The Aldol Reaction of Silyl Enol Ethers with Aldehydes in Aqueous Media
Identifieur interne : 002958 ( Istex/Curation ); précédent : 002957; suivant : 002959The Aldol Reaction of Silyl Enol Ethers with Aldehydes in Aqueous Media
Auteurs : Sh Kobayashi [Japon] ; Iwao Hachiya [Japon]Source :
- Tetrahedron Letters [ 0040-4039 ] ; 1992.
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Abstract
Abstract: The aldol reaction of silyl enol ethers with aldehydes is successfully carried out in aqueous media by using a lanthanide trifluoromethanesulfonate as a catalyst. Water soluble aldehydes are applicable and the catalyst can be recovered and reused in this reaction.
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DOI: 10.1016/S0040-4039(00)91691-5
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<author><name sortKey="Kobayashi, Sh" sort="Kobayashi, Sh" uniqKey="Kobayashi S" first="Sh" last="Kobayashi">Sh Kobayashi</name>
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<term>Aqueous media</term>
<term>Chem</term>
<term>Enol</term>
<term>Ether</term>
<term>High yields</term>
<term>Lanthanide</term>
<term>Lanthanide triflate</term>
<term>Lett</term>
<term>Lewis acids</term>
<term>Mukaiyama</term>
<term>Phcho</term>
<term>Silyl</term>
<term>Silyl enol ether</term>
<term>Silyl enol ethers</term>
<term>Triflate</term>
<term>Triflates</term>
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<term>Chem</term>
<term>Enol</term>
<term>Ether</term>
<term>High yields</term>
<term>Lanthanide</term>
<term>Lanthanide triflate</term>
<term>Lett</term>
<term>Lewis acids</term>
<term>Mukaiyama</term>
<term>Phcho</term>
<term>Silyl</term>
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<front><div type="abstract" xml:lang="en">Abstract: The aldol reaction of silyl enol ethers with aldehydes is successfully carried out in aqueous media by using a lanthanide trifluoromethanesulfonate as a catalyst. Water soluble aldehydes are applicable and the catalyst can be recovered and reused in this reaction.</div>
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