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Isotope Geochemistry of the Pb‐Zn‐Ba(‐Ag‐Au) Mineralization at Triades‐Galana, Milos Island, Greece

Identifieur interne : 000153 ( Istex/Corpus ); précédent : 000152; suivant : 000154

Isotope Geochemistry of the Pb‐Zn‐Ba(‐Ag‐Au) Mineralization at Triades‐Galana, Milos Island, Greece

Auteurs : Robert Marschik ; Tobias Bauer ; Ana-Sophie Hensler ; Nikos Skarpelis ; Stefan Hölzl

Source :

RBID : ISTEX:53AA336A54BE355F90B11CBA34F752D12CB506E5

English descriptors

Abstract

The Pb‐Zn‐Ba(‐Ag‐Au) mineralization in the Triades and Galana mine areas is hosted in 2.5–1.4 Ma pyroclastic rocks, and structurally controlled mostly by NE‐SW or N‐S trending brittle faults. Proximal pervasive silica and distal pervasive sericite‐illite alteration are the two main alteration types present at the surface. The distribution of mineralization‐alteration in the district suggests at least two hydrothermal events or that hydrothermal activity lasted longer at Galana. The Sr isotope signature of sphalerite and barite (87Sr/86Sr = 0.709162 to 0.710214) and calculated oxygen isotope composition of a fluid in equilibrium with barite and associated quartz at temperatures of around 230°C are suggestive of a seawater hydrothermal system and fluid/rock interaction. Lead isotope ratios of galena and sphalerite (206Pb/204Pb from 18.8384 to 18.8711; 207Pb/204Pb from 15.6695 to 15.6976; 208Pb/204Pb from 38.9158 to 39.0161) are similar to those of South Aegean Arc volcanic and Aegean Miocene plutonic rocks, and compatible with Pb derived from an igneous source. Galena and sphalerite from Triades‐Galana have δ34SVCDT values ranging from +1 to +3.6‰, whereas barite sulfate shows δ34SVCDT values from +22.8 to +24.4‰. The sulfur isotope signatures of these minerals are explained by seawater sulfate reduction processes. The new analytical data are consistent with a seawater‐dominated hydrothermal system and interaction of the hydrothermal fluid with the country rocks, which are the source of the ore metals.

Url:
DOI: 10.1111/j.1751-3928.2010.00139.x

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ISTEX:53AA336A54BE355F90B11CBA34F752D12CB506E5

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<div type="abstract" xml:lang="en">The Pb‐Zn‐Ba(‐Ag‐Au) mineralization in the Triades and Galana mine areas is hosted in 2.5–1.4 Ma pyroclastic rocks, and structurally controlled mostly by NE‐SW or N‐S trending brittle faults. Proximal pervasive silica and distal pervasive sericite‐illite alteration are the two main alteration types present at the surface. The distribution of mineralization‐alteration in the district suggests at least two hydrothermal events or that hydrothermal activity lasted longer at Galana. The Sr isotope signature of sphalerite and barite (87Sr/86Sr = 0.709162 to 0.710214) and calculated oxygen isotope composition of a fluid in equilibrium with barite and associated quartz at temperatures of around 230°C are suggestive of a seawater hydrothermal system and fluid/rock interaction. Lead isotope ratios of galena and sphalerite (206Pb/204Pb from 18.8384 to 18.8711; 207Pb/204Pb from 15.6695 to 15.6976; 208Pb/204Pb from 38.9158 to 39.0161) are similar to those of South Aegean Arc volcanic and Aegean Miocene plutonic rocks, and compatible with Pb derived from an igneous source. Galena and sphalerite from Triades‐Galana have δ34SVCDT values ranging from +1 to +3.6‰, whereas barite sulfate shows δ34SVCDT values from +22.8 to +24.4‰. The sulfur isotope signatures of these minerals are explained by seawater sulfate reduction processes. The new analytical data are consistent with a seawater‐dominated hydrothermal system and interaction of the hydrothermal fluid with the country rocks, which are the source of the ore metals.</div>
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<p>The Pb‐Zn‐Ba(‐Ag‐Au) mineralization in the Triades and Galana mine areas is hosted in 2.5–1.4 Ma pyroclastic rocks, and structurally controlled mostly by NE‐SW or N‐S trending brittle faults. Proximal pervasive silica and distal pervasive sericite‐illite alteration are the two main alteration types present at the surface. The distribution of mineralization‐alteration in the district suggests at least two hydrothermal events or that hydrothermal activity lasted longer at Galana. The Sr isotope signature of sphalerite and barite (
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<hi rend="superscript">206</hi>
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<hi rend="superscript">204</hi>
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<hi rend="superscript">207</hi>
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Pb/
<hi rend="superscript">204</hi>
Pb from 38.9158 to 39.0161) are similar to those of South Aegean Arc volcanic and Aegean Miocene plutonic rocks, and compatible with Pb derived from an igneous source. Galena and sphalerite from Triades‐Galana have δ
<hi rend="superscript">34</hi>
S
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<p>The Pb‐Zn‐Ba(‐Ag‐Au) mineralization in the Triades and Galana mine areas is hosted in 2.5–1.4 Ma pyroclastic rocks, and structurally controlled mostly by NE‐SW or N‐S trending brittle faults. Proximal pervasive silica and distal pervasive sericite‐illite alteration are the two main alteration types present at the surface. The distribution of mineralization‐alteration in the district suggests at least two hydrothermal events or that hydrothermal activity lasted longer at Galana. The Sr isotope signature of sphalerite and barite (
<sup>87</sup>
Sr/
<sup>86</sup>
Sr = 0.709162 to 0.710214) and calculated oxygen isotope composition of a fluid in equilibrium with barite and associated quartz at temperatures of around 230°C are suggestive of a seawater hydrothermal system and fluid/rock interaction. Lead isotope ratios of galena and sphalerite (
<sup>206</sup>
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Pb from 18.8384 to 18.8711;
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Pb/
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Pb/
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Pb from 38.9158 to 39.0161) are similar to those of South Aegean Arc volcanic and Aegean Miocene plutonic rocks, and compatible with Pb derived from an igneous source. Galena and sphalerite from Triades‐Galana have δ
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S
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S
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<abstract lang="en">The Pb‐Zn‐Ba(‐Ag‐Au) mineralization in the Triades and Galana mine areas is hosted in 2.5–1.4 Ma pyroclastic rocks, and structurally controlled mostly by NE‐SW or N‐S trending brittle faults. Proximal pervasive silica and distal pervasive sericite‐illite alteration are the two main alteration types present at the surface. The distribution of mineralization‐alteration in the district suggests at least two hydrothermal events or that hydrothermal activity lasted longer at Galana. The Sr isotope signature of sphalerite and barite (87Sr/86Sr = 0.709162 to 0.710214) and calculated oxygen isotope composition of a fluid in equilibrium with barite and associated quartz at temperatures of around 230°C are suggestive of a seawater hydrothermal system and fluid/rock interaction. Lead isotope ratios of galena and sphalerite (206Pb/204Pb from 18.8384 to 18.8711; 207Pb/204Pb from 15.6695 to 15.6976; 208Pb/204Pb from 38.9158 to 39.0161) are similar to those of South Aegean Arc volcanic and Aegean Miocene plutonic rocks, and compatible with Pb derived from an igneous source. Galena and sphalerite from Triades‐Galana have δ34SVCDT values ranging from +1 to +3.6‰, whereas barite sulfate shows δ34SVCDT values from +22.8 to +24.4‰. The sulfur isotope signatures of these minerals are explained by seawater sulfate reduction processes. The new analytical data are consistent with a seawater‐dominated hydrothermal system and interaction of the hydrothermal fluid with the country rocks, which are the source of the ore metals.</abstract>
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