The Tb2(Cu0.47Al0.53)17 and Tb(Cu0.58Al0.42)11 aluminides and their crystal structures
Identifieur interne : 000016 ( Istex/Corpus ); précédent : 000015; suivant : 000017The Tb2(Cu0.47Al0.53)17 and Tb(Cu0.58Al0.42)11 aluminides and their crystal structures
Auteurs : B. M. Stel'Makhovych ; L. G. Aksel'Rud ; Yu. B. Kuz'MaSource :
- Journal of Alloys and Compounds [ 0925-8388 ] ; 1996.
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Abstract
Abstract: The crystal structure of the new compound Tb2(Cu0.47Al0.53)17 with Th2Zn17-type structure (space group R3m, a = 8.767(3), c = 12.824(3)Å) has been determined using single crystal X-ray diffraction leading to R = 0.036 for 407 independent Fhkl values. The crystal structure of Tb(Cu0.58Al0.42)11 has been established from X-ray powder data with atomic parameter refinement by the Rietveld method (space group Fddd, a = 14.2792(6), b = 14.8916(6), c = 6.5644(3)Å). Both structures are characterized by an icosahedral coordination of the smallest atoms.
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DOI: 10.1016/0925-8388(95)01944-8
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Stel'Makhovych</name><affiliation><mods:affiliation>Institute of Chemistry, L'viv State University, Kyryla and Mefodiya Str. 6, Lviv-5, Ukraine</mods:affiliation></affiliation></author><author><name sortKey="Aksel Rud, L G" sort="Aksel Rud, L G" uniqKey="Aksel Rud L" first="L. G." last="Aksel'Rud">L. G. Aksel'Rud</name><affiliation><mods:affiliation>Institute of Chemistry, L'viv State University, Kyryla and Mefodiya Str. 6, Lviv-5, Ukraine</mods:affiliation></affiliation></author><author><name sortKey="Kuz Ma, Yu B" sort="Kuz Ma, Yu B" uniqKey="Kuz Ma Y" first="Yu. B." last="Kuz'Ma">Yu. B. Kuz'Ma</name><affiliation><mods:affiliation>Institute of Chemistry, L'viv State University, Kyryla and Mefodiya Str. 6, Lviv-5, Ukraine</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Journal of Alloys and Compounds</title><title level="j" type="abbrev">JALCOM</title><idno type="ISSN">0925-8388</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1996">1996</date><biblScope unit="volume">234</biblScope><biblScope unit="issue">2</biblScope><biblScope unit="page" from="167">167</biblScope><biblScope unit="page" to="170">170</biblScope></imprint><idno type="ISSN">0925-8388</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0925-8388</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aluminium</term><term>Aluminium atoms</term><term>Approximate composition</term><term>Atomic radii</term><term>Chemical formula</term><term>Coordination polyhedra</term><term>Crystal structure</term><term>Icosahedral coordination</term><term>Single crystal</term><term>Single crystals</term><term>Smallest atoms</term><term>Space group</term><term>Structure group</term><term>Structure types</term><term>Ternary systems</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Aluminium</term><term>Aluminium atoms</term><term>Approximate composition</term><term>Atomic radii</term><term>Chemical formula</term><term>Coordination polyhedra</term><term>Crystal structure</term><term>Icosahedral coordination</term><term>Single crystal</term><term>Single crystals</term><term>Smallest atoms</term><term>Space group</term><term>Structure group</term><term>Structure types</term><term>Ternary systems</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: The crystal structure of the new compound Tb2(Cu0.47Al0.53)17 with Th2Zn17-type structure (space group R3m, a = 8.767(3), c = 12.824(3)Å) has been determined using single crystal X-ray diffraction leading to R = 0.036 for 407 independent Fhkl values. The crystal structure of Tb(Cu0.58Al0.42)11 has been established from X-ray powder data with atomic parameter refinement by the Rietveld method (space group Fddd, a = 14.2792(6), b = 14.8916(6), c = 6.5644(3)Å). Both structures are characterized by an icosahedral coordination of the smallest atoms.</div></front></TEI><istex><corpusName>elsevier</corpusName><keywords><teeft><json:string>aluminium</json:string><json:string>crystal structure</json:string><json:string>single crystal</json:string><json:string>aluminium atoms</json:string><json:string>single crystals</json:string><json:string>approximate composition</json:string><json:string>icosahedral coordination</json:string><json:string>space group</json:string><json:string>smallest atoms</json:string><json:string>chemical formula</json:string><json:string>atomic radii</json:string><json:string>ternary systems</json:string><json:string>coordination polyhedra</json:string><json:string>structure group</json:string><json:string>structure types</json:string></teeft></keywords><author><json:item><name>B.M. Stel'makhovych</name><affiliations><json:string>Institute of Chemistry, L'viv State University, Kyryla and Mefodiya Str. 6, Lviv-5, Ukraine</json:string></affiliations></json:item><json:item><name>L.G. Aksel'rud</name><affiliations><json:string>Institute of Chemistry, L'viv State University, Kyryla and Mefodiya Str. 6, Lviv-5, Ukraine</json:string></affiliations></json:item><json:item><name>Yu.B. Kuz'ma</name><affiliations><json:string>Institute of Chemistry, L'viv State University, Kyryla and Mefodiya Str. 6, Lviv-5, Ukraine</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>TbCuAl compounds</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Single crystals</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Crystal structure</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Site preference</value></json:item></subject><language><json:string>eng</json:string></language><originalGenre><json:string>Full-length article</json:string></originalGenre><abstract>The crystal structure of the new compound Tb2(Cu0.47Al0.53)17 with Th2Zn17-type structure (space group R3m, a = 8.767(3), c = 12.824(3)Å) has been determined using single crystal X-ray diffraction leading to R = 0.036 for 407 independent Fhkl values. The crystal structure of Tb(Cu0.58Al0.42)11 has been established from X-ray powder data with atomic parameter refinement by the Rietveld method (space group Fddd, a = 14.2792(6), b = 14.8916(6), c = 6.5644(3)Å). Both structures are characterized by an icosahedral coordination of the smallest atoms.</abstract><qualityIndicators><score>3.465</score><pdfVersion>1.2</pdfVersion><pdfPageSize>591 x 807 pts</pdfPageSize><refBibsNative>true</refBibsNative><keywordCount>4</keywordCount><abstractCharCount>550</abstractCharCount><pdfWordCount>2481</pdfWordCount><pdfCharCount>10161</pdfCharCount><pdfPageCount>4</pdfPageCount><abstractWordCount>82</abstractWordCount></qualityIndicators><title>The Tb2(Cu0.47Al0.53)17 and Tb(Cu0.58Al0.42)11 aluminides and their crystal structures</title><pii><json:string>0925-8388(95)01944-8</json:string></pii><genre><json:string>research-article</json:string></genre><serie><title>Collected Abstracts of XII European Crystallographic Meet. 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The crystal structure of Tb(Cu0.58Al0.42)11 has been established from X-ray powder data with atomic parameter refinement by the Rietveld method (space group Fddd, a = 14.2792(6), b = 14.8916(6), c = 6.5644(3)Å). Both structures are characterized by an icosahedral coordination of the smallest atoms.</p></abstract><textClass><keywords scheme="keyword"><list><head>Keywords</head><item><term>TbCuAl compounds</term></item><item><term>Single crystals</term></item><item><term>Crystal structure</term></item><item><term>Site preference</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="1996">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/009C764F22F37D26F16CF5C5A6C5475C36DB0577/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: tail"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="fla"><item-info><jid>JALCOM</jid><aid>95019448</aid><ce:pii>0925-8388(95)01944-8</ce:pii><ce:doi>10.1016/0925-8388(95)01944-8</ce:doi><ce:copyright type="unknown" year="1996"></ce:copyright></item-info><head><ce:dochead><ce:textfn>Chemistry</ce:textfn></ce:dochead><ce:title>The Tb<ce:inf>2</ce:inf>(Cu<ce:inf>0.47</ce:inf>Al<ce:inf>0.53</ce:inf>)<ce:inf>17</ce:inf> and Tb(Cu<ce:inf>0.58</ce:inf>Al<ce:inf>0.42</ce:inf>)<ce:inf>11</ce:inf> aluminides and their crystal structures</ce:title><ce:author-group><ce:author><ce:given-name>B.M.</ce:given-name><ce:surname>Stel'makhovych</ce:surname></ce:author><ce:author><ce:given-name>L.G.</ce:given-name><ce:surname>Aksel'rud</ce:surname></ce:author><ce:author><ce:given-name>Yu.B.</ce:given-name><ce:surname>Kuz'ma</ce:surname></ce:author><ce:affiliation><ce:textfn>Institute of Chemistry, L'viv State University, Kyryla and Mefodiya Str. 6, Lviv-5, Ukraine</ce:textfn></ce:affiliation></ce:author-group><ce:date-received day="6" month="4" year="1995"></ce:date-received><ce:abstract><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para>The crystal structure of the new compound Tb<ce:inf>2</ce:inf>(Cu<ce:inf>0.47</ce:inf>Al<ce:inf>0.53</ce:inf>)<ce:inf>17</ce:inf> with Th<ce:inf>2</ce:inf>Zn<ce:inf>17</ce:inf>-type structure (space group <math altimg="si1.gif">R<ovl type="bar">3</ovl>m, a = 8.767(3)</math>, <ce:italic>c</ce:italic> = 12.824(3)Å) has been determined using single crystal X-ray diffraction leading to <ce:italic>R</ce:italic> = 0.036 for 407 independent <ce:italic>F</ce:italic><ce:inf><ce:italic>hkl</ce:italic></ce:inf> values. The crystal structure of Tb(Cu<ce:inf>0.58</ce:inf>Al<ce:inf>0.42</ce:inf>)<ce:inf>11</ce:inf> has been established from X-ray powder data with atomic parameter refinement by the Rietveld method (space group <ce:italic>Fddd</ce:italic>, <ce:italic>a</ce:italic> = 14.2792(6), <ce:italic>b</ce:italic> = 14.8916(6), <ce:italic>c</ce:italic> = 6.5644(3)Å). Both structures are characterized by an icosahedral coordination of the smallest atoms.</ce:simple-para></ce:abstract-sec></ce:abstract><ce:keywords><ce:section-title>Keywords</ce:section-title><ce:keyword><ce:text>TbCuAl compounds</ce:text></ce:keyword><ce:keyword><ce:text>Single crystals</ce:text></ce:keyword><ce:keyword><ce:text>Crystal structure</ce:text></ce:keyword><ce:keyword><ce:text>Site preference</ce:text></ce:keyword></ce:keywords></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo><title>The Tb2(Cu0.47Al0.53)17 and Tb(Cu0.58Al0.42)11 aluminides and their crystal structures</title></titleInfo><titleInfo type="alternative" contentType="CDATA"><title>The Tb</title></titleInfo><name type="personal"><namePart type="given">B.M.</namePart><namePart type="family">Stel'makhovych</namePart><affiliation>Institute of Chemistry, L'viv State University, Kyryla and Mefodiya Str. 6, Lviv-5, Ukraine</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">L.G.</namePart><namePart type="family">Aksel'rud</namePart><affiliation>Institute of Chemistry, L'viv State University, Kyryla and Mefodiya Str. 6, Lviv-5, Ukraine</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Yu.B.</namePart><namePart type="family">Kuz'ma</namePart><affiliation>Institute of Chemistry, L'viv State University, Kyryla and Mefodiya Str. 6, Lviv-5, Ukraine</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1996</dateIssued><copyrightDate encoding="w3cdtf">1996</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><abstract lang="en">Abstract: The crystal structure of the new compound Tb2(Cu0.47Al0.53)17 with Th2Zn17-type structure (space group R3m, a = 8.767(3), c = 12.824(3)Å) has been determined using single crystal X-ray diffraction leading to R = 0.036 for 407 independent Fhkl values. The crystal structure of Tb(Cu0.58Al0.42)11 has been established from X-ray powder data with atomic parameter refinement by the Rietveld method (space group Fddd, a = 14.2792(6), b = 14.8916(6), c = 6.5644(3)Å). Both structures are characterized by an icosahedral coordination of the smallest atoms.</abstract><note type="content">Section title: Chemistry</note><subject><genre>Keywords</genre><topic>TbCuAl compounds</topic><topic>Single crystals</topic><topic>Crystal structure</topic><topic>Site preference</topic></subject><relatedItem type="host"><titleInfo><title>Journal of Alloys and Compounds</title></titleInfo><titleInfo type="abbreviated"><title>JALCOM</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">19960215</dateIssued></originInfo><identifier type="ISSN">0925-8388</identifier><identifier type="PII">S0925-8388(00)X0030-8</identifier><part><date>19960215</date><detail type="volume"><number>234</number><caption>vol.</caption></detail><detail type="issue"><number>2</number><caption>no.</caption></detail><extent unit="issue-pages"><start>L1</start><end>L15</end></extent><extent unit="issue-pages"><start>167</start><end>307</end></extent><extent unit="pages"><start>167</start><end>170</end></extent></part></relatedItem><identifier type="istex">009C764F22F37D26F16CF5C5A6C5475C36DB0577</identifier><identifier type="ark">ark:/67375/6H6-8KKDFX09-M</identifier><identifier type="DOI">10.1016/0925-8388(95)01944-8</identifier><identifier type="PII">0925-8388(95)01944-8</identifier><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-HKKZVM7B-M">elsevier</recordContentSource></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/009C764F22F37D26F16CF5C5A6C5475C36DB0577/metadata/json</uri></json:item></metadata></istex></record>Pour manipuler ce document sous Unix (Dilib)
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