Experimental and calculated enthalpies of formation of rare earth-tin alloys
Identifieur interne : 001484 ( Istex/Curation ); précédent : 001483; suivant : 001485Experimental and calculated enthalpies of formation of rare earth-tin alloys
Auteurs : C. Colinet ; A. Pasturel ; A. Percheron-Guégan [France] ; J. C. Achard [France]Source :
- Journal of The Less-Common Metals [ 0022-5088 ] ; 1984.
Descripteurs français
- Wicri :
- topic : Alliage.
English descriptors
- KwdEn :
- Alloy, Atomic number, Binary alloys, Calorimetric method, Calorimetry, Concentration range, Dissolution, Earth elements, Ecole nationale, Elemental parameters, Enthalpy, Experimental data, Experimental determinations, Experimental results, Experimental values, Heavy lanthanide metals, Hybridization, Hybridization term, Infinite dilution, Integral heat, Lanthanide, Lanthanide elements, Lanthanide series, Lanthanum, Large groups, Liquid alloys, Lutetium, Metal atom, Metallic radius, Miedema, Partial enthalpies, Partial enthalpy, Partial heat, Rare alloys, Rare compounds, Rare earth, Rare earth element, Rare earth elements, Rare earth metals, Rare earths, Reference states, Same temperature range, Solid alloys, Solid compounds, Solid state, Temperature range, Transition metal, Transition metals, Various compositions.
- Teeft :
- Alloy, Atomic number, Binary alloys, Calorimetric method, Calorimetry, Concentration range, Dissolution, Earth elements, Ecole nationale, Elemental parameters, Enthalpy, Experimental data, Experimental determinations, Experimental results, Experimental values, Heavy lanthanide metals, Hybridization, Hybridization term, Infinite dilution, Integral heat, Lanthanide, Lanthanide elements, Lanthanide series, Lanthanum, Large groups, Liquid alloys, Lutetium, Metal atom, Metallic radius, Miedema, Partial enthalpies, Partial enthalpy, Partial heat, Rare alloys, Rare compounds, Rare earth, Rare earth element, Rare earth elements, Rare earth metals, Rare earths, Reference states, Same temperature range, Solid alloys, Solid compounds, Solid state, Temperature range, Transition metal, Transition metals, Various compositions.
Abstract
Abstract: The partial enthalpies of some rare earth elements (lanthanum, cerium, thulium, lutetium and yttrium) at infinite dilution in liquid tin were determined by means of a calorimetric method. The change in this thermodynamic property with atomic number is discussed in terms of the contribution of the 4f electrons to the bonding. This assumption is used to calculate the hybridization term involved in Miedema's relation. Experimental results therefore allow an accurate determination of the parameters of Miedema's relation. These are used to calculate the enthalpies of formation of rare earth-tin compounds. The predicted values are compared with available experimental data.
Url:
DOI: 10.1016/0022-5088(84)90313-8
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C. Colinet<affiliation><mods:affiliation>Laboratoire de Thermodynamique et Physico-Chimie Métallurgiques, Ecole Nationale Supérieure d'Electrochimie et d'Electrométallurgie de Grenoble, B.P. 75, 38402 Saint Martin d'HèresFrance</mods:affiliation>
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<affiliation><mods:affiliation>Laboratoire de Thermodynamique et Physico-Chimie Métallurgiques, Ecole Nationale Supérieure d'Electrochimie et d'Electrométallurgie de Grenoble, B.P. 75, 38402 Saint Martin d'HèresFrance</mods:affiliation>
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<term>Atomic number</term>
<term>Binary alloys</term>
<term>Calorimetric method</term>
<term>Calorimetry</term>
<term>Concentration range</term>
<term>Dissolution</term>
<term>Earth elements</term>
<term>Ecole nationale</term>
<term>Elemental parameters</term>
<term>Enthalpy</term>
<term>Experimental data</term>
<term>Experimental determinations</term>
<term>Experimental results</term>
<term>Experimental values</term>
<term>Heavy lanthanide metals</term>
<term>Hybridization</term>
<term>Hybridization term</term>
<term>Infinite dilution</term>
<term>Integral heat</term>
<term>Lanthanide</term>
<term>Lanthanide elements</term>
<term>Lanthanide series</term>
<term>Lanthanum</term>
<term>Large groups</term>
<term>Liquid alloys</term>
<term>Lutetium</term>
<term>Metal atom</term>
<term>Metallic radius</term>
<term>Miedema</term>
<term>Partial enthalpies</term>
<term>Partial enthalpy</term>
<term>Partial heat</term>
<term>Rare alloys</term>
<term>Rare compounds</term>
<term>Rare earth</term>
<term>Rare earth element</term>
<term>Rare earth elements</term>
<term>Rare earth metals</term>
<term>Rare earths</term>
<term>Reference states</term>
<term>Same temperature range</term>
<term>Solid alloys</term>
<term>Solid compounds</term>
<term>Solid state</term>
<term>Temperature range</term>
<term>Transition metal</term>
<term>Transition metals</term>
<term>Various compositions</term>
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<term>Binary alloys</term>
<term>Calorimetric method</term>
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<term>Concentration range</term>
<term>Dissolution</term>
<term>Earth elements</term>
<term>Ecole nationale</term>
<term>Elemental parameters</term>
<term>Enthalpy</term>
<term>Experimental data</term>
<term>Experimental determinations</term>
<term>Experimental results</term>
<term>Experimental values</term>
<term>Heavy lanthanide metals</term>
<term>Hybridization</term>
<term>Hybridization term</term>
<term>Infinite dilution</term>
<term>Integral heat</term>
<term>Lanthanide</term>
<term>Lanthanide elements</term>
<term>Lanthanide series</term>
<term>Lanthanum</term>
<term>Large groups</term>
<term>Liquid alloys</term>
<term>Lutetium</term>
<term>Metal atom</term>
<term>Metallic radius</term>
<term>Miedema</term>
<term>Partial enthalpies</term>
<term>Partial enthalpy</term>
<term>Partial heat</term>
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<term>Rare earth elements</term>
<term>Rare earth metals</term>
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<term>Reference states</term>
<term>Same temperature range</term>
<term>Solid alloys</term>
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<front><div type="abstract" xml:lang="en">Abstract: The partial enthalpies of some rare earth elements (lanthanum, cerium, thulium, lutetium and yttrium) at infinite dilution in liquid tin were determined by means of a calorimetric method. The change in this thermodynamic property with atomic number is discussed in terms of the contribution of the 4f electrons to the bonding. This assumption is used to calculate the hybridization term involved in Miedema's relation. Experimental results therefore allow an accurate determination of the parameters of Miedema's relation. These are used to calculate the enthalpies of formation of rare earth-tin compounds. The predicted values are compared with available experimental data.</div>
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