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Experimental and calculated enthalpies of formation of rare earth-tin alloys

Identifieur interne : 001484 ( Istex/Curation ); précédent : 001483; suivant : 001485

Experimental and calculated enthalpies of formation of rare earth-tin alloys

Auteurs : C. Colinet ; A. Pasturel ; A. Percheron-Guégan [France] ; J. C. Achard [France]

Source :

Journal of The Less-Common Metals [ 0022-5088 ] ; 1984.

RBID : ISTEX:5DF743F579B1C4593D8A3EB56FE987A26D28F4FF

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Wicri :
- topic : Alliage.

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Abstract

Abstract: The partial enthalpies of some rare earth elements (lanthanum, cerium, thulium, lutetium and yttrium) at infinite dilution in liquid tin were determined by means of a calorimetric method. The change in this thermodynamic property with atomic number is discussed in terms of the contribution of the 4f electrons to the bonding. This assumption is used to calculate the hybridization term involved in Miedema's relation. Experimental results therefore allow an accurate determination of the parameters of Miedema's relation. These are used to calculate the enthalpies of formation of rare earth-tin compounds. The predicted values are compared with available experimental data.

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DOI: 10.1016/0022-5088(84)90313-8

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C. Colinet

<affiliation><mods:affiliation>Laboratoire de Thermodynamique et Physico-Chimie Métallurgiques, Ecole Nationale Supérieure d'Electrochimie et d'Electrométallurgie de Grenoble, B.P. 75, 38402 Saint Martin d'HèresFrance</mods:affiliation>
<wicri:noCountry code="subField">d'HèresFrance</wicri:noCountry>
</affiliation>

A. Pasturel

<affiliation><mods:affiliation>Laboratoire de Thermodynamique et Physico-Chimie Métallurgiques, Ecole Nationale Supérieure d'Electrochimie et d'Electrométallurgie de Grenoble, B.P. 75, 38402 Saint Martin d'HèresFrance</mods:affiliation>
<wicri:noCountry code="subField">d'HèresFrance</wicri:noCountry>
</affiliation>

Le document en format XML

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<term>Experimental determinations</term>
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<front><div type="abstract" xml:lang="en">Abstract: The partial enthalpies of some rare earth elements (lanthanum, cerium, thulium, lutetium and yttrium) at infinite dilution in liquid tin were determined by means of a calorimetric method. The change in this thermodynamic property with atomic number is discussed in terms of the contribution of the 4f electrons to the bonding. This assumption is used to calculate the hybridization term involved in Miedema's relation. Experimental results therefore allow an accurate determination of the parameters of Miedema's relation. These are used to calculate the enthalpies of formation of rare earth-tin compounds. The predicted values are compared with available experimental data.</div>
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Experimental and calculated enthalpies of formation of rare earth-tin alloys

Experimental and calculated enthalpies of formation of rare earth-tin alloys

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English descriptors

Abstract

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