ThuliumV1, Istex, Corpus, bibRecord, 002067

Preparation and Crystal Structure of the Ternary Lanthanoid Nickel Arsenides Ln13Ni25As19 (Ln = Tm, Yb, and Lu)

Identifieur interne : 002067 ( Istex/Corpus ); précédent : 002066; suivant : 002068

Preparation and Crystal Structure of the Ternary Lanthanoid Nickel Arsenides Ln13Ni25As19 (Ln = Tm, Yb, and Lu)

Auteurs : Wolfgang Jeitschko ; Ludger J. Terbüchte ; Ute Ch. Rodewald

Source :

ZAAC ‐ Journal of Inorganic and General Chemistry [ 0044-2313 ] ; 2001-09.

RBID : ISTEX:933DE9E38CB404B4069839D9C25C129EFC583B2D

English descriptors

Abstract

The title compounds were prepared by reaction of the elemental components at high temperatures. They crystallize with a new structure type which was determined from single‐crystal X‐ray data of Tm13Ni25As19: P 6, a = 1621.9(4) pm, c = 387.78(8) pm, Z = 1, R = 0.025 for 3164 structure factors and 119 variable parameters. The refinement of the occupancy parameters suggested a mixed Tm/Ni occupancy for one metal position and defects for one nickel site resulting in the composition Tm12.57(1)Ni25.22(2)As19. These arsenides belong to a large structural family with a metal to metalloid ratio of 2 : 1.

Url:

https://api.istex.fr/document/933DE9E38CB404B4069839D9C25C129EFC583B2D/fulltext/pdf

DOI: 10.1002/1521-3749(200109)627:9<2095::AID-ZAAC2095>3.0.CO;2-B

Links to Exploration step

ISTEX:933DE9E38CB404B4069839D9C25C129EFC583B2D

Le document en format XML

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<p>The title compounds were prepared by reaction of the elemental components at high temperatures. They crystallize with a new structure type which was determined from single‐crystal X‐ray data of Tm<hi rend="subscript">13</hi>
Ni<hi rend="subscript">25</hi>
As<hi rend="subscript">19</hi>
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As<hi rend="subscript">19</hi>
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<abstract xml:lang="de" style="main"><p><hi rend="bold">Darstellung und Kristallstruktur der ternären Lanthanoid‐Nickel‐Arsenide </hi>
<hi rend="italic">Ln</hi>
<hi rend="bold"><hi rend="subscript">13</hi>
Ni<hi rend="subscript">25</hi>
As<hi rend="subscript">19</hi>
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<p>Die im Titel genannten Verbindungen wurden durch Reaktion der elementaren Komponenten bei hohen Temperaturen hergestellt. Sie kristallisieren in einem neuen Strukturtyp, der aus Röntgen‐Einkristalldaten von Tm<hi rend="subscript">13</hi>
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Ni<hi rend="subscript">25,22(2)</hi>
As<hi rend="subscript">19</hi>
. Diese Arsenide gehören zu einer großen Strukturfamilie mit einem Metall‐ zu Metalloid‐Verhältnis von 2 : 1.</p>
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<correspondenceTo>Anorganisch‐Chemisches Institut, Universität Münster, Wilhelm Klemm‐Straße 8, D‐48149 Münster, Germany</correspondenceTo>
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<titleGroup><title type="main" xml:lang="en">Preparation and Crystal Structure of the Ternary Lanthanoid Nickel Arsenides <i>Ln</i>
<sub>13</sub>
Ni<sub>25</sub>
As<sub>19</sub>
 (<i>Ln</i>
 = Tm, Yb, and Lu)</title>
</titleGroup>
<creators><creator xml:id="au1" creatorRole="author" affiliationRef="#a1" corresponding="yes"><personName><givenNames>Wolfgang</givenNames>
<familyName>Jeitschko</familyName>
</personName>
</creator>
<creator xml:id="au2" creatorRole="author" affiliationRef="#a1"><personName><givenNames>Ludger J.</givenNames>
<familyName>Terbüchte</familyName>
</personName>
</creator>
<creator xml:id="au3" creatorRole="author" affiliationRef="#a1"><personName><givenNames>Ute Ch.</givenNames>
<familyName>Rodewald</familyName>
</personName>
</creator>
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</affiliation>
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<keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">Crystal structure</keyword>
<keyword xml:id="kwd2">Rare earth compounds</keyword>
<keyword xml:id="kwd3">Arsenides</keyword>
</keywordGroup>
<abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title>
<p>The title compounds were prepared by reaction of the elemental components at high temperatures. They crystallize with a new structure type which was determined from single‐crystal X‐ray data of Tm<sub>13</sub>
Ni<sub>25</sub>
As<sub>19</sub>
: <i>P</i>
 6, <i>a</i>
 = 1621.9(4) pm, <i>c</i>
 = 387.78(8) pm, <i>Z</i>
 = 1, <i>R</i>
 = 0.025 for 3164 structure factors and 119 variable parameters. The refinement of the occupancy parameters suggested a mixed Tm/Ni occupancy for one metal position and defects for one nickel site resulting in the composition Tm<sub>12.57(1)</sub>
Ni<sub>25.22(2)</sub>
As<sub>19</sub>
. These arsenides belong to a large structural family with a metal to metalloid ratio of 2 : 1.</p>
</abstract>
<abstract type="main" xml:lang="de"><p><b>Darstellung und Kristallstruktur der ternären Lanthanoid‐Nickel‐Arsenide </b>
<i>Ln</i>
<b><sub>13</sub>
Ni<sub>25</sub>
As<sub>19</sub>
 (</b>
<i>Ln</i>
<b> = Tm, Yb und Lu)</b>
</p>
<p>Die im Titel genannten Verbindungen wurden durch Reaktion der elementaren Komponenten bei hohen Temperaturen hergestellt. Sie kristallisieren in einem neuen Strukturtyp, der aus Röntgen‐Einkristalldaten von Tm<sub>13</sub>
Ni<sub>25</sub>
As<sub>19</sub>
 bestimmt worden ist: <i>P</i>
 6, <i>a</i>
 = 1621,9(4) pm, <i>c</i>
 = 387,78(8) pm, <i>Z</i>
 = 1. <i>R</i>
 = 0,025 für 3164 Strukturfaktoren und 119 variable Parameter. Die Verfeinerung der Besetzungsparameter ergab eine gemischte Tm/Ni‐Besetzung für eine der Metallpositionen und eine leichte Unterbesetzung einer Nickellage entsprechend der Zusammensetzung Tm<sub>12,57(1)</sub>
Ni<sub>25,22(2)</sub>
As<sub>19</sub>
. Diese Arsenide gehören zu einer großen Strukturfamilie mit einem Metall‐ zu Metalloid‐Verhältnis von 2 : 1.</p>
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<name type="personal"><namePart type="given">Wolfgang</namePart>
<namePart type="family">Jeitschko</namePart>
<affiliation>Münster, Anorganisch‐Chemisches Institut der Westfälischen Wilhelms‐Universität</affiliation>
<affiliation>Correspondence address: Anorganisch‐Chemisches Institut, Universität Münster, Wilhelm Klemm‐Straße 8, D‐48149 Münster, Germany</affiliation>
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<name type="personal"><namePart type="given">Ludger J.</namePart>
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<name type="personal"><namePart type="given">Ute Ch.</namePart>
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<abstract lang="en">The title compounds were prepared by reaction of the elemental components at high temperatures. They crystallize with a new structure type which was determined from single‐crystal X‐ray data of Tm13Ni25As19: P 6, a = 1621.9(4) pm, c = 387.78(8) pm, Z = 1, R = 0.025 for 3164 structure factors and 119 variable parameters. The refinement of the occupancy parameters suggested a mixed Tm/Ni occupancy for one metal position and defects for one nickel site resulting in the composition Tm12.57(1)Ni25.22(2)As19. These arsenides belong to a large structural family with a metal to metalloid ratio of 2 : 1.</abstract>
<abstract>Darstellung und Kristallstruktur der ternären Lanthanoid‐Nickel‐Arsenide Ln13Ni25As19 (Ln = Tm, Yb und Lu)</abstract>
<abstract>Die im Titel genannten Verbindungen wurden durch Reaktion der elementaren Komponenten bei hohen Temperaturen hergestellt. Sie kristallisieren in einem neuen Strukturtyp, der aus Röntgen‐Einkristalldaten von Tm13Ni25As19 bestimmt worden ist: P 6, a = 1621,9(4) pm, c = 387,78(8) pm, Z = 1. R = 0,025 für 3164 Strukturfaktoren und 119 variable Parameter. Die Verfeinerung der Besetzungsparameter ergab eine gemischte Tm/Ni‐Besetzung für eine der Metallpositionen und eine leichte Unterbesetzung einer Nickellage entsprechend der Zusammensetzung Tm12,57(1)Ni25,22(2)As19. Diese Arsenide gehören zu einer großen Strukturfamilie mit einem Metall‐ zu Metalloid‐Verhältnis von 2 : 1.</abstract>
<subject lang="en"><genre>keywords</genre>
<topic>Crystal structure</topic>
<topic>Rare earth compounds</topic>
<topic>Arsenides</topic>
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Preparation and Crystal Structure of the Ternary Lanthanoid Nickel Arsenides Ln13Ni25As19 (Ln = Tm, Yb, and Lu)

Preparation and Crystal Structure of the Ternary Lanthanoid Nickel Arsenides Ln13Ni25As19 (Ln = Tm, Yb, and Lu)

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