Sm2O2I – A New Mixed‐Valence Samarium(II,III) Oxide Halide
Identifieur interne : 000B06 ( Istex/Corpus ); précédent : 000B05; suivant : 000B07Sm2O2I – A New Mixed‐Valence Samarium(II,III) Oxide Halide
Auteurs : Mikhail Ryazanov ; Constantin Hoch ; Hansjürgen Mattausch ; Arndt SimonSource :
- ZAAC ‐ Journal of Inorganic and General Chemistry [ 0044-2313 ] ; 2006-11.
English descriptors
- KwdEn :
- Acta, Acta crystallogr, Allg, Anorg, Atomic coordinates, Bond valence parameters, Chem, Corrugated layer, Corrugated layers, Crystal data, Crystal structure, Crystallogr, Divalent, Empirical valence, Gmbh, Halide, Kgaa, Mattausch, Metal atoms, Oxide halide, Oxide halides, Room temperature, Ryazanov, Samarium, Sm4o, Smi2, Stoe, Stoe ipds, Structure determination, Tetrahedron, Valence, Verlag, Verlag gmbh, Weinheim.
- Teeft :
- Acta, Acta crystallogr, Allg, Anorg, Atomic coordinates, Bond valence parameters, Chem, Corrugated layer, Corrugated layers, Crystal data, Crystal structure, Crystallogr, Divalent, Empirical valence, Gmbh, Halide, Kgaa, Mattausch, Metal atoms, Oxide halide, Oxide halides, Room temperature, Ryazanov, Samarium, Sm4o, Smi2, Stoe, Stoe ipds, Structure determination, Tetrahedron, Valence, Verlag, Verlag gmbh, Weinheim.
Abstract
Dark red single crystals of Sm2O2I were obtained from a reaction of SmI2 (in the presence of SmOI) and Na in a sealed tantalum ampoule at 650 °C. The title compound crystallizes in the monoclinic system (C2/m, Z = 4, a = 12.639(2), b = 4.100(1), c = 9.762(3) Å, β = 117.97(2)°). The structure consists of corrugated [Sm2+Sm3+(O2−)2]+ layers of edge and vertex‐connected Sm4O tetrahedral units with I− anions separating the layers.
Url:
DOI: 10.1002/zaac.200600176
Links to Exploration step
ISTEX:3218E9B3DDAA100F46B44FFF1FDF67B7EB8645D5Le document en format XML
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für Festkörperforschung</mods:affiliation></affiliation></author><author><name sortKey="Simon, Arndt" sort="Simon, Arndt" uniqKey="Simon A" first="Arndt" last="Simon">Arndt Simon</name><affiliation><mods:affiliation>Stuttgart, Max‐Planck Institut für Festkörperforschung</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: A.Simon@fkf.mpg.de</mods:affiliation></affiliation><affiliation><mods:affiliation>Correspondence address: Max‐Planck‐Institut für Festkörperforschung, Heisenbergstr. 1, D‐70569 Stuttgart, Deutschland, FAX: 0711/689/1091</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">ZAAC ‐ Journal of Inorganic and General Chemistry</title><idno type="ISSN">0044-2313</idno><idno type="eISSN">1521-3749</idno><imprint><biblScope unit="vol">632</biblScope><biblScope unit="issue">15</biblScope><biblScope unit="page" from="2385">2385</biblScope><biblScope unit="page" to="2388">2388</biblScope><biblScope 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gmbh</term><term>Weinheim</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Dark red single crystals of Sm2O2I were obtained from a reaction of SmI2 (in the presence of SmOI) and Na in a sealed tantalum ampoule at 650 °C. The title compound crystallizes in the monoclinic system (C2/m, Z = 4, a = 12.639(2), b = 4.100(1), c = 9.762(3) Å, β = 117.97(2)°). The structure consists of corrugated [Sm2+Sm3+(O2−)2]+ layers of edge and vertex‐connected Sm4O tetrahedral units with I− anions separating the layers.</div></front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>chem</json:string><json:string>halide</json:string><json:string>allg</json:string><json:string>anorg</json:string><json:string>valence</json:string><json:string>mattausch</json:string><json:string>smi2</json:string><json:string>samarium</json:string><json:string>crystallogr</json:string><json:string>gmbh</json:string><json:string>sm4o</json:string><json:string>acta crystallogr</json:string><json:string>acta</json:string><json:string>stoe</json:string><json:string>crystal structure</json:string><json:string>verlag</json:string><json:string>tetrahedron</json:string><json:string>ryazanov</json:string><json:string>kgaa</json:string><json:string>divalent</json:string><json:string>weinheim</json:string><json:string>verlag gmbh</json:string><json:string>metal atoms</json:string><json:string>oxide halides</json:string><json:string>corrugated layers</json:string><json:string>oxide halide</json:string><json:string>crystal data</json:string><json:string>structure determination</json:string><json:string>bond valence parameters</json:string><json:string>empirical valence</json:string><json:string>corrugated layer</json:string><json:string>room temperature</json:string><json:string>stoe ipds</json:string><json:string>atomic coordinates</json:string></teeft></keywords><author><json:item><name>Mikhail Ryazanov</name><affiliations><json:string>Stuttgart, Max‐Planck Institut für Festkörperforschung</json:string></affiliations></json:item><json:item><name>Constantin Hoch</name><affiliations><json:string>Stuttgart, Max‐Planck Institut für Festkörperforschung</json:string></affiliations></json:item><json:item><name>Hansjürgen Mattausch</name><affiliations><json:string>Stuttgart, Max‐Planck Institut für Festkörperforschung</json:string></affiliations></json:item><json:item><name>Arndt Simon Prof. Dr. Dr.h.c. mult.</name><affiliations><json:string>Stuttgart, Max‐Planck Institut für Festkörperforschung</json:string><json:string>Max‐Planck‐Institut für Festkörperforschung, Heisenbergstr. 1, D‐70569 Stuttgart, Deutschland, FAX: 0711/689/1091</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>Samarium mixed‐valence Samarium (II,III)</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Oxide halides</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Crystal structure</value></json:item></subject><articleId><json:string>ZAAC200600176</json:string></articleId><language><json:string>eng</json:string></language><originalGenre><json:string>article</json:string></originalGenre><abstract>Dark red single crystals of Sm2O2I were obtained from a reaction of SmI2 (in the presence of SmOI) and Na in a sealed tantalum ampoule at 650 °C. The title compound crystallizes in the monoclinic system (C2/m, Z = 4, a = 12.639(2), b = 4.100(1), c = 9.762(3) Å, β = 117.97(2)°). The structure consists of corrugated [Sm2+Sm3+(O2−)2]+ layers of edge and vertex‐connected Sm4O tetrahedral units with I− anions separating the layers.</abstract><qualityIndicators><score>2.841</score><pdfVersion>1.3</pdfVersion><pdfPageSize>599 x 788 pts</pdfPageSize><refBibsNative>true</refBibsNative><abstractCharCount>430</abstractCharCount><pdfWordCount>1965</pdfWordCount><pdfCharCount>12365</pdfCharCount><pdfPageCount>4</pdfPageCount><abstractWordCount>73</abstractWordCount></qualityIndicators><title>Sm2O2I – A New Mixed‐Valence Samarium(II,III) Oxide Halide</title><genre><json:string>article</json:string></genre><host><title>ZAAC ‐ Journal of Inorganic and General Chemistry</title><language><json:string>unknown</json:string></language><doi><json:string>10.1002/(ISSN)1521-3749</json:string></doi><issn><json:string>0044-2313</json:string></issn><eissn><json:string>1521-3749</json:string></eissn><publisherId><json:string>ZAAC</json:string></publisherId><volume>632</volume><issue>15</issue><pages><first>2385</first><last>2388</last><total>4</total></pages><genre><json:string>journal</json:string></genre><subject><json:item><value>Article</value></json:item></subject></host><categories><wos><json:string>science</json:string><json:string>chemistry, inorganic & nuclear</json:string></wos><scienceMetrix><json:string>natural sciences</json:string><json:string>chemistry</json:string><json:string>inorganic & nuclear chemistry</json:string></scienceMetrix><inist><json:string>sciences appliquees, technologies et medecines</json:string><json:string>sciences biologiques et medicales</json:string><json:string>sciences biologiques fondamentales et appliquees. psychologie</json:string></inist></categories><publicationDate>2006</publicationDate><copyrightDate>2006</copyrightDate><doi><json:string>10.1002/zaac.200600176</json:string></doi><id>3218E9B3DDAA100F46B44FFF1FDF67B7EB8645D5</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/document/3218E9B3DDAA100F46B44FFF1FDF67B7EB8645D5/fulltext/pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/document/3218E9B3DDAA100F46B44FFF1FDF67B7EB8645D5/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/3218E9B3DDAA100F46B44FFF1FDF67B7EB8645D5/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">Sm<hi rend="subscript">2</hi>O<hi rend="subscript">2</hi>I – A New Mixed‐Valence Samarium(II,III) Oxide Halide</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><availability><licence>Copyright © 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</licence></availability><date type="published" when="2006-11"></date></publicationStmt><notesStmt><note type="content-type" subtype="article" source="article" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</note><note type="publication-type" subtype="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note></notesStmt><sourceDesc><biblStruct type="article"><analytic><title level="a" type="main" xml:lang="en">Sm<hi rend="subscript">2</hi>O<hi rend="subscript">2</hi>I – A New Mixed‐Valence Samarium(II,III) Oxide Halide</title><author xml:id="author-0000"><persName><forename type="first">Mikhail</forename><surname>Ryazanov</surname></persName><affiliation>Stuttgart, Max‐Planck Institut für Festkörperforschung<address><country key="DE"></country></address></affiliation></author><author xml:id="author-0001"><persName><forename type="first">Constantin</forename><surname>Hoch</surname></persName><affiliation>Stuttgart, Max‐Planck Institut für Festkörperforschung<address><country key="DE"></country></address></affiliation></author><author xml:id="author-0002"><persName><forename type="first">Hansjürgen</forename><surname>Mattausch</surname></persName><affiliation>Stuttgart, Max‐Planck Institut für Festkörperforschung<address><country key="DE"></country></address></affiliation></author><author xml:id="author-0003" role="corresp"><persName><forename type="first">Arndt</forename><surname>Simon</surname><roleName type="degree">Prof. Dr. Dr.h.c. mult.</roleName></persName><email>A.Simon@fkf.mpg.de</email><affiliation>Stuttgart, Max‐Planck Institut für Festkörperforschung<address><country key="DE"></country></address></affiliation><affiliation>Max‐Planck‐Institut für Festkörperforschung, Heisenbergstr. 1, D‐70569 Stuttgart, Deutschland, FAX: 0711/689/1091</affiliation></author><idno type="istex">3218E9B3DDAA100F46B44FFF1FDF67B7EB8645D5</idno><idno type="ark">ark:/67375/WNG-M288V30V-K</idno><idno type="DOI">10.1002/zaac.200600176</idno><idno type="unit">ZAAC200600176</idno><idno type="toTypesetVersion">file:ZAAC.ZAAC200600176.pdf</idno></analytic><monogr><title level="j" type="main">ZAAC ‐ Journal of Inorganic and General Chemistry</title><idno type="pISSN">0044-2313</idno><idno type="eISSN">1521-3749</idno><idno type="book-DOI">10.1002/(ISSN)1521-3749</idno><idno type="book-part-DOI">10.1002/zaac.v632:15</idno><idno type="product">ZAAC</idno><imprint><biblScope unit="vol">632</biblScope><biblScope unit="issue">15</biblScope><biblScope unit="page" from="2385">2385</biblScope><biblScope unit="page" to="2388">2388</biblScope><biblScope unit="page-count">4</biblScope><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2006-11"></date></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><abstract xml:lang="en" style="main"><head>Abstract</head><p>Dark red single crystals of Sm<hi rend="subscript">2</hi>O<hi rend="subscript">2</hi>I were obtained from a reaction of SmI<hi rend="subscript">2</hi> (in the presence of SmOI) and Na in a sealed tantalum ampoule at 650 °C. The title compound crystallizes in the monoclinic system (<hi rend="italic">C</hi>2/<hi rend="italic">m</hi>, <hi rend="italic">Z</hi> = 4, <hi rend="italic">a</hi> = 12.639(2), <hi rend="italic">b</hi> = 4.100(1), <hi rend="italic">c</hi> = 9.762(3) Å, <hi rend="italic">β</hi> = 117.97(2)°). The structure consists of corrugated [Sm<hi rend="superscript">2+</hi>Sm<hi rend="superscript">3+</hi>(O<hi rend="superscript">2−</hi>)<hi rend="subscript">2</hi>]<hi rend="superscript">+</hi> layers of edge and vertex‐connected Sm<hi rend="subscript">4</hi>O tetrahedral units with I<hi rend="superscript">−</hi> anions separating the layers.</p></abstract><textClass><keywords xml:lang="en"><term xml:id="kwd1">Samarium mixed‐valence Samarium (II,III)</term><term xml:id="kwd2">Oxide halides</term><term xml:id="kwd3">Crystal structure</term></keywords><keywords rend="articleCategory"><term>Article</term></keywords><keywords rend="tocHeading1"><term>Articles</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/3218E9B3DDAA100F46B44FFF1FDF67B7EB8645D5/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>WILEY‐VCH Verlag</publisherName><publisherLoc>Weinheim</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1521-3749</doi><issn type="print">0044-2313</issn><issn type="electronic">1521-3749</issn><idGroup><id type="product" value="ZAAC"></id></idGroup><titleGroup><title type="main" xml:lang="en">ZAAC ‐ Journal of Inorganic and General Chemistry</title><title type="tocForm">ZAAC ‐ Journal of Inorganic and General Chemistry</title><title type="short">Z. anorg. allg. 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KGaA, Weinheim</copyright><eventGroup><event type="manuscriptReceived" date="2006-06-27"></event><event type="firstOnline" date="2006-11-02"></event><event type="publishedOnlineFinalForm" date="2006-11-02"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.12 mode:FullText source:HeaderRef result:HeaderRef" date="2010-07-09"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-02-11"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-11-04"></event></eventGroup><numberingGroup><numbering type="pageFirst">2385</numbering><numbering type="pageLast">2388</numbering></numberingGroup><correspondenceTo>Max‐Planck‐Institut für Festkörperforschung, Heisenbergstr. 1, D‐70569 Stuttgart, Deutschland, FAX: 0711/689/1091</correspondenceTo><linkGroup><link type="toTypesetVersion" href="file:ZAAC.ZAAC200600176.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="3"></count><count type="tableTotal" number="3"></count><count type="referenceTotal" number="18"></count></countGroup><titleGroup><title type="main" xml:lang="en">Sm<sub>2</sub>O<sub>2</sub>I – A New Mixed‐Valence Samarium(II,III) Oxide Halide</title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#a1"><personName><givenNames>Mikhail</givenNames><familyName>Ryazanov</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#a1"><personName><givenNames>Constantin</givenNames><familyName>Hoch</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#a1"><personName><givenNames>Hansjürgen</givenNames><familyName>Mattausch</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#a1" corresponding="yes"><personName><givenNames>Arndt</givenNames><familyName>Simon</familyName><degrees>Prof. Dr. Dr.h.c. mult.</degrees></personName><contactDetails><email>A.Simon@fkf.mpg.de</email></contactDetails></creator></creators><affiliationGroup><affiliation xml:id="a1" countryCode="DE" type="organization"><unparsedAffiliation>Stuttgart, Max‐Planck Institut für Festkörperforschung</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">Samarium mixed‐valence Samarium (II,III)</keyword><keyword xml:id="kwd2">Oxide halides</keyword><keyword xml:id="kwd3">Crystal structure</keyword></keywordGroup><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>Dark red single crystals of Sm<sub>2</sub>O<sub>2</sub>I were obtained from a reaction of SmI<sub>2</sub> (in the presence of SmOI) and Na in a sealed tantalum ampoule at 650 °C. The title compound crystallizes in the monoclinic system (<i>C</i>2/<i>m</i>, <i>Z</i> = 4, <i>a</i> = 12.639(2), <i>b</i> = 4.100(1), <i>c</i> = 9.762(3) Å, <i>β</i> = 117.97(2)°). The structure consists of corrugated [Sm<sup>2+</sup>Sm<sup>3+</sup>(O<sup>2−</sup>)<sub>2</sub>]<sup>+</sup> layers of edge and vertex‐connected Sm<sub>4</sub>O tetrahedral units with I<sup>−</sup> anions separating the layers.</p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Sm2O2I – A New Mixed‐Valence Samarium(II,III) Oxide Halide</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Sm2O2I – A New Mixed‐Valence Samarium(II,III) Oxide Halide</title></titleInfo><name type="personal"><namePart type="given">Mikhail</namePart><namePart type="family">Ryazanov</namePart><affiliation>Stuttgart, Max‐Planck Institut für Festkörperforschung</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Constantin</namePart><namePart type="family">Hoch</namePart><affiliation>Stuttgart, Max‐Planck Institut für Festkörperforschung</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Hansjürgen</namePart><namePart type="family">Mattausch</namePart><affiliation>Stuttgart, Max‐Planck Institut für Festkörperforschung</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Arndt</namePart><namePart type="family">Simon</namePart><namePart type="termsOfAddress">Prof. Dr. Dr.h.c. mult.</namePart><affiliation>Stuttgart, Max‐Planck Institut für Festkörperforschung</affiliation><affiliation>E-mail: A.Simon@fkf.mpg.de</affiliation><affiliation>Correspondence address: Max‐Planck‐Institut für Festkörperforschung, Heisenbergstr. 1, D‐70569 Stuttgart, Deutschland, FAX: 0711/689/1091</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</genre><originInfo><publisher>WILEY‐VCH Verlag</publisher><place><placeTerm type="text">Weinheim</placeTerm></place><dateIssued encoding="w3cdtf">2006-11</dateIssued><dateCaptured encoding="w3cdtf">2006-06-27</dateCaptured><copyrightDate encoding="w3cdtf">2006</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">3</extent><extent unit="tables">3</extent><extent unit="references">18</extent></physicalDescription><abstract lang="en">Dark red single crystals of Sm2O2I were obtained from a reaction of SmI2 (in the presence of SmOI) and Na in a sealed tantalum ampoule at 650 °C. The title compound crystallizes in the monoclinic system (C2/m, Z = 4, a = 12.639(2), b = 4.100(1), c = 9.762(3) Å, β = 117.97(2)°). The structure consists of corrugated [Sm2+Sm3+(O2−)2]+ layers of edge and vertex‐connected Sm4O tetrahedral units with I− anions separating the layers.</abstract><subject lang="en"><genre>keywords</genre><topic>Samarium mixed‐valence Samarium (II,III)</topic><topic>Oxide halides</topic><topic>Crystal structure</topic></subject><relatedItem type="host"><titleInfo><title>ZAAC ‐ Journal of Inorganic and General Chemistry</title></titleInfo><titleInfo type="abbreviated"><title>Z. anorg. allg. Chem.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><subject><genre>article-category</genre><topic>Article</topic></subject><identifier type="ISSN">0044-2313</identifier><identifier type="eISSN">1521-3749</identifier><identifier type="DOI">10.1002/(ISSN)1521-3749</identifier><identifier type="PublisherID">ZAAC</identifier><part><date>2006</date><detail type="volume"><caption>vol.</caption><number>632</number></detail><detail type="issue"><caption>no.</caption><number>15</number></detail><extent unit="pages"><start>2385</start><end>2388</end><total>4</total></extent></part></relatedItem><identifier type="istex">3218E9B3DDAA100F46B44FFF1FDF67B7EB8645D5</identifier><identifier type="ark">ark:/67375/WNG-M288V30V-K</identifier><identifier type="DOI">10.1002/zaac.200600176</identifier><identifier type="ArticleID">ZAAC200600176</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-L0C46X92-X">wiley</recordContentSource><recordOrigin>WILEY‐VCH Verlag</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/3218E9B3DDAA100F46B44FFF1FDF67B7EB8645D5/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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