)91691-5</idno><idno type="url">https://api.istex.fr/document/BB9F10F2FA11ED1BF94FD0489EFD0733B5599899/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">002958</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">002958</idno><idno type="wicri:Area/Istex/Curation">002958</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a">The Aldol Reaction of Silyl Enol Ethers with Aldehydes in Aqueous Media</title><author><name sortKey="Kobayashi, Sh" sort="Kobayashi, Sh" uniqKey="Kobayashi S" first="Sh" last="Kobayashi">Sh Kobayashi</name><affiliation wicri:level="1"><mods:affiliation>Department of Applied Chemistry, Faculty of Science, Science University of Tokyo (SUT), Kagurazaka, Shinjuku-ku, Tokyo 162 Japan</mods:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Applied Chemistry, Faculty of Science, Science University of Tokyo (SUT), Kagurazaka, Shinjuku-ku</wicri:regionArea></affiliation></author><author><name sortKey="Hachiya, Iwao" sort="Hachiya, Iwao" uniqKey="Hachiya I" first="Iwao" last="Hachiya">Iwao Hachiya</name><affiliation wicri:level="1"><mods:affiliation>Department of Applied Chemistry, Faculty of Science, Science University of Tokyo (SUT), Kagurazaka, Shinjuku-ku, Tokyo 162 Japan</mods:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Applied Chemistry, Faculty of Science, Science University of Tokyo (SUT), Kagurazaka, Shinjuku-ku</wicri:regionArea></affiliation></author></analytic><monogr></monogr><series><title level="j">Tetrahedron Letters</title><title level="j" type="abbrev">TETL</title><idno type="ISSN">0040-4039</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1992">1992</date><biblScope unit="volume">33</biblScope><biblScope unit="issue">12</biblScope><biblScope unit="page" from="1625">1625</biblScope><biblScope unit="page" to="1628">1628</biblScope></imprint><idno type="ISSN">0040-4039</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0040-4039</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Adduct</term><term>Aldehyde</term><term>Aldol</term><term>Aldol reaction</term><term>Aqueous media</term><term>Chem</term><term>Enol</term><term>Ether</term><term>High yields</term><term>Lanthanide</term><term>Lanthanide triflate</term><term>Lett</term><term>Lewis acids</term><term>Mukaiyama</term><term>Phcho</term><term>Silyl</term><term>Silyl enol ether</term><term>Silyl enol ethers</term><term>Triflate</term><term>Triflates</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Adduct</term><term>Aldehyde</term><term>Aldol</term><term>Aldol reaction</term><term>Aqueous media</term><term>Chem</term><term>Enol</term><term>Ether</term><term>High yields</term><term>Lanthanide</term><term>Lanthanide triflate</term><term>Lett</term><term>Lewis acids</term><term>Mukaiyama</term><term>Phcho</term><term>Silyl</term><term>Silyl enol ether</term><term>Silyl enol ethers</term><term>Triflate</term><term>Triflates</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: The aldol reaction of silyl enol ethers with aldehydes is successfully carried out in aqueous media by using a lanthanide trifluoromethanesulfonate as a catalyst. Water soluble aldehydes are applicable and the catalyst can be recovered and reused in this reaction.</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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