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The Determination of the Stability Constants of some Lanthanide‐α‐Hydroxyisobutyrate Complexes Using Cation Exchange Methods

Identifieur interne : 001F97 ( Istex/Corpus ); précédent : 001F96; suivant : 001F98

The Determination of the Stability Constants of some Lanthanide‐α‐Hydroxyisobutyrate Complexes Using Cation Exchange Methods

Auteurs : H. Deelstra ; F. Verbeek

Source :

RBID : ISTEX:906870B2849754205289086B856296F691EC1A10

English descriptors

Abstract

The stability constants of some lanthanide‐α‐hydroxyisobutyrate complex systems have been determined by cation exchange measurements. Fronaeus' method was used to calculate the consecutive formation constants of the terbium and thulium complex systems in 0.2 M and 1 M ammonium perchlorate. The β3 values of nine lanthanide complex systems have been derived by Schubert's method. The formation constants determined by the cation exchange technique agree with the values found by potentiometric titration.

Url:
DOI: 10.1002/bscb.19640730527

Links to Exploration step

ISTEX:906870B2849754205289086B856296F691EC1A10

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