Excited-state dynamics of the Tm3+ ions and Tm3+ → Ho3+ energy transfers in LiYF4
Identifieur interne : 000021 ( Hal/Corpus ); précédent : 000020; suivant : 000022Excited-state dynamics of the Tm3+ ions and Tm3+ → Ho3+ energy transfers in LiYF4
Auteurs : A. Brenier ; J. Rubin ; R. Moncorge ; C. PedriniSource :
English descriptors
- mix :
Abstract
The excited-state dynamics of the Tm3+ ions in a singly doped crystal of LiYF4 is analysed. The Stokes fluorescence processes are interpreted by taking into account the numerous coincidences between the fluorescences emitted by the Tm3+ ions and by considering two kinds of sites. The anti-Stokes fluorescence dynamics which are more complicated are only briefly described. The Tm3+ → Ho3+ energy transfers are then analysed in codoped systems. Very efficient 3F 4 → 5I7 energy transfers are reported at room temperature whereas the 5I7 → 3F 4 back-transfer is completely quenched at low temperatures (T < 200 K ). When the Tm3+ ions are excited in their 3H 4 level, it is shown that three channels of de-excitation have to be considered : a Tm3+ intra-center de-excitation, a cross-relaxation process between adjacent Tm3+ ions of type 3H 4, 3H6 → 3F4, 3F4 and a direct Tm3+ → Ho3+ energy transfer. The former mechanism is very weak while the other two compete, the latter being largely dominant at high Ho3+ concentrations.
Url:
DOI: 10.1051/jphys:0198900500120146300
Links to Exploration step
Hal:jpa-00211009Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Excited-state dynamics of the Tm3+ ions and Tm3+ → Ho3+ energy transfers in LiYF4</title><author><name sortKey="Brenier, A" sort="Brenier, A" uniqKey="Brenier A" first="A." last="Brenier">A. Brenier</name></author><author><name sortKey="Rubin, J" sort="Rubin, J" uniqKey="Rubin J" first="J." last="Rubin">J. Rubin</name></author><author><name sortKey="Moncorge, R" sort="Moncorge, R" uniqKey="Moncorge R" first="R." last="Moncorge">R. Moncorge</name></author><author><name sortKey="Pedrini, C" sort="Pedrini, C" uniqKey="Pedrini C" first="C." last="Pedrini">C. Pedrini</name></author></titleStmt><publicationStmt><idno type="wicri:source">HAL</idno><idno type="RBID">Hal:jpa-00211009</idno><idno type="halId">jpa-00211009</idno><idno type="halUri">https://hal.archives-ouvertes.fr/jpa-00211009</idno><idno type="url">https://hal.archives-ouvertes.fr/jpa-00211009</idno><idno type="doi">10.1051/jphys:0198900500120146300</idno><date when="1989">1989</date><idno type="wicri:Area/Hal/Corpus">000021</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Excited-state dynamics of the Tm3+ ions and Tm3+ → Ho3+ energy transfers in LiYF4</title><author><name sortKey="Brenier, A" sort="Brenier, A" uniqKey="Brenier A" first="A." last="Brenier">A. Brenier</name></author><author><name sortKey="Rubin, J" sort="Rubin, J" uniqKey="Rubin J" first="J." last="Rubin">J. Rubin</name></author><author><name sortKey="Moncorge, R" sort="Moncorge, R" uniqKey="Moncorge R" first="R." last="Moncorge">R. Moncorge</name></author><author><name sortKey="Pedrini, C" sort="Pedrini, C" uniqKey="Pedrini C" first="C." last="Pedrini">C. Pedrini</name></author></analytic><idno type="DOI">10.1051/jphys:0198900500120146300</idno></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="mix" xml:lang="en"><term>fluorescence</term><term>holmium</term><term>lithium compounds</term><term>luminescence of inorganic solids</term><term>thulium</term><term>yttrium compounds</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The excited-state dynamics of the Tm3+ ions in a singly doped crystal of LiYF4 is analysed. The Stokes fluorescence processes are interpreted by taking into account the numerous coincidences between the fluorescences emitted by the Tm3+ ions and by considering two kinds of sites. The anti-Stokes fluorescence dynamics which are more complicated are only briefly described. The Tm3+ → Ho3+ energy transfers are then analysed in codoped systems. Very efficient 3F 4 → 5I7 energy transfers are reported at room temperature whereas the 5I7 → 3F 4 back-transfer is completely quenched at low temperatures (T < 200 K ). When the Tm3+ ions are excited in their 3H 4 level, it is shown that three channels of de-excitation have to be considered : a Tm3+ intra-center de-excitation, a cross-relaxation process between adjacent Tm3+ ions of type 3H 4, 3H6 → 3F4, 3F4 and a direct Tm3+ → Ho3+ energy transfer. The former mechanism is very weak while the other two compete, the latter being largely dominant at high Ho3+ concentrations.</div></front></TEI><hal api="V3"><titleStmt><title xml:lang="en">Excited-state dynamics of the Tm3+ ions and Tm3+ → Ho3+ energy transfers in LiYF4</title><author role="aut"><persName><forename type="first">A.</forename><surname>Brenier</surname></persName><email></email><idno type="halauthor">132967</idno></author><author role="aut"><persName><forename type="first">J.</forename><surname>Rubin</surname></persName><email></email><idno type="idhal">jacques-rubin</idno><idno type="halauthor">1089562</idno></author><author role="aut"><persName><forename type="first">R.</forename><surname>Moncorge</surname></persName><email></email><idno type="halauthor">55554</idno></author><author role="aut"><persName><forename type="first">C.</forename><surname>Pedrini</surname></persName><email></email><idno type="halauthor">12871</idno></author><editor role="depositor"><persName><forename>Archives</forename><surname>Journal de Physique</surname></persName><email>ccsd-tech@ccsd.cnrs.fr</email></editor></titleStmt><editionStmt><edition n="v1" type="current"><date type="whenSubmitted">1989-01-01 08:00:00</date><date type="whenWritten">1989</date><date type="whenModified">1989-01-01 08:00:00</date><date type="whenReleased">1989-01-01 08:00:00</date><date type="whenProduced">1989</date><date type="whenEndEmbargoed">1989-01-01</date><ref type="file" target="https://hal.archives-ouvertes.fr/jpa-00211009/document"><date notBefore="1989-01-01"></date></ref><ref type="file" subtype="publisherAgreement" n="1" target="https://hal.archives-ouvertes.fr/jpa-00211009/file/ajp-jphys_1989_50_12_1463_0.pdf"><date notBefore="1989-01-01"></date></ref></edition><respStmt><resp>contributor</resp><name key="122646"><persName><forename>Archives</forename><surname>Journal de Physique</surname></persName><email>ccsd-tech@ccsd.cnrs.fr</email></name></respStmt></editionStmt><publicationStmt><distributor>CCSD</distributor><idno type="halId">jpa-00211009</idno><idno type="halUri">https://hal.archives-ouvertes.fr/jpa-00211009</idno><idno type="halBibtex">brenier:jpa-00211009</idno><idno type="halRefHtml">Journal de Physique, 1989, 50 (12), pp.1463-1482. <10.1051/jphys:0198900500120146300></idno><idno type="halRef">Journal de Physique, 1989, 50 (12), pp.1463-1482. <10.1051/jphys:0198900500120146300></idno></publicationStmt><seriesStmt><idno type="stamp" n="AJP">Archive du Journal de Physique</idno></seriesStmt><notesStmt><note type="audience" n="1">Not set</note><note type="popular" n="0">No</note><note type="peer" n="1">Yes</note></notesStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Excited-state dynamics of the Tm3+ ions and Tm3+ → Ho3+ energy transfers in LiYF4</title><author role="aut"><persName><forename type="first">A.</forename><surname>Brenier</surname></persName><idno type="halAuthorId">132967</idno></author><author role="aut"><persName><forename type="first">J.</forename><surname>Rubin</surname></persName><idno type="idHal">jacques-rubin</idno><idno type="halAuthorId">1089562</idno></author><author role="aut"><persName><forename type="first">R.</forename><surname>Moncorge</surname></persName><idno type="halAuthorId">55554</idno></author><author role="aut"><persName><forename type="first">C.</forename><surname>Pedrini</surname></persName><idno type="halAuthorId">12871</idno></author></analytic><monogr><idno type="halJournalId" status="VALID">20197</idno><title level="j">Journal de Physique</title><imprint><biblScope unit="volume">50</biblScope><biblScope unit="issue">12</biblScope><biblScope unit="pp">1463-1482</biblScope><date type="datePub">1989</date></imprint></monogr><idno type="doi">10.1051/jphys:0198900500120146300</idno></biblStruct></sourceDesc><profileDesc><langUsage><language ident="en">English</language></langUsage><textClass><keywords scheme="author"><term xml:lang="en">fluorescence</term><term xml:lang="en">holmium</term><term xml:lang="en">lithium compounds</term><term xml:lang="en">luminescence of inorganic solids</term><term xml:lang="en">thulium</term><term xml:lang="en">yttrium compounds</term></keywords><classCode scheme="halDomain" n="phys.hist">Physics [physics]/Physics archives</classCode><classCode scheme="halTypology" n="ART">Journal articles</classCode></textClass><abstract xml:lang="en">The excited-state dynamics of the Tm3+ ions in a singly doped crystal of LiYF4 is analysed. The Stokes fluorescence processes are interpreted by taking into account the numerous coincidences between the fluorescences emitted by the Tm3+ ions and by considering two kinds of sites. The anti-Stokes fluorescence dynamics which are more complicated are only briefly described. The Tm3+ → Ho3+ energy transfers are then analysed in codoped systems. Very efficient 3F 4 → 5I7 energy transfers are reported at room temperature whereas the 5I7 → 3F 4 back-transfer is completely quenched at low temperatures (T < 200 K ). When the Tm3+ ions are excited in their 3H 4 level, it is shown that three channels of de-excitation have to be considered : a Tm3+ intra-center de-excitation, a cross-relaxation process between adjacent Tm3+ ions of type 3H 4, 3H6 → 3F4, 3F4 and a direct Tm3+ → Ho3+ energy transfer. The former mechanism is very weak while the other two compete, the latter being largely dominant at high Ho3+ concentrations.</abstract></profileDesc></hal></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/ThuliumV1/Data/Hal/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000021 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Hal/Corpus/biblio.hfd -nk 000021 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Terre
|area= ThuliumV1
|flux= Hal
|étape= Corpus
|type= RBID
|clé= Hal:jpa-00211009
|texte= Excited-state dynamics of the Tm3+ ions and Tm3+ → Ho3+ energy transfers in LiYF4
}}
| This area was generated with Dilib version V0.6.21. |  |