Absorption spectrum and energy levels of the Pr3+ ion in the low symmetry crystal field of hexahydrate trichloride crystals
Identifieur interne : 001E37 ( Istex/Curation ); précédent : 001E36; suivant : 001E38Absorption spectrum and energy levels of the Pr3+ ion in the low symmetry crystal field of hexahydrate trichloride crystals
Auteurs : B. Sarup [France]Source :
- Spectrochimica Acta Part B: Atomic Spectroscopy [ 0584-8547 ] ; 1968.
English descriptors
- KwdEn :
- Absorption lines, Absorption spectrum, Axial spectrum, Base lines, Chem, Different matrices, Electric vector, Ground state, Ground state components, Host lattice, Hydrated, Magnetic field, Matrix, Opposite polarization, Optical spectra, Praseodymium, Rare earth, Rare earth ions, Site symmetry, Strong lines, Symmetry, Symmetry axis, Symmetry crystal field, Symmetry site, Visible region, Water molecules, Wide band.
- Teeft :
- Absorption lines, Absorption spectrum, Axial spectrum, Base lines, Chem, Different matrices, Electric vector, Ground state, Ground state components, Host lattice, Hydrated, Magnetic field, Matrix, Opposite polarization, Optical spectra, Praseodymium, Rare earth, Rare earth ions, Site symmetry, Strong lines, Symmetry, Symmetry axis, Symmetry crystal field, Symmetry site, Visible region, Water molecules, Wide band.
Abstract
Abstract: The absorption spectrum of Pr3+ ion in diluted, hydrated chloride crystals in the visible region was observed at 77°K and 4.2°K with polarized light and high dispersion. An analysis has been made and crystal quantum numbers assigned to many of the stark levels of 3H4,3P0,1,2, 1I6 and 1D2 states. A comparison is made with the corresponding levels in the anhydrous salts and with the free ion levels. Shielding of the rare earth ion from the surrounding ligands by the water molecules is pointed out.
Url:
DOI: 10.1016/0584-8547(68)80026-6
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ISTEX:88FDFF42695F6E4AFE2BE0F9FB3A0A44F6CC5E24Le document en format XML
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