Magnetic susceptibility studies of some new ternary and quaternary chlorides RENb6Cl18 and MRENb6Cl18 (RE = rare-Earth; M = monovalent cation)
Identifieur interne : 002722 ( Istex/Corpus ); précédent : 002721; suivant : 002723Magnetic susceptibility studies of some new ternary and quaternary chlorides RENb6Cl18 and MRENb6Cl18 (RE = rare-Earth; M = monovalent cation)
Auteurs : S. Ihmaïne ; C. Perrin ; O. Pe A ; M. SergentSource :
- Physica B: Physics of Condensed Matter [ 0921-4526 ] ; 1990.
English descriptors
- KwdEn :
- Acta cryst, Behaviour, Corresponding ternary compound, Divalent, Divalent state, Effective moment, Further work, Ground state, Ihmaine, Magnetic anisotropy, Magnetic behaviour, Magnetic clusters, Magnetic interactions, Magnetic state, Magnetic studies, Magnetic susceptibility, Monovalent cation, Niobium, Oxidation states, Quaternary, Quaternary chlorides, Quaternary compound, Sergent, Single crystals, Singlet ground state, Sintered, Sintered powder, Such interactions, Susceptibility, Ternary, Vleck, Vleck susceptibility.
- Teeft :
- Acta cryst, Behaviour, Corresponding ternary compound, Divalent, Divalent state, Effective moment, Further work, Ground state, Ihmaine, Magnetic anisotropy, Magnetic behaviour, Magnetic clusters, Magnetic interactions, Magnetic state, Magnetic studies, Magnetic susceptibility, Monovalent cation, Niobium, Oxidation states, Quaternary, Quaternary chlorides, Quaternary compound, Sergent, Single crystals, Singlet ground state, Sintered, Sintered powder, Such interactions, Susceptibility, Ternary, Vleck, Vleck susceptibility.
Abstract
Abstract: Magnetic susceptibility of recently isolated ternary and quaternary niobium chlorides containing rare-earth atoms are presented (RENb6Cl18, MRENb6Cl18; M = monovalent, RE = rare earth). These phases contain |Nb6Cl18|n- units and crystallize in the R3̄ space group, except for the CsRENb6Cl18 compounds which crystallize in hexagonal P3̄1c. These |Nb6Cl18|n- units may present a magnetic behaviour corresponding to one unpaired electron per Nb6 cluster (n = 3,15 e7minus;/Nb6), or may be nonmagnetic (n = 4, 16e−/Nb6). The magnetic state of both clusters and rare-earth atoms were studied on single crystals and powders. Interesting features are seen such as: magnetic interactions, Van Vleck susceptibility, mixed valences and magnetic anisotropy.
Url:
DOI: 10.1016/0921-4526(90)90286-4
Links to Exploration step
ISTEX:B08DEE3E8EDE5CA6D151DE42B2F48B76F0E94CDBLe document en format XML
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C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Physica B: Physics of Condensed Matter</title><title level="j" type="abbrev">PHYSB</title><idno type="ISSN">0921-4526</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1990">1990</date><biblScope unit="volume">163</biblScope><biblScope unit="issue">1–3</biblScope><biblScope unit="page" from="615">615</biblScope><biblScope unit="page" to="617">617</biblScope></imprint><idno type="ISSN">0921-4526</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0921-4526</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acta cryst</term><term>Behaviour</term><term>Corresponding ternary compound</term><term>Divalent</term><term>Divalent state</term><term>Effective moment</term><term>Further work</term><term>Ground state</term><term>Ihmaine</term><term>Magnetic anisotropy</term><term>Magnetic behaviour</term><term>Magnetic clusters</term><term>Magnetic interactions</term><term>Magnetic state</term><term>Magnetic studies</term><term>Magnetic susceptibility</term><term>Monovalent cation</term><term>Niobium</term><term>Oxidation states</term><term>Quaternary</term><term>Quaternary chlorides</term><term>Quaternary compound</term><term>Sergent</term><term>Single crystals</term><term>Singlet ground state</term><term>Sintered</term><term>Sintered powder</term><term>Such interactions</term><term>Susceptibility</term><term>Ternary</term><term>Vleck</term><term>Vleck susceptibility</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Acta cryst</term><term>Behaviour</term><term>Corresponding ternary compound</term><term>Divalent</term><term>Divalent state</term><term>Effective moment</term><term>Further work</term><term>Ground state</term><term>Ihmaine</term><term>Magnetic anisotropy</term><term>Magnetic behaviour</term><term>Magnetic clusters</term><term>Magnetic interactions</term><term>Magnetic state</term><term>Magnetic studies</term><term>Magnetic susceptibility</term><term>Monovalent cation</term><term>Niobium</term><term>Oxidation states</term><term>Quaternary</term><term>Quaternary chlorides</term><term>Quaternary compound</term><term>Sergent</term><term>Single crystals</term><term>Singlet ground state</term><term>Sintered</term><term>Sintered powder</term><term>Such interactions</term><term>Susceptibility</term><term>Ternary</term><term>Vleck</term><term>Vleck susceptibility</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: Magnetic susceptibility of recently isolated ternary and quaternary niobium chlorides containing rare-earth atoms are presented (RENb6Cl18, MRENb6Cl18; M = monovalent, RE = rare earth). These phases contain |Nb6Cl18|n- units and crystallize in the R3̄ space group, except for the CsRENb6Cl18 compounds which crystallize in hexagonal P3̄1c. These |Nb6Cl18|n- units may present a magnetic behaviour corresponding to one unpaired electron per Nb6 cluster (n = 3,15 e7minus;/Nb6), or may be nonmagnetic (n = 4, 16e−/Nb6). The magnetic state of both clusters and rare-earth atoms were studied on single crystals and powders. Interesting features are seen such as: magnetic interactions, Van Vleck susceptibility, mixed valences and magnetic anisotropy.</div></front></TEI><istex><corpusName>elsevier</corpusName><keywords><teeft><json:string>quaternary</json:string><json:string>single crystals</json:string><json:string>ihmaine</json:string><json:string>ternary</json:string><json:string>effective moment</json:string><json:string>sergent</json:string><json:string>magnetic susceptibility</json:string><json:string>susceptibility</json:string><json:string>magnetic state</json:string><json:string>vleck</json:string><json:string>niobium</json:string><json:string>sintered powder</json:string><json:string>divalent</json:string><json:string>magnetic interactions</json:string><json:string>vleck susceptibility</json:string><json:string>magnetic behaviour</json:string><json:string>such interactions</json:string><json:string>sintered</json:string><json:string>quaternary compound</json:string><json:string>corresponding ternary compound</json:string><json:string>magnetic anisotropy</json:string><json:string>magnetic studies</json:string><json:string>oxidation states</json:string><json:string>quaternary chlorides</json:string><json:string>further work</json:string><json:string>monovalent cation</json:string><json:string>divalent state</json:string><json:string>ground state</json:string><json:string>acta cryst</json:string><json:string>magnetic clusters</json:string><json:string>singlet ground state</json:string><json:string>behaviour</json:string></teeft></keywords><author><json:item><name>S. Ihmaïne</name><affiliations><json:string>Laboratoire de Chimie Minérale B, U.R.A. C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</json:string></affiliations></json:item><json:item><name>C. Perrin</name><affiliations><json:string>Laboratoire de Chimie Minérale B, U.R.A. C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</json:string></affiliations></json:item><json:item><name>O. Peña</name><affiliations><json:string>Laboratoire de Chimie Minérale B, U.R.A. C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</json:string></affiliations></json:item><json:item><name>M. Sergent</name><affiliations><json:string>Laboratoire de Chimie Minérale B, U.R.A. C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</json:string></affiliations></json:item></author><language><json:string>eng</json:string></language><originalGenre><json:string>Full-length article</json:string></originalGenre><abstract>Magnetic susceptibility of recently isolated ternary and quaternary niobium chlorides containing rare-earth atoms are presented (RENb6Cl18, MRENb6Cl18; M = monovalent, RE = rare earth). These phases contain |Nb6Cl18|n- units and crystallize in the R3̄ space group, except for the CsRENb6Cl18 compounds which crystallize in hexagonal P3̄1c. These |Nb6Cl18|n- units may present a magnetic behaviour corresponding to one unpaired electron per Nb6 cluster (n = 3,15 e7minus;/Nb6), or may be nonmagnetic (n = 4, 16e−/Nb6). The magnetic state of both clusters and rare-earth atoms were studied on single crystals and powders. Interesting features are seen such as: magnetic interactions, Van Vleck susceptibility, mixed valences and magnetic anisotropy.</abstract><qualityIndicators><score>2.691</score><pdfVersion>1.2</pdfVersion><pdfPageSize>548 x 749 pts</pdfPageSize><refBibsNative>true</refBibsNative><keywordCount>0</keywordCount><abstractCharCount>761</abstractCharCount><pdfWordCount>1419</pdfWordCount><pdfCharCount>8415</pdfCharCount><pdfPageCount>3</pdfPageCount><abstractWordCount>106</abstractWordCount></qualityIndicators><title>Magnetic susceptibility studies of some new ternary and quaternary chlorides RENb6Cl18 and MRENb6Cl18 (RE = rare-Earth; M = monovalent cation)</title><pii><json:string>0921-4526(90)90286-4</json:string></pii><genre><json:string>research-article</json:string></genre><host><title>Physica B: Physics of Condensed Matter</title><language><json:string>unknown</json:string></language><publicationDate>1990</publicationDate><issn><json:string>0921-4526</json:string></issn><pii><json:string>S0921-4526(00)X0191-3</json:string></pii><volume>163</volume><issue>1–3</issue><pages><first>615</first><last>617</last></pages><genre><json:string>journal</json:string></genre></host><categories><wos><json:string>science</json:string><json:string>physics, condensed matter</json:string></wos><scienceMetrix><json:string>natural sciences</json:string><json:string>physics & astronomy</json:string><json:string>general physics</json:string></scienceMetrix><inist><json:string>sciences appliquees, technologies et medecines</json:string><json:string>sciences biologiques et medicales</json:string><json:string>sciences biologiques fondamentales et appliquees. psychologie</json:string><json:string>vertebres: systeme cardiovasculaire</json:string></inist></categories><publicationDate>1990</publicationDate><copyrightDate>1990</copyrightDate><doi><json:string>10.1016/0921-4526(90)90286-4</json:string></doi><id>B08DEE3E8EDE5CA6D151DE42B2F48B76F0E94CDB</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/document/B08DEE3E8EDE5CA6D151DE42B2F48B76F0E94CDB/fulltext/pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/document/B08DEE3E8EDE5CA6D151DE42B2F48B76F0E94CDB/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/B08DEE3E8EDE5CA6D151DE42B2F48B76F0E94CDB/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a">Magnetic susceptibility studies of some new ternary and quaternary chlorides RENb6Cl18 and MRENb6Cl18 (RE = rare-Earth; M = monovalent cation)</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>ELSEVIER</publisher><availability><p>ELSEVIER</p></availability><date>1990</date></publicationStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a">Magnetic susceptibility studies of some new ternary and quaternary chlorides RENb6Cl18 and MRENb6Cl18 (RE = rare-Earth; M = monovalent cation)</title><author xml:id="author-0000"><persName><forename type="first">S.</forename><surname>Ihmaïne</surname></persName><affiliation>Laboratoire de Chimie Minérale B, U.R.A. C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</affiliation></author><author xml:id="author-0001"><persName><forename type="first">C.</forename><surname>Perrin</surname></persName><affiliation>Laboratoire de Chimie Minérale B, U.R.A. C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</affiliation></author><author xml:id="author-0002"><persName><forename type="first">O.</forename><surname>Peña</surname></persName><affiliation>Laboratoire de Chimie Minérale B, U.R.A. C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</affiliation></author><author xml:id="author-0003"><persName><forename type="first">M.</forename><surname>Sergent</surname></persName><affiliation>Laboratoire de Chimie Minérale B, U.R.A. C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</affiliation></author><idno type="istex">B08DEE3E8EDE5CA6D151DE42B2F48B76F0E94CDB</idno><idno type="DOI">10.1016/0921-4526(90)90286-4</idno><idno type="PII">0921-4526(90)90286-4</idno></analytic><monogr><title level="j">Physica B: Physics of Condensed Matter</title><title level="j" type="abbrev">PHYSB</title><idno type="pISSN">0921-4526</idno><idno type="PII">S0921-4526(00)X0191-3</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1990"></date><biblScope unit="volume">163</biblScope><biblScope unit="issue">1–3</biblScope><biblScope unit="page" from="615">615</biblScope><biblScope unit="page" to="617">617</biblScope></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>1990</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>Magnetic susceptibility of recently isolated ternary and quaternary niobium chlorides containing rare-earth atoms are presented (RENb6Cl18, MRENb6Cl18; M = monovalent, RE = rare earth). These phases contain |Nb6Cl18|n- units and crystallize in the R3̄ space group, except for the CsRENb6Cl18 compounds which crystallize in hexagonal P3̄1c. These |Nb6Cl18|n- units may present a magnetic behaviour corresponding to one unpaired electron per Nb6 cluster (n = 3,15 e7minus;/Nb6), or may be nonmagnetic (n = 4, 16e−/Nb6). The magnetic state of both clusters and rare-earth atoms were studied on single crystals and powders. Interesting features are seen such as: magnetic interactions, Van Vleck susceptibility, mixed valences and magnetic anisotropy.</p></abstract></profileDesc><revisionDesc><change when="1990">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/B08DEE3E8EDE5CA6D151DE42B2F48B76F0E94CDB/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: tail"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="fla"><item-info><jid>PHYSB</jid><aid>90902864</aid><ce:pii>0921-4526(90)90286-4</ce:pii><ce:doi>10.1016/0921-4526(90)90286-4</ce:doi><ce:copyright type="unknown" year="1990"></ce:copyright></item-info><head><ce:title>Magnetic susceptibility studies of some new ternary and quaternary chlorides RENb<ce:inf>6</ce:inf>Cl<ce:inf>18</ce:inf> and MRENb<ce:inf>6</ce:inf>Cl<ce:inf>18</ce:inf> (RE = rare-Earth; M = monovalent cation)</ce:title><ce:author-group><ce:author><ce:given-name>S.</ce:given-name><ce:surname>Ihmaïne</ce:surname></ce:author><ce:author><ce:given-name>C.</ce:given-name><ce:surname>Perrin</ce:surname></ce:author><ce:author><ce:given-name>O.</ce:given-name><ce:surname>Peña</ce:surname></ce:author><ce:author><ce:given-name>M.</ce:given-name><ce:surname>Sergent</ce:surname></ce:author><ce:affiliation><ce:textfn>Laboratoire de Chimie Minérale B, U.R.A. C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</ce:textfn></ce:affiliation></ce:author-group><ce:abstract><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para>Magnetic susceptibility of recently isolated ternary and quaternary niobium chlorides containing rare-earth atoms are presented (RENb<ce:inf>6</ce:inf>Cl<ce:inf>18</ce:inf>, MRENb<ce:inf>6</ce:inf>Cl<ce:inf>18</ce:inf>; M = monovalent, RE = rare earth). These phases contain |Nb<ce:inf>6</ce:inf>Cl<ce:inf>18</ce:inf>|<ce:sup><ce:italic>n-</ce:italic></ce:sup> units and crystallize in the R3̄ space group, except for the CsRENb<ce:inf>6</ce:inf>Cl<ce:inf>18</ce:inf> compounds which crystallize in hexagonal P3̄1c. These |Nb<ce:inf>6</ce:inf>Cl<ce:inf>18</ce:inf>|<ce:sup><ce:italic>n-</ce:italic></ce:sup> units may present a magnetic behaviour corresponding to one unpaired electron per Nb<ce:inf>6</ce:inf> cluster (<ce:italic>n</ce:italic> = 3,15 e<ce:sup>7minus;</ce:sup>/Nb<ce:inf>6</ce:inf>), or may be nonmagnetic (<ce:italic>n</ce:italic> = 4, 16e<ce:sup>−</ce:sup>/Nb<ce:inf>6</ce:inf>). The magnetic state of both clusters and rare-earth atoms were studied on single crystals and powders. Interesting features are seen such as: magnetic interactions, Van Vleck susceptibility, mixed valences and magnetic anisotropy.</ce:simple-para></ce:abstract-sec></ce:abstract></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo><title>Magnetic susceptibility studies of some new ternary and quaternary chlorides RENb6Cl18 and MRENb6Cl18 (RE = rare-Earth; M = monovalent cation)</title></titleInfo><titleInfo type="alternative" contentType="CDATA"><title>Magnetic susceptibility studies of some new ternary and quaternary chlorides RENb</title></titleInfo><name type="personal"><namePart type="given">S.</namePart><namePart type="family">Ihmaïne</namePart><affiliation>Laboratoire de Chimie Minérale B, U.R.A. C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">C.</namePart><namePart type="family">Perrin</namePart><affiliation>Laboratoire de Chimie Minérale B, U.R.A. C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">O.</namePart><namePart type="family">Peña</namePart><affiliation>Laboratoire de Chimie Minérale B, U.R.A. C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Sergent</namePart><affiliation>Laboratoire de Chimie Minérale B, U.R.A. C.N.R.S. no. 254, Université de Rennes I, 35042 Rennes Cédex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1990</dateIssued><copyrightDate encoding="w3cdtf">1990</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><abstract lang="en">Abstract: Magnetic susceptibility of recently isolated ternary and quaternary niobium chlorides containing rare-earth atoms are presented (RENb6Cl18, MRENb6Cl18; M = monovalent, RE = rare earth). These phases contain |Nb6Cl18|n- units and crystallize in the R3̄ space group, except for the CsRENb6Cl18 compounds which crystallize in hexagonal P3̄1c. These |Nb6Cl18|n- units may present a magnetic behaviour corresponding to one unpaired electron per Nb6 cluster (n = 3,15 e7minus;/Nb6), or may be nonmagnetic (n = 4, 16e−/Nb6). The magnetic state of both clusters and rare-earth atoms were studied on single crystals and powders. Interesting features are seen such as: magnetic interactions, Van Vleck susceptibility, mixed valences and magnetic anisotropy.</abstract><relatedItem type="host"><titleInfo><title>Physica B: Physics of Condensed Matter</title></titleInfo><titleInfo type="abbreviated"><title>PHYSB</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">199004</dateIssued></originInfo><identifier type="ISSN">0921-4526</identifier><identifier type="PII">S0921-4526(00)X0191-3</identifier><part><date>199004</date><detail type="volume"><number>163</number><caption>vol.</caption></detail><detail type="issue"><number>1–3</number><caption>no.</caption></detail><extent unit="issue-pages"><start>1</start><end>755</end></extent><extent unit="pages"><start>615</start><end>617</end></extent></part></relatedItem><identifier type="istex">B08DEE3E8EDE5CA6D151DE42B2F48B76F0E94CDB</identifier><identifier type="ark">ark:/67375/6H6-G2QFGH7K-S</identifier><identifier type="DOI">10.1016/0921-4526(90)90286-4</identifier><identifier type="PII">0921-4526(90)90286-4</identifier><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-HKKZVM7B-M">elsevier</recordContentSource></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/B08DEE3E8EDE5CA6D151DE42B2F48B76F0E94CDB/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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