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Bright Red Upconversion Luminescence of Thulium Ion-Doped GeS2−In2S3−CsI Glasses

Identifieur interne : 000009 ( Hal/Corpus ); précédent : 000008; suivant : 000010

Bright Red Upconversion Luminescence of Thulium Ion-Doped GeS2−In2S3−CsI Glasses

Auteurs : Yinsheng Xu ; Danping Chen ; Qiang Zhang ; Huidan Zeng ; Ce Shen ; Jean-Luc Adam ; Xianghua Zhang ; Guorong Chen

Source :

RBID : Hal:hal-00411488

Abstract

In this paper, we report a novel phenomenon in GeS2−In2S3−CsI chalcohalide glasses doped with Tm3+ ions. Under irradiation with an 808 nm laser diode, a bright red emission centered at 700 nm is observed for the first time. By codoping with different concentration of Er3+ ions, emission can be tuned from monochromatic red to green. The Er3+ ions codopant and higher concentration of Tm3+ ions are favoring the 700 nm red emission. Meanwhile, the indium (In) contents plays a significant role on the enhanced upconversion and near-IR emissions. These observations are interesting and may enable the device based on the chalcohalide glass to meet the specific color demands, which have potential applications in the fields of optical and solid state lasers.

Url:
DOI: 10.1021/jp9010857

Links to Exploration step

Hal:hal-00411488

Le document en format XML

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<div type="abstract" xml:lang="en">In this paper, we report a novel phenomenon in GeS2−In2S3−CsI chalcohalide glasses doped with Tm3+ ions. Under irradiation with an 808 nm laser diode, a bright red emission centered at 700 nm is observed for the first time. By codoping with different concentration of Er3+ ions, emission can be tuned from monochromatic red to green. The Er3+ ions codopant and higher concentration of Tm3+ ions are favoring the 700 nm red emission. Meanwhile, the indium (In) contents plays a significant role on the enhanced upconversion and near-IR emissions. These observations are interesting and may enable the device based on the chalcohalide glass to meet the specific color demands, which have potential applications in the fields of optical and solid state lasers.</div>
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<funder>National Natural Science Foundation of China (NSFC 60578042, 50702021); Shanghai Leading Academic Discipline Project, Project No. B502.</funder>
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<date type="whenSubmitted">2009-08-27 16:39:55</date>
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<idno type="stamp" n="UNIV-RENNES1">Université de Rennes 1</idno>
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<idno type="stamp" n="UR1-SPM">Université de Rennes 1 - UFR Sciences et Propriétés de la Matière</idno>
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<title xml:lang="en">Bright Red Upconversion Luminescence of Thulium Ion-Doped GeS2−In2S3−CsI Glasses</title>
<author role="aut">
<persName>
<forename type="first">Yinsheng</forename>
<surname>Xu</surname>
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<author role="crp">
<persName>
<forename type="first">Danping</forename>
<surname>Chen</surname>
</persName>
<email>d-chen@mail.siom.ac.cn</email>
<idno type="halAuthorId">887248</idno>
</author>
<author role="aut">
<persName>
<forename type="first">Qiang</forename>
<surname>Zhang</surname>
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<author role="aut">
<persName>
<forename type="first">Huidan</forename>
<surname>Zeng</surname>
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<author role="aut">
<persName>
<forename type="first">Ce</forename>
<surname>Shen</surname>
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<idno type="halAuthorId">887250</idno>
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<author role="aut">
<persName>
<forename type="first">Jean-Luc</forename>
<surname>Adam</surname>
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<email>jean-luc.adam@univ-rennes1.fr</email>
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<author role="aut">
<persName>
<forename type="first">Xianghua</forename>
<surname>Zhang</surname>
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<author role="aut">
<persName>
<forename type="first">Guorong</forename>
<surname>Chen</surname>
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<idno type="halAuthorId">880832</idno>
<affiliation ref="#struct-245276"></affiliation>
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<idno type="issn">1932-7447</idno>
<idno type="eissn">1932-7455</idno>
<title level="j">Journal of Physical Chemistry C</title>
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<publisher>American Chemical Society</publisher>
<biblScope unit="volume">113</biblScope>
<biblScope unit="issue">22</biblScope>
<biblScope unit="pp">9911-9915</biblScope>
<date type="datePub">2009-06-04</date>
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<abstract xml:lang="en">In this paper, we report a novel phenomenon in GeS2−In2S3−CsI chalcohalide glasses doped with Tm3+ ions. Under irradiation with an 808 nm laser diode, a bright red emission centered at 700 nm is observed for the first time. By codoping with different concentration of Er3+ ions, emission can be tuned from monochromatic red to green. The Er3+ ions codopant and higher concentration of Tm3+ ions are favoring the 700 nm red emission. Meanwhile, the indium (In) contents plays a significant role on the enhanced upconversion and near-IR emissions. These observations are interesting and may enable the device based on the chalcohalide glass to meet the specific color demands, which have potential applications in the fields of optical and solid state lasers.</abstract>
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