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Conditions for stability of oxidation states derived from photo‐electron spectra and inductive quantum chemistry

Identifieur interne : 001A53 ( Istex/Curation ); précédent : 001A52; suivant : 001A54

Conditions for stability of oxidation states derived from photo‐electron spectra and inductive quantum chemistry

Auteurs : C. K. J Rgensen [Suisse]

Source :

ZAAC ‐ Journal of Inorganic and General Chemistry [ 0044-2313 ] ; 1986-09.

RBID : ISTEX:76C739F77FD7C1FF2CF621745D8F87B8431BF3E5

English descriptors

Abstract

The 315 oxidation states in non‐metallic, non‐catenated compounds are arranged according to their Kossel number of electrons K in 81 isoelectronic series. The profound differences between the four categories (the 4f, the 5f and the d groups, and the other elements) are analyzed and compared with ionization energies I of loosely bound electrons obtained from photo‐electron spectra, and their slope (dI/dZ). It seems difficult, but not impossible, still to prepare a few new oxidation states. The examples argon(II), copper(IV), silver(V), thulium(IV), mercury(III) and francium(V) are discussed.

Url:

https://api.istex.fr/document/76C739F77FD7C1FF2CF621745D8F87B8431BF3E5/fulltext/pdf

DOI: 10.1002/zaac.19865400912

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Le document en format XML

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<term>Monatomic entities</term>
<term>More acidic</term>
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<term>Other hand</term>
<term>Oxidation numbers</term>
<term>Oxidation state</term>
<term>Oxidation states</term>
<term>Oxide ligands</term>
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<term>Periodisches system</term>
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<term>Rare earths</term>
<term>Same time</term>
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<term>Central atom</term>
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<term>Condensed matter</term>
<term>Conditional oxidation state</term>
<term>Electron affinity</term>
<term>Electron configuration</term>
<term>Electron configurations</term>
<term>Electron transfer</term>
<term>Electron transfer bands</term>
<term>Equal amounts</term>
<term>Fluoride</term>
<term>Fractional charge</term>
<term>Further comments</term>
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<term>Gaseous atoms</term>
<term>Gaseous molecules</term>
<term>Groundstate</term>
<term>High oxidation states</term>
<term>High pressure</term>
<term>Higher oxidation states</term>
<term>Hydroxo complexes</term>
<term>Inorganic compounds</term>
<term>Interesting case</term>
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<term>Ligand field</term>
<term>Main groups</term>
<term>Many compounds</term>
<term>Metallic elements</term>
<term>Monatomic entities</term>
<term>More acidic</term>
<term>Nephelauxetic effect</term>
<term>Other hand</term>
<term>Oxidation numbers</term>
<term>Oxidation state</term>
<term>Oxidation states</term>
<term>Oxide ligands</term>
<term>Periodic table</term>
<term>Periodisches system</term>
<term>Phys</term>
<term>Rare earths</term>
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<front><div type="abstract" xml:lang="en">The 315 oxidation states in non‐metallic, non‐catenated compounds are arranged according to their Kossel number of electrons K in 81 isoelectronic series. The profound differences between the four categories (the 4f, the 5f and the d groups, and the other elements) are analyzed and compared with ionization energies I of loosely bound electrons obtained from photo‐electron spectra, and their slope (dI/dZ). It seems difficult, but not impossible, still to prepare a few new oxidation states. The examples argon(II), copper(IV), silver(V), thulium(IV), mercury(III) and francium(V) are discussed.</div>
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Conditions for stability of oxidation states derived from photo‐electron spectra and inductive quantum chemistry

Conditions for stability of oxidation states derived from photo‐electron spectra and inductive quantum chemistry

Source :

English descriptors

Abstract

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