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Volatile organic compounds (VOCs) in air from Nisyros Island (Dodecanese Archipelago, Greece): Natural versus anthropogenic sources

Identifieur interne : 000039 ( PascalFrancis/Curation ); précédent : 000038; suivant : 000040

Volatile organic compounds (VOCs) in air from Nisyros Island (Dodecanese Archipelago, Greece): Natural versus anthropogenic sources

Auteurs : F. Tassi [Italie] ; F. Capecchiacci [Italie] ; L. Giannini [Italie] ; G. E. Vougioukalakis [Grèce] ; O. Vaselli [Italie]

Source :

RBID : Pascal:13-0260601

Descripteurs français

English descriptors

Abstract

This study presents the chemical composition of VOCs in air and gas discharges collected at Nisyros Island (Dodecanese Archipelago, Greece). The main goals are i) to discriminate between natural and anthropogenic VOC sources and ii) to evaluate their impact on local air quality. Up to 63 different VOCs were recognized and quantitatively determined in 6 fumaroles and 19 air samples collected in the Lakki caldera, where fumarolic emissions are located, and the outer ring of the island, including the Mandraki village and the main harbor. Air samples from the crater area show significant concentrations of alkanes, alkenes, cyclic, aromatics, and S- and O-bearing heterocycles directly deriving from the hydrothermal system, as well as secondary O-bearing compounds from oxidation of primary VOCs. At Mandraki village, C6H6/Σ(methylated aromatics) and Σ(linear)/Σ(branched) alkanes ratios <1 allow to distinguish an anthropogenic source related to emissions from outlet pipes of touristic and private boats and buses.
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A11 01  1    @1 TASSI (F.)
A11 02  1    @1 CAPECCHIACCI (F.)
A11 03  1    @1 GIANNINI (L.)
A11 04  1    @1 VOUGIOUKALAKIS (G. E.)
A11 05  1    @1 VASELLI (O.)
A14 01      @1 Department of Earth Sciences, University of Florence, Via La Pira 4 @2 50121 Florence @3 ITA @Z 1 aut. @Z 3 aut. @Z 5 aut.
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A14 03      @1 IGME Institute for Geology and Mineral Exploration, 3rd Exit Olympic Village, 13677, Aharne @2 Athens @3 GRC @Z 4 aut.
A20       @1 111-121
A21       @1 2013
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A44       @0 0000 @1 © 2013 INIST-CNRS. All rights reserved.
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A60       @1 P
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C01 01    ENG  @0 This study presents the chemical composition of VOCs in air and gas discharges collected at Nisyros Island (Dodecanese Archipelago, Greece). The main goals are i) to discriminate between natural and anthropogenic VOC sources and ii) to evaluate their impact on local air quality. Up to 63 different VOCs were recognized and quantitatively determined in 6 fumaroles and 19 air samples collected in the Lakki caldera, where fumarolic emissions are located, and the outer ring of the island, including the Mandraki village and the main harbor. Air samples from the crater area show significant concentrations of alkanes, alkenes, cyclic, aromatics, and S- and O-bearing heterocycles directly deriving from the hydrothermal system, as well as secondary O-bearing compounds from oxidation of primary VOCs. At Mandraki village, C6H6/Σ(methylated aromatics) and Σ(linear)/Σ(branched) alkanes ratios <1 allow to distinguish an anthropogenic source related to emissions from outlet pipes of touristic and private boats and buses.
C02 01  X    @0 001D16C04D
C03 01  X  FRE  @0 Composé organique volatil @5 01
C03 01  X  ENG  @0 Volatile organic compound @5 01
C03 01  X  SPA  @0 Compuesto orgánico volátil @5 01
C03 02  X  FRE  @0 Air @5 02
C03 02  X  ENG  @0 Air @5 02
C03 02  X  SPA  @0 Aire @5 02
C03 03  X  FRE  @0 Grèce @2 NG @5 03
C03 03  X  ENG  @0 Greece @2 NG @5 03
C03 03  X  SPA  @0 Grecia @2 NG @5 03
C03 04  X  FRE  @0 Facteur anthropique @5 04
C03 04  X  ENG  @0 Anthropogenic factor @5 04
C03 04  X  SPA  @0 Factor antrópico @5 04
C03 05  X  FRE  @0 Qualité air @5 05
C03 05  X  ENG  @0 Air quality @5 05
C03 05  X  SPA  @0 Calidad aire @5 05
C03 06  X  FRE  @0 Pollution air @5 06
C03 06  X  ENG  @0 Air pollution @5 06
C03 06  X  SPA  @0 Contaminación aire @5 06
C03 07  X  FRE  @0 Pollution origine naturelle @5 07
C03 07  X  ENG  @0 Natural origin pollution @5 07
C03 07  X  SPA  @0 Polución origen natural @5 07
C03 08  3  FRE  @0 Fumerolle @5 08
C03 08  3  ENG  @0 Fumaroles @5 08
C03 09  X  FRE  @0 Iles Dodécanèse @4 INC @5 76
C07 01  X  FRE  @0 Europe @2 NG
C07 01  X  ENG  @0 Europe @2 NG
C07 01  X  SPA  @0 Europa @2 NG
N21       @1 252

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Pascal:13-0260601

Le document en format XML

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<div type="abstract" xml:lang="en">This study presents the chemical composition of VOCs in air and gas discharges collected at Nisyros Island (Dodecanese Archipelago, Greece). The main goals are i) to discriminate between natural and anthropogenic VOC sources and ii) to evaluate their impact on local air quality. Up to 63 different VOCs were recognized and quantitatively determined in 6 fumaroles and 19 air samples collected in the Lakki caldera, where fumarolic emissions are located, and the outer ring of the island, including the Mandraki village and the main harbor. Air samples from the crater area show significant concentrations of alkanes, alkenes, cyclic, aromatics, and S- and O-bearing heterocycles directly deriving from the hydrothermal system, as well as secondary O-bearing compounds from oxidation of primary VOCs. At Mandraki village, C
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<fC03 i1="05" i2="X" l="FRE">
<s0>Qualité air</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG">
<s0>Air quality</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA">
<s0>Calidad aire</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Pollution air</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Air pollution</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Contaminación aire</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Pollution origine naturelle</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Natural origin pollution</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Polución origen natural</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Fumerolle</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>Fumaroles</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Iles Dodécanèse</s0>
<s4>INC</s4>
<s5>76</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE">
<s0>Europe</s0>
<s2>NG</s2>
</fC07>
<fC07 i1="01" i2="X" l="ENG">
<s0>Europe</s0>
<s2>NG</s2>
</fC07>
<fC07 i1="01" i2="X" l="SPA">
<s0>Europa</s0>
<s2>NG</s2>
</fC07>
<fN21>
<s1>252</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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   |texte=   Volatile organic compounds (VOCs) in air from Nisyros Island (Dodecanese Archipelago, Greece): Natural versus anthropogenic sources
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