The Quantum Chemistry of Unusual Oxidation States of the Lanthanides and Actinides
Identifieur interne : 002324 ( Istex/Curation ); précédent : 002323; suivant : 002325The Quantum Chemistry of Unusual Oxidation States of the Lanthanides and Actinides
Auteurs :Source :
- Russian Chemical Reviews [ 0036-021X ] ; 1984-08-31.
Descripteurs français
- Wicri :
- topic : Plutonium.
English descriptors
- KwdEn :
- Absorption spectrum, Acceptor, Acceptor level, Acceptor levels, Actinide, Actinide atoms, Actinide ions, Actinide series, Actinyl, Actinyl ions, Active cations, Americium, Angular coordination, Antibonding, Atomic data, Atomic number, Bivalent, Bivalent state, Californium, Cation, Cationic forms, Central atom, Chemical properties, Configuration, Corresponding lanthanides, Curium, Effective charge, Effective charges, Einsteinium, Electron configuration, Electron configurations, Electron density, Electron density distribution, Electron repulsion, Electronic spectra, Electronic structure, Energy levels, Equatorial, Equatorial bonds, Equatorial plane, Excitation, Excitation energies, Excitation energy, Experimental data, Extremal oxidation states, First half, Fundamental difference, Gradual stabilisation, Ground state, Heavy elements, High value, Higher oxidation states, Highest oxidation states, Holmium, Ion, Ionic radii, Ionic radius, Ionisation, Ionisation energies, Ionisation energy, Isoelectronic, Isoelectronic ions, Journees, Kcal mole, Lanthanide, Lanthanide series, Lanthanyl groups, Ligand, Linear coordination, Lower oxidation states, Molecular orbitals, Neptunium, Nuclear data tables, Octahedral, Octahedral oxyanions, Orbital, Orbital effect, Orbital symmetry, Orbitals, Oxidation number, Oxidation potentials, Oxidation state, Oxidation states, Oxyanions, Oxygen atom, Oxygen atoms, Oxygen compounds, Pergamon press, Periodic system, Plutonium, Possible existence, Present authors, Quantum chemistry, Radiokhimiya, Reaction mechanisms, Regular features, Reiativistic, Reiativistic effect, Relativistic, Relativistic effect, Relativistic effects, Russian chemical reviews, Same direction, Same time, Same type, Second half, Splitting, Sssr, Stabilisation, Symmetry point group, Tervalent, Tervalent state, Total energy, Transition elements, Transuranium elements, Univalent, Univalent state, Unusual oxidation states, Uranyl, Uranyl group, Valence, Valence electrons.
- Teeft :
- Absorption spectrum, Acceptor, Acceptor level, Acceptor levels, Actinide, Actinide atoms, Actinide ions, Actinide series, Actinyl, Actinyl ions, Active cations, Americium, Angular coordination, Antibonding, Atomic data, Atomic number, Bivalent, Bivalent state, Californium, Cation, Cationic forms, Central atom, Chemical properties, Configuration, Corresponding lanthanides, Curium, Effective charge, Effective charges, Einsteinium, Electron configuration, Electron configurations, Electron density, Electron density distribution, Electron repulsion, Electronic spectra, Electronic structure, Energy levels, Equatorial, Equatorial bonds, Equatorial plane, Excitation, Excitation energies, Excitation energy, Experimental data, Extremal oxidation states, First half, Fundamental difference, Gradual stabilisation, Ground state, Heavy elements, High value, Higher oxidation states, Highest oxidation states, Holmium, Ion, Ionic radii, Ionic radius, Ionisation, Ionisation energies, Ionisation energy, Isoelectronic, Isoelectronic ions, Journees, Kcal mole, Lanthanide, Lanthanide series, Lanthanyl groups, Ligand, Linear coordination, Lower oxidation states, Molecular orbitals, Neptunium, Nuclear data tables, Octahedral, Octahedral oxyanions, Orbital, Orbital effect, Orbital symmetry, Orbitals, Oxidation number, Oxidation potentials, Oxidation state, Oxidation states, Oxyanions, Oxygen atom, Oxygen atoms, Oxygen compounds, Pergamon press, Periodic system, Plutonium, Possible existence, Present authors, Quantum chemistry, Radiokhimiya, Reaction mechanisms, Regular features, Reiativistic, Reiativistic effect, Relativistic, Relativistic effect, Relativistic effects, Russian chemical reviews, Same direction, Same time, Same type, Second half, Splitting, Sssr, Stabilisation, Symmetry point group, Tervalent, Tervalent state, Total energy, Transition elements, Transuranium elements, Univalent, Univalent state, Unusual oxidation states, Uranyl, Uranyl group, Valence, Valence electrons.
Url:
DOI: 10.1070/RC1984v053n08ABEH003094
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Absorption spectrum</term>
<term>Acceptor</term>
<term>Acceptor level</term>
<term>Acceptor levels</term>
<term>Actinide</term>
<term>Actinide atoms</term>
<term>Actinide ions</term>
<term>Actinide series</term>
<term>Actinyl</term>
<term>Actinyl ions</term>
<term>Active cations</term>
<term>Americium</term>
<term>Angular coordination</term>
<term>Antibonding</term>
<term>Atomic data</term>
<term>Atomic number</term>
<term>Bivalent</term>
<term>Bivalent state</term>
<term>Californium</term>
<term>Cation</term>
<term>Cationic forms</term>
<term>Central atom</term>
<term>Chemical properties</term>
<term>Configuration</term>
<term>Corresponding lanthanides</term>
<term>Curium</term>
<term>Effective charge</term>
<term>Effective charges</term>
<term>Einsteinium</term>
<term>Electron configuration</term>
<term>Electron configurations</term>
<term>Electron density</term>
<term>Electron density distribution</term>
<term>Electron repulsion</term>
<term>Electronic spectra</term>
<term>Electronic structure</term>
<term>Energy levels</term>
<term>Equatorial</term>
<term>Equatorial bonds</term>
<term>Equatorial plane</term>
<term>Excitation</term>
<term>Excitation energies</term>
<term>Excitation energy</term>
<term>Experimental data</term>
<term>Extremal oxidation states</term>
<term>First half</term>
<term>Fundamental difference</term>
<term>Gradual stabilisation</term>
<term>Ground state</term>
<term>Heavy elements</term>
<term>High value</term>
<term>Higher oxidation states</term>
<term>Highest oxidation states</term>
<term>Holmium</term>
<term>Ion</term>
<term>Ionic radii</term>
<term>Ionic radius</term>
<term>Ionisation</term>
<term>Ionisation energies</term>
<term>Ionisation energy</term>
<term>Isoelectronic</term>
<term>Isoelectronic ions</term>
<term>Journees</term>
<term>Kcal mole</term>
<term>Lanthanide</term>
<term>Lanthanide series</term>
<term>Lanthanyl groups</term>
<term>Ligand</term>
<term>Linear coordination</term>
<term>Lower oxidation states</term>
<term>Molecular orbitals</term>
<term>Neptunium</term>
<term>Nuclear data tables</term>
<term>Octahedral</term>
<term>Octahedral oxyanions</term>
<term>Orbital</term>
<term>Orbital effect</term>
<term>Orbital symmetry</term>
<term>Orbitals</term>
<term>Oxidation number</term>
<term>Oxidation potentials</term>
<term>Oxidation state</term>
<term>Oxidation states</term>
<term>Oxyanions</term>
<term>Oxygen atom</term>
<term>Oxygen atoms</term>
<term>Oxygen compounds</term>
<term>Pergamon press</term>
<term>Periodic system</term>
<term>Plutonium</term>
<term>Possible existence</term>
<term>Present authors</term>
<term>Quantum chemistry</term>
<term>Radiokhimiya</term>
<term>Reaction mechanisms</term>
<term>Regular features</term>
<term>Reiativistic</term>
<term>Reiativistic effect</term>
<term>Relativistic</term>
<term>Relativistic effect</term>
<term>Relativistic effects</term>
<term>Russian chemical reviews</term>
<term>Same direction</term>
<term>Same time</term>
<term>Same type</term>
<term>Second half</term>
<term>Splitting</term>
<term>Sssr</term>
<term>Stabilisation</term>
<term>Symmetry point group</term>
<term>Tervalent</term>
<term>Tervalent state</term>
<term>Total energy</term>
<term>Transition elements</term>
<term>Transuranium elements</term>
<term>Univalent</term>
<term>Univalent state</term>
<term>Unusual oxidation states</term>
<term>Uranyl</term>
<term>Uranyl group</term>
<term>Valence</term>
<term>Valence electrons</term>
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<keywords scheme="Teeft" xml:lang="en"><term>Absorption spectrum</term>
<term>Acceptor</term>
<term>Acceptor level</term>
<term>Acceptor levels</term>
<term>Actinide</term>
<term>Actinide atoms</term>
<term>Actinide ions</term>
<term>Actinide series</term>
<term>Actinyl</term>
<term>Actinyl ions</term>
<term>Active cations</term>
<term>Americium</term>
<term>Angular coordination</term>
<term>Antibonding</term>
<term>Atomic data</term>
<term>Atomic number</term>
<term>Bivalent</term>
<term>Bivalent state</term>
<term>Californium</term>
<term>Cation</term>
<term>Cationic forms</term>
<term>Central atom</term>
<term>Chemical properties</term>
<term>Configuration</term>
<term>Corresponding lanthanides</term>
<term>Curium</term>
<term>Effective charge</term>
<term>Effective charges</term>
<term>Einsteinium</term>
<term>Electron configuration</term>
<term>Electron configurations</term>
<term>Electron density</term>
<term>Electron density distribution</term>
<term>Electron repulsion</term>
<term>Electronic spectra</term>
<term>Electronic structure</term>
<term>Energy levels</term>
<term>Equatorial</term>
<term>Equatorial bonds</term>
<term>Equatorial plane</term>
<term>Excitation</term>
<term>Excitation energies</term>
<term>Excitation energy</term>
<term>Experimental data</term>
<term>Extremal oxidation states</term>
<term>First half</term>
<term>Fundamental difference</term>
<term>Gradual stabilisation</term>
<term>Ground state</term>
<term>Heavy elements</term>
<term>High value</term>
<term>Higher oxidation states</term>
<term>Highest oxidation states</term>
<term>Holmium</term>
<term>Ion</term>
<term>Ionic radii</term>
<term>Ionic radius</term>
<term>Ionisation</term>
<term>Ionisation energies</term>
<term>Ionisation energy</term>
<term>Isoelectronic</term>
<term>Isoelectronic ions</term>
<term>Journees</term>
<term>Kcal mole</term>
<term>Lanthanide</term>
<term>Lanthanide series</term>
<term>Lanthanyl groups</term>
<term>Ligand</term>
<term>Linear coordination</term>
<term>Lower oxidation states</term>
<term>Molecular orbitals</term>
<term>Neptunium</term>
<term>Nuclear data tables</term>
<term>Octahedral</term>
<term>Octahedral oxyanions</term>
<term>Orbital</term>
<term>Orbital effect</term>
<term>Orbital symmetry</term>
<term>Orbitals</term>
<term>Oxidation number</term>
<term>Oxidation potentials</term>
<term>Oxidation state</term>
<term>Oxidation states</term>
<term>Oxyanions</term>
<term>Oxygen atom</term>
<term>Oxygen atoms</term>
<term>Oxygen compounds</term>
<term>Pergamon press</term>
<term>Periodic system</term>
<term>Plutonium</term>
<term>Possible existence</term>
<term>Present authors</term>
<term>Quantum chemistry</term>
<term>Radiokhimiya</term>
<term>Reaction mechanisms</term>
<term>Regular features</term>
<term>Reiativistic</term>
<term>Reiativistic effect</term>
<term>Relativistic</term>
<term>Relativistic effect</term>
<term>Relativistic effects</term>
<term>Russian chemical reviews</term>
<term>Same direction</term>
<term>Same time</term>
<term>Same type</term>
<term>Second half</term>
<term>Splitting</term>
<term>Sssr</term>
<term>Stabilisation</term>
<term>Symmetry point group</term>
<term>Tervalent</term>
<term>Tervalent state</term>
<term>Total energy</term>
<term>Transition elements</term>
<term>Transuranium elements</term>
<term>Univalent</term>
<term>Univalent state</term>
<term>Unusual oxidation states</term>
<term>Uranyl</term>
<term>Uranyl group</term>
<term>Valence</term>
<term>Valence electrons</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Plutonium</term>
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