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ABIOTIC METHANE ON EARTH

Identifieur interne : 000568 ( Istex/Corpus ); précédent : 000567; suivant : 000569

ABIOTIC METHANE ON EARTH

Auteurs : Giuseppe Etiope ; Barbara Sherwood Lollar

Source :

RBID : ISTEX:A1F0AE4F9BA78C1A1D9103A4DFDD6E01D327488C

English descriptors

Abstract

Over the last 30 years, geochemical research has demonstrated that abiotic methane (CH4), formed by chemical reactions which do not directly involve organic matter, occurs on Earth in several specific geologic environments. It can be produced by either high‐temperature magmatic processes in volcanic and geothermal areas, or via low‐temperature (<100°C) gas‐water‐rock reactions in continental settings, even at shallow depths. The isotopic composition of C and H is a first step in distinguishing abiotic from biotic (including either microbial or thermogenic) CH4. Herein we demonstrate that integrated geochemical diagnostic techniques, based on molecular composition of associated gases, noble gas isotopes, mixing models, and a detailed knowledge of the geologic and hydrogeologic context are necessary to confirm the occurrence of abiotic CH4 in natural gases, which are frequently mixtures of multiple sources. Although it has been traditionally assumed that abiotic CH4 is mainly related to mantle‐derived or magmatic processes, a new generation of data is showing that low‐temperature synthesis related to gas‐water‐rock reactions is more common than previously thought. This paper reviews the major sources of abiotic CH4 and the primary approaches for differentiating abiotic from biotic CH4, including novel potential tools such as clumped isotope geochemistry. A diagnostic approach for differentiation is proposed.
Abiotic CH4 occurs in specific geologic areas under a wide range of temperature Updated global CH4 isotopic diagram is provided Integration of geochemical‐geological data necessary to determine abiotic origin

Url:
DOI: 10.1002/rog.20011

Links to Exploration step

ISTEX:A1F0AE4F9BA78C1A1D9103A4DFDD6E01D327488C

Le document en format XML

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<div type="abstract">Over the last 30 years, geochemical research has demonstrated that abiotic methane (CH4), formed by chemical reactions which do not directly involve organic matter, occurs on Earth in several specific geologic environments. It can be produced by either high‐temperature magmatic processes in volcanic and geothermal areas, or via low‐temperature (<100°C) gas‐water‐rock reactions in continental settings, even at shallow depths. The isotopic composition of C and H is a first step in distinguishing abiotic from biotic (including either microbial or thermogenic) CH4. Herein we demonstrate that integrated geochemical diagnostic techniques, based on molecular composition of associated gases, noble gas isotopes, mixing models, and a detailed knowledge of the geologic and hydrogeologic context are necessary to confirm the occurrence of abiotic CH4 in natural gases, which are frequently mixtures of multiple sources. Although it has been traditionally assumed that abiotic CH4 is mainly related to mantle‐derived or magmatic processes, a new generation of data is showing that low‐temperature synthesis related to gas‐water‐rock reactions is more common than previously thought. This paper reviews the major sources of abiotic CH4 and the primary approaches for differentiating abiotic from biotic CH4, including novel potential tools such as clumped isotope geochemistry. A diagnostic approach for differentiation is proposed.</div>
<div type="abstract">Abiotic CH4 occurs in specific geologic areas under a wide range of temperature Updated global CH4 isotopic diagram is provided Integration of geochemical‐geological data necessary to determine abiotic origin</div>
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<abstract>Over the last 30 years, geochemical research has demonstrated that abiotic methane (CH4), formed by chemical reactions which do not directly involve organic matter, occurs on Earth in several specific geologic environments. It can be produced by either high‐temperature magmatic processes in volcanic and geothermal areas, or via low‐temperature (<100°C) gas‐water‐rock reactions in continental settings, even at shallow depths. The isotopic composition of C and H is a first step in distinguishing abiotic from biotic (including either microbial or thermogenic) CH4. Herein we demonstrate that integrated geochemical diagnostic techniques, based on molecular composition of associated gases, noble gas isotopes, mixing models, and a detailed knowledge of the geologic and hydrogeologic context are necessary to confirm the occurrence of abiotic CH4 in natural gases, which are frequently mixtures of multiple sources. Although it has been traditionally assumed that abiotic CH4 is mainly related to mantle‐derived or magmatic processes, a new generation of data is showing that low‐temperature synthesis related to gas‐water‐rock reactions is more common than previously thought. This paper reviews the major sources of abiotic CH4 and the primary approaches for differentiating abiotic from biotic CH4, including novel potential tools such as clumped isotope geochemistry. A diagnostic approach for differentiation is proposed.</abstract>
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