Serveur d'exploration sur le nickel au Maghreb

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New composites of ZnO-P2O5/Ni having PTC transition and high Seebeck coefficient

Identifieur interne : 000372 ( PascalFrancis/Curation ); précédent : 000371; suivant : 000373

New composites of ZnO-P2O5/Ni having PTC transition and high Seebeck coefficient

Auteurs : A. Maaroufi [Maroc] ; O. Oabi [Maroc] ; B. Lucas [France] ; A. El Amrani [Maroc] ; S. Degot [France]

Source :

RBID : Pascal:13-0090410

Descripteurs français

English descriptors

Abstract

In this article, we report the electrical conductivity (σ) and Seebeck coefficient (S) of ZnO-P2O5 matrix filled with conductive powder of nickel (Ni). The variation of σ versus volume fraction of Ni showed a non-conducting to conducting phase transition at percolation threshold (28 vol. %). The change of S from high positive to negative values exhibits that this transition is accompanied by the passing of carrier charge from p to n type. On the other hand, the measurements of σ and S as function of temperature, above the percolation threshold, showed a positive temperature coefficient (PTC) phase transition at Tc≥400 K, linked with a high S = -5000 μV/K, giving highest power factor PF=σ.S2≃2.10-4 Wm-1 K-2. The temperature dependence of the volume expansion enabled to confirm that this transition is associated to the thermal volume variation in matrix. However, the temperature dependence of σ below the percolation threshold showed two different mechanisms: thermally activated hopping behavior at high temperatures and Mott's variable range hopping (VRH) at low temperatures.
pA  
A01 01  1    @0 0022-3093
A02 01      @0 JNCSBJ
A03   1    @0 J. non-cryst. solids
A05       @2 358
A06       @2 23
A08 01  1  ENG  @1 New composites of ZnO-P2O5/Ni having PTC transition and high Seebeck coefficient
A11 01  1    @1 MAAROUFI (A.)
A11 02  1    @1 OABI (O.)
A11 03  1    @1 LUCAS (B.)
A11 04  1    @1 EL AMRANI (A.)
A11 05  1    @1 DEGOT (S.)
A14 01      @1 University Mohammed VAgdal, Laboratory of Composite Materials, Polymers and Environment, Department of Chemistry, Faculty of Sciences P.B. 1014 @2 Rabat-Agdal @3 MAR @Z 1 aut. @Z 2 aut.
A14 02      @1 XLIM UMR 6172-Université de Limoges/CNRS 123 avenue Albert Thomas- @2 87060 Limoges @3 FRA @Z 3 aut.
A14 03      @1 LPSMS, FST Errachidia, University Moulay Ismail Meknès, B. P. 509, Boutalamine @2 , Errachidia @3 MAR @Z 4 aut.
A14 04      @1 SPCTS, CNRS UMR 6638, European Ceramic Center, 12, rue Atlantis @2 87068 Limoges @3 FRA @Z 5 aut.
A20       @1 3312-3317
A21       @1 2012
A23 01      @0 ENG
A43 01      @1 INIST @2 14572 @5 354000506890750400
A44       @0 0000 @1 © 2013 INIST-CNRS. All rights reserved.
A45       @0 46 ref.
A47 01  1    @0 13-0090410
A60       @1 P
A61       @0 A
A64 01  1    @0 Journal of non-crystalline solids
A66 01      @0 GBR
C01 01    ENG  @0 In this article, we report the electrical conductivity (σ) and Seebeck coefficient (S) of ZnO-P2O5 matrix filled with conductive powder of nickel (Ni). The variation of σ versus volume fraction of Ni showed a non-conducting to conducting phase transition at percolation threshold (28 vol. %). The change of S from high positive to negative values exhibits that this transition is accompanied by the passing of carrier charge from p to n type. On the other hand, the measurements of σ and S as function of temperature, above the percolation threshold, showed a positive temperature coefficient (PTC) phase transition at Tc≥400 K, linked with a high S = -5000 μV/K, giving highest power factor PF=σ.S2≃2.10-4 Wm-1 K-2. The temperature dependence of the volume expansion enabled to confirm that this transition is associated to the thermal volume variation in matrix. However, the temperature dependence of σ below the percolation threshold showed two different mechanisms: thermally activated hopping behavior at high temperatures and Mott's variable range hopping (VRH) at low temperatures.
C02 01  3    @0 001B70B20E
C02 02  3    @0 001B80A05K
C02 03  3    @0 001B70B80N
C03 01  3  FRE  @0 Effet Seebeck @5 01
C03 01  3  ENG  @0 Seebeck effect @5 01
C03 02  3  FRE  @0 Conductivité électrique @5 02
C03 02  3  ENG  @0 Electrical conductivity @5 02
C03 03  3  FRE  @0 Nickel @2 NC @5 03
C03 03  3  ENG  @0 Nickel @2 NC @5 03
C03 04  X  FRE  @0 Fraction volumique @5 04
C03 04  X  ENG  @0 Volume fraction @5 04
C03 04  X  SPA  @0 Fracción volumétrica @5 04
C03 05  X  FRE  @0 Transition phase @5 05
C03 05  X  ENG  @0 Phase transitions @5 05
C03 05  X  SPA  @0 Transición fase @5 05
C03 06  3  FRE  @0 Percolation @5 06
C03 06  3  ENG  @0 Percolation @5 06
C03 07  3  FRE  @0 Porteur charge @5 07
C03 07  3  ENG  @0 Charge carriers @5 07
C03 08  3  FRE  @0 Dépendance température @5 08
C03 08  3  ENG  @0 Temperature dependence @5 08
C03 09  3  FRE  @0 Coefficient température @5 09
C03 09  3  ENG  @0 Temperature coefficient @5 09
C03 10  X  FRE  @0 Expansion volume @5 10
C03 10  X  ENG  @0 Volume expansion @5 10
C03 10  X  SPA  @0 Expansión volumen @5 10
C03 11  3  FRE  @0 Energie activation @5 11
C03 11  3  ENG  @0 Activation energy @5 11
C03 12  X  FRE  @0 Haute température @5 12
C03 12  X  ENG  @0 High temperature @5 12
C03 12  X  SPA  @0 Alta temperatura @5 12
C03 13  3  FRE  @0 Conduction saut @5 13
C03 13  3  ENG  @0 Hopping conduction @5 13
C03 14  3  FRE  @0 Propriété électrique @5 14
C03 14  3  ENG  @0 Electrical properties @5 14
C03 15  3  FRE  @0 Matériau composite @5 15
C03 15  3  ENG  @0 Composite materials @5 15
C03 16  3  FRE  @0 Verre @5 16
C03 16  3  ENG  @0 Glass @5 16
C03 17  3  FRE  @0 ZnO @4 INC @5 46
C03 18  3  FRE  @0 P2O5 @4 INC @5 47
C03 19  3  FRE  @0 7280N @4 INC @5 65
C03 20  3  FRE  @0 8105K @4 INC @5 71
C03 21  3  FRE  @0 7220E @4 INC @5 72
N21       @1 063

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Le document en format XML

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<term>Electrical conductivity</term>
<term>Electrical properties</term>
<term>Glass</term>
<term>High temperature</term>
<term>Hopping conduction</term>
<term>Nickel</term>
<term>Percolation</term>
<term>Phase transitions</term>
<term>Seebeck effect</term>
<term>Temperature coefficient</term>
<term>Temperature dependence</term>
<term>Volume expansion</term>
<term>Volume fraction</term>
</keywords>
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<term>Effet Seebeck</term>
<term>Conductivité électrique</term>
<term>Nickel</term>
<term>Fraction volumique</term>
<term>Transition phase</term>
<term>Percolation</term>
<term>Porteur charge</term>
<term>Dépendance température</term>
<term>Coefficient température</term>
<term>Expansion volume</term>
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<div type="abstract" xml:lang="en">In this article, we report the electrical conductivity (σ) and Seebeck coefficient (S) of ZnO-P
<sub>2</sub>
O
<sub>5</sub>
matrix filled with conductive powder of nickel (Ni). The variation of σ versus volume fraction of Ni showed a non-conducting to conducting phase transition at percolation threshold (28 vol. %). The change of S from high positive to negative values exhibits that this transition is accompanied by the passing of carrier charge from p to n type. On the other hand, the measurements of σ and S as function of temperature, above the percolation threshold, showed a positive temperature coefficient (PTC) phase transition at T
<sub>c</sub>
≥400 K, linked with a high S = -5000 μV/K, giving highest power factor PF=σ.S
<sup>2≃</sup>
2.10
<sup>-4</sup>
Wm
<sup>-1</sup>
K
<sup>-2</sup>
. The temperature dependence of the volume expansion enabled to confirm that this transition is associated to the thermal volume variation in matrix. However, the temperature dependence of σ below the percolation threshold showed two different mechanisms: thermally activated hopping behavior at high temperatures and Mott's variable range hopping (VRH) at low temperatures.</div>
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<sub>2</sub>
O
<sub>5</sub>
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<sZ>4 aut.</sZ>
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<s1>SPCTS, CNRS UMR 6638, European Ceramic Center, 12, rue Atlantis</s1>
<s2>87068 Limoges</s2>
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</fA66>
<fC01 i1="01" l="ENG">
<s0>In this article, we report the electrical conductivity (σ) and Seebeck coefficient (S) of ZnO-P
<sub>2</sub>
O
<sub>5</sub>
matrix filled with conductive powder of nickel (Ni). The variation of σ versus volume fraction of Ni showed a non-conducting to conducting phase transition at percolation threshold (28 vol. %). The change of S from high positive to negative values exhibits that this transition is accompanied by the passing of carrier charge from p to n type. On the other hand, the measurements of σ and S as function of temperature, above the percolation threshold, showed a positive temperature coefficient (PTC) phase transition at T
<sub>c</sub>
≥400 K, linked with a high S = -5000 μV/K, giving highest power factor PF=σ.S
<sup>2≃</sup>
2.10
<sup>-4</sup>
Wm
<sup>-1</sup>
K
<sup>-2</sup>
. The temperature dependence of the volume expansion enabled to confirm that this transition is associated to the thermal volume variation in matrix. However, the temperature dependence of σ below the percolation threshold showed two different mechanisms: thermally activated hopping behavior at high temperatures and Mott's variable range hopping (VRH) at low temperatures.</s0>
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<s5>02</s5>
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<fC03 i1="03" i2="3" l="FRE">
<s0>Nickel</s0>
<s2>NC</s2>
<s5>03</s5>
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<fC03 i1="03" i2="3" l="ENG">
<s0>Nickel</s0>
<s2>NC</s2>
<s5>03</s5>
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<fC03 i1="04" i2="X" l="FRE">
<s0>Fraction volumique</s0>
<s5>04</s5>
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<fC03 i1="04" i2="X" l="ENG">
<s0>Volume fraction</s0>
<s5>04</s5>
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<s5>04</s5>
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<s5>05</s5>
</fC03>
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<s0>Phase transitions</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA">
<s0>Transición fase</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE">
<s0>Percolation</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG">
<s0>Percolation</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE">
<s0>Porteur charge</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG">
<s0>Charge carriers</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Dépendance température</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>Temperature dependence</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE">
<s0>Coefficient température</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG">
<s0>Temperature coefficient</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Expansion volume</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>Volume expansion</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Expansión volumen</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>Energie activation</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG">
<s0>Activation energy</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Haute température</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>High temperature</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Alta temperatura</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>Conduction saut</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG">
<s0>Hopping conduction</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE">
<s0>Propriété électrique</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG">
<s0>Electrical properties</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>Matériau composite</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG">
<s0>Composite materials</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE">
<s0>Verre</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="3" l="ENG">
<s0>Glass</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE">
<s0>ZnO</s0>
<s4>INC</s4>
<s5>46</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>P2O5</s0>
<s4>INC</s4>
<s5>47</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE">
<s0>7280N</s0>
<s4>INC</s4>
<s5>65</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE">
<s0>8105K</s0>
<s4>INC</s4>
<s5>71</s5>
</fC03>
<fC03 i1="21" i2="3" l="FRE">
<s0>7220E</s0>
<s4>INC</s4>
<s5>72</s5>
</fC03>
<fN21>
<s1>063</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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