Serveur d'exploration sur le nickel au Maghreb

Attention, ce site est en cours de développement !
Attention, site généré par des moyens informatiques à partir de corpus bruts.
Les informations ne sont donc pas validées.

Synthesis, structural characterization and magnetism of the solid solution : copper nickel pyrophosphate

Identifieur interne : 000571 ( PascalFrancis/Corpus ); précédent : 000570; suivant : 000572

Synthesis, structural characterization and magnetism of the solid solution : copper nickel pyrophosphate

Auteurs : A. Handizi ; A. Boukhari ; E. M. Holt ; J. Aride ; S. Flandois

Source :

RBID : Pascal:94-0131881

Descripteurs français

English descriptors

Abstract

The solid solution, Cu2-xNixP2O7 (0≤x≤2), has been synthesized and characterized by X-ray diffraction on powder. A study of the crystal chemistry of this system has revealed the existence of a phase, Cu2-xNixP2O7 (0.04≤x≤1.75), isomorphous with the high temperature forms: β-Cu2P2O7 and β-Ni2P2O7. The magnetism of this phase has been measured at x=0.25, 0.5, 1.0, 1.5 and 1.75 between 5.2 and 300 K. Antiferromagnetic interactions between ions weaken with the substitution of Ni2+ for Cu2+ in the solid state lattice of Cu2P2O7

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0025-5408
A02 01      @0 MRBUAC
A03   1    @0 Mater. res. bull.
A05       @2 28
A06       @2 12
A08 01  1  ENG  @1 Synthesis, structural characterization and magnetism of the solid solution : copper nickel pyrophosphate
A11 01  1    @1 HANDIZI (A.)
A11 02  1    @1 BOUKHARI (A.)
A11 03  1    @1 HOLT (E. M.)
A11 04  1    @1 ARIDE (J.)
A11 05  1    @1 FLANDOIS (S.)
A14 01      @1 Univ. Mohammed V, fac. sci., lab. chimie solide appliquée @2 Rabat @3 MAR @Z 1 aut. @Z 2 aut.
A14 02      @1 Cent. rech. Paul Pascal @2 33405 Talence @3 FRA @Z 5 aut.
A20       @1 1241-1247
A21       @1 1993
A23 01      @0 ENG
A43 01      @1 INIST @2 13343 @5 354000023929500030
A44       @0 0000
A45       @0 23 ref.
A47 01  1    @0 94-0131881
A60       @1 P
A61       @0 A
A64 01  1    @0 Materials research bulletin
A66 01      @0 USA
C01 01    ENG  @0 The solid solution, Cu2-xNixP2O7 (0≤x≤2), has been synthesized and characterized by X-ray diffraction on powder. A study of the crystal chemistry of this system has revealed the existence of a phase, Cu2-xNixP2O7 (0.04≤x≤1.75), isomorphous with the high temperature forms: β-Cu2P2O7 and β-Ni2P2O7. The magnetism of this phase has been measured at x=0.25, 0.5, 1.0, 1.5 and 1.75 between 5.2 and 300 K. Antiferromagnetic interactions between ions weaken with the substitution of Ni2+ for Cu2+ in the solid state lattice of Cu2P2O7
C02 01  3    @0 001B60A66F
C02 02  3    @0 001B60A10M
C02 03  3    @0 001B70E30C
C03 01  3  FRE  @0 Etude expérimentale @5 01
C03 01  3  ENG  @0 Experimental study @5 01
C03 02  3  FRE  @0 XRD @5 02
C03 02  3  ENG  @0 XRD @5 02
C03 03  3  FRE  @0 Structure cristalline @5 03
C03 03  3  ENG  @0 Crystal structure @5 03
C03 04  3  FRE  @0 Matériau magnétique @5 04
C03 04  3  ENG  @0 Magnetic materials @5 04
C03 05  3  FRE  @0 Composé quaternaire @5 06
C03 05  3  ENG  @0 Quaternary compounds @5 06
C03 06  3  FRE  @0 Solution solide @5 07
C03 06  3  ENG  @0 Solid solutions @5 07
C03 07  3  FRE  @0 Composition chimique @5 08
C03 07  3  ENG  @0 Chemical composition @5 08
C03 08  3  FRE  @0 Cuivre Diphosphate @2 NC @2 NA @5 11
C03 08  3  ENG  @0 Copper Pyrophosphates @2 NC @2 NA @5 11
C03 09  3  FRE  @0 Nickel Diphosphate @2 NC @2 NA @5 13
C03 09  3  ENG  @0 Nickel Pyrophosphates @2 NC @2 NA @5 13
C03 10  3  FRE  @0 Synthèse @5 14
C03 10  3  ENG  @0 Synthesis @5 14
C03 11  3  FRE  @0 Dépendance température @5 15
C03 11  3  ENG  @0 Temperature dependence @5 15
C03 12  X  FRE  @0 Substitution ion @5 16
C03 12  X  ENG  @0 Ion substitution @5 16
C03 12  X  SPA  @0 Sustitución ión @5 16
C03 13  3  FRE  @0 Susceptibilité magnétique @5 17
C03 13  3  ENG  @0 Magnetic susceptibility @5 17
C03 14  3  FRE  @0 6166F @2 PAC @4 INC @5 56
C03 15  3  FRE  @0 6110M @2 PAC @4 INC @5 57
C03 16  3  FRE  @0 7530C @2 PAC @4 INC @5 58
C03 17  3  FRE  @0 Cu2-xNixP2O7 @4 INC @5 92
C03 18  3  FRE  @0 Cu Ni O P @4 INC @5 93
C07 01  3  FRE  @0 Composé minéral @5 05
C07 01  3  ENG  @0 Inorganic compounds @5 05
C07 02  3  FRE  @0 Métal transition composé @5 09
C07 02  3  ENG  @0 Transition element compounds @5 09
C07 03  3  FRE  @0 Cuivre phosphate @2 NK @5 10
C07 03  3  ENG  @0 Copper phosphates @2 NK @5 10
C07 04  3  FRE  @0 Nickel phosphate @2 NK @5 12
C07 04  3  ENG  @0 Nickel phosphates @2 NK @5 12
N21       @1 061

Format Inist (serveur)

NO : PASCAL 94-0131881 INIST
ET : Synthesis, structural characterization and magnetism of the solid solution : copper nickel pyrophosphate
AU : HANDIZI (A.); BOUKHARI (A.); HOLT (E. M.); ARIDE (J.); FLANDOIS (S.)
AF : Univ. Mohammed V, fac. sci., lab. chimie solide appliquée/Rabat/Maroc (1 aut., 2 aut.); Cent. rech. Paul Pascal/33405 Talence/France (5 aut.)
DT : Publication en série; Niveau analytique
SO : Materials research bulletin; ISSN 0025-5408; Coden MRBUAC; Etats-Unis; Da. 1993; Vol. 28; No. 12; Pp. 1241-1247; Bibl. 23 ref.
LA : Anglais
EA : The solid solution, Cu2-xNixP2O7 (0≤x≤2), has been synthesized and characterized by X-ray diffraction on powder. A study of the crystal chemistry of this system has revealed the existence of a phase, Cu2-xNixP2O7 (0.04≤x≤1.75), isomorphous with the high temperature forms: β-Cu2P2O7 and β-Ni2P2O7. The magnetism of this phase has been measured at x=0.25, 0.5, 1.0, 1.5 and 1.75 between 5.2 and 300 K. Antiferromagnetic interactions between ions weaken with the substitution of Ni2+ for Cu2+ in the solid state lattice of Cu2P2O7
CC : 001B60A66F; 001B60A10M; 001B70E30C
FD : Etude expérimentale; XRD; Structure cristalline; Matériau magnétique; Composé quaternaire; Solution solide; Composition chimique; Cuivre Diphosphate; Nickel Diphosphate; Synthèse; Dépendance température; Substitution ion; Susceptibilité magnétique; 6166F; 6110M; 7530C; Cu2-xNixP2O7; Cu Ni O P
FG : Composé minéral; Métal transition composé; Cuivre phosphate; Nickel phosphate
ED : Experimental study; XRD; Crystal structure; Magnetic materials; Quaternary compounds; Solid solutions; Chemical composition; Copper Pyrophosphates; Nickel Pyrophosphates; Synthesis; Temperature dependence; Ion substitution; Magnetic susceptibility
EG : Inorganic compounds; Transition element compounds; Copper phosphates; Nickel phosphates
SD : Sustitución ión
LO : INIST-13343.354000023929500030
ID : 94-0131881

Links to Exploration step

Pascal:94-0131881

Le document en format XML

<record>
<TEI>
<teiHeader>
<fileDesc>
<titleStmt>
<title xml:lang="en" level="a">Synthesis, structural characterization and magnetism of the solid solution : copper nickel pyrophosphate</title>
<author>
<name sortKey="Handizi, A" sort="Handizi, A" uniqKey="Handizi A" first="A." last="Handizi">A. Handizi</name>
<affiliation>
<inist:fA14 i1="01">
<s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliquée</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author>
<name sortKey="Boukhari, A" sort="Boukhari, A" uniqKey="Boukhari A" first="A." last="Boukhari">A. Boukhari</name>
<affiliation>
<inist:fA14 i1="01">
<s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliquée</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author>
<name sortKey="Holt, E M" sort="Holt, E M" uniqKey="Holt E" first="E. M." last="Holt">E. M. Holt</name>
</author>
<author>
<name sortKey="Aride, J" sort="Aride, J" uniqKey="Aride J" first="J." last="Aride">J. Aride</name>
</author>
<author>
<name sortKey="Flandois, S" sort="Flandois, S" uniqKey="Flandois S" first="S." last="Flandois">S. Flandois</name>
<affiliation>
<inist:fA14 i1="02">
<s1>Cent. rech. Paul Pascal</s1>
<s2>33405 Talence</s2>
<s3>FRA</s3>
<sZ>5 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
</titleStmt>
<publicationStmt>
<idno type="wicri:source">INIST</idno>
<idno type="inist">94-0131881</idno>
<date when="1993">1993</date>
<idno type="stanalyst">PASCAL 94-0131881 INIST</idno>
<idno type="RBID">Pascal:94-0131881</idno>
<idno type="wicri:Area/PascalFrancis/Corpus">000571</idno>
</publicationStmt>
<sourceDesc>
<biblStruct>
<analytic>
<title xml:lang="en" level="a">Synthesis, structural characterization and magnetism of the solid solution : copper nickel pyrophosphate</title>
<author>
<name sortKey="Handizi, A" sort="Handizi, A" uniqKey="Handizi A" first="A." last="Handizi">A. Handizi</name>
<affiliation>
<inist:fA14 i1="01">
<s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliquée</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author>
<name sortKey="Boukhari, A" sort="Boukhari, A" uniqKey="Boukhari A" first="A." last="Boukhari">A. Boukhari</name>
<affiliation>
<inist:fA14 i1="01">
<s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliquée</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author>
<name sortKey="Holt, E M" sort="Holt, E M" uniqKey="Holt E" first="E. M." last="Holt">E. M. Holt</name>
</author>
<author>
<name sortKey="Aride, J" sort="Aride, J" uniqKey="Aride J" first="J." last="Aride">J. Aride</name>
</author>
<author>
<name sortKey="Flandois, S" sort="Flandois, S" uniqKey="Flandois S" first="S." last="Flandois">S. Flandois</name>
<affiliation>
<inist:fA14 i1="02">
<s1>Cent. rech. Paul Pascal</s1>
<s2>33405 Talence</s2>
<s3>FRA</s3>
<sZ>5 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
</analytic>
<series>
<title level="j" type="main">Materials research bulletin</title>
<title level="j" type="abbreviated">Mater. res. bull.</title>
<idno type="ISSN">0025-5408</idno>
<imprint>
<date when="1993">1993</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt>
<title level="j" type="main">Materials research bulletin</title>
<title level="j" type="abbreviated">Mater. res. bull.</title>
<idno type="ISSN">0025-5408</idno>
</seriesStmt>
</fileDesc>
<profileDesc>
<textClass>
<keywords scheme="KwdEn" xml:lang="en">
<term>Chemical composition</term>
<term>Copper Pyrophosphates</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Ion substitution</term>
<term>Magnetic materials</term>
<term>Magnetic susceptibility</term>
<term>Nickel Pyrophosphates</term>
<term>Quaternary compounds</term>
<term>Solid solutions</term>
<term>Synthesis</term>
<term>Temperature dependence</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Etude expérimentale</term>
<term>XRD</term>
<term>Structure cristalline</term>
<term>Matériau magnétique</term>
<term>Composé quaternaire</term>
<term>Solution solide</term>
<term>Composition chimique</term>
<term>Cuivre Diphosphate</term>
<term>Nickel Diphosphate</term>
<term>Synthèse</term>
<term>Dépendance température</term>
<term>Substitution ion</term>
<term>Susceptibilité magnétique</term>
<term>6166F</term>
<term>6110M</term>
<term>7530C</term>
<term>Cu2-xNixP2O7</term>
<term>Cu Ni O P</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front>
<div type="abstract" xml:lang="en">The solid solution, Cu
<sub>2-x</sub>
Ni
<sub>x</sub>
P
<sub>2</sub>
O
<sub>7</sub>
(0≤x≤2), has been synthesized and characterized by X-ray diffraction on powder. A study of the crystal chemistry of this system has revealed the existence of a phase, Cu
<sub>2-x</sub>
Ni
<sub>x</sub>
P
<sub>2</sub>
O
<sub>7</sub>
(0.04≤x≤1.75), isomorphous with the high temperature forms: β-Cu
<sub>2</sub>
P
<sub>2</sub>
O
<sub>7</sub>
and β-Ni
<sub>2</sub>
P
<sub>2</sub>
O
<sub>7</sub>
. The magnetism of this phase has been measured at x=0.25, 0.5, 1.0, 1.5 and 1.75 between 5.2 and 300 K. Antiferromagnetic interactions between ions weaken with the substitution of Ni
<sup>2+</sup>
for Cu
<sup>2+</sup>
in the solid state lattice of Cu
<sub>2</sub>
P
<sub>2</sub>
O
<sub>7</sub>
</div>
</front>
</TEI>
<inist>
<standard h6="B">
<pA>
<fA01 i1="01" i2="1">
<s0>0025-5408</s0>
</fA01>
<fA02 i1="01">
<s0>MRBUAC</s0>
</fA02>
<fA03 i2="1">
<s0>Mater. res. bull.</s0>
</fA03>
<fA05>
<s2>28</s2>
</fA05>
<fA06>
<s2>12</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG">
<s1>Synthesis, structural characterization and magnetism of the solid solution : copper nickel pyrophosphate</s1>
</fA08>
<fA11 i1="01" i2="1">
<s1>HANDIZI (A.)</s1>
</fA11>
<fA11 i1="02" i2="1">
<s1>BOUKHARI (A.)</s1>
</fA11>
<fA11 i1="03" i2="1">
<s1>HOLT (E. M.)</s1>
</fA11>
<fA11 i1="04" i2="1">
<s1>ARIDE (J.)</s1>
</fA11>
<fA11 i1="05" i2="1">
<s1>FLANDOIS (S.)</s1>
</fA11>
<fA14 i1="01">
<s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliquée</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</fA14>
<fA14 i1="02">
<s1>Cent. rech. Paul Pascal</s1>
<s2>33405 Talence</s2>
<s3>FRA</s3>
<sZ>5 aut.</sZ>
</fA14>
<fA20>
<s1>1241-1247</s1>
</fA20>
<fA21>
<s1>1993</s1>
</fA21>
<fA23 i1="01">
<s0>ENG</s0>
</fA23>
<fA43 i1="01">
<s1>INIST</s1>
<s2>13343</s2>
<s5>354000023929500030</s5>
</fA43>
<fA44>
<s0>0000</s0>
</fA44>
<fA45>
<s0>23 ref.</s0>
</fA45>
<fA47 i1="01" i2="1">
<s0>94-0131881</s0>
</fA47>
<fA60>
<s1>P</s1>
</fA60>
<fA61>
<s0>A</s0>
</fA61>
<fA64 i1="01" i2="1">
<s0>Materials research bulletin</s0>
</fA64>
<fA66 i1="01">
<s0>USA</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>The solid solution, Cu
<sub>2-x</sub>
Ni
<sub>x</sub>
P
<sub>2</sub>
O
<sub>7</sub>
(0≤x≤2), has been synthesized and characterized by X-ray diffraction on powder. A study of the crystal chemistry of this system has revealed the existence of a phase, Cu
<sub>2-x</sub>
Ni
<sub>x</sub>
P
<sub>2</sub>
O
<sub>7</sub>
(0.04≤x≤1.75), isomorphous with the high temperature forms: β-Cu
<sub>2</sub>
P
<sub>2</sub>
O
<sub>7</sub>
and β-Ni
<sub>2</sub>
P
<sub>2</sub>
O
<sub>7</sub>
. The magnetism of this phase has been measured at x=0.25, 0.5, 1.0, 1.5 and 1.75 between 5.2 and 300 K. Antiferromagnetic interactions between ions weaken with the substitution of Ni
<sup>2+</sup>
for Cu
<sup>2+</sup>
in the solid state lattice of Cu
<sub>2</sub>
P
<sub>2</sub>
O
<sub>7</sub>
</s0>
</fC01>
<fC02 i1="01" i2="3">
<s0>001B60A66F</s0>
</fC02>
<fC02 i1="02" i2="3">
<s0>001B60A10M</s0>
</fC02>
<fC02 i1="03" i2="3">
<s0>001B70E30C</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE">
<s0>Etude expérimentale</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG">
<s0>Experimental study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE">
<s0>XRD</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG">
<s0>XRD</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE">
<s0>Structure cristalline</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG">
<s0>Crystal structure</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE">
<s0>Matériau magnétique</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG">
<s0>Magnetic materials</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE">
<s0>Composé quaternaire</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG">
<s0>Quaternary compounds</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE">
<s0>Solution solide</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG">
<s0>Solid solutions</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE">
<s0>Composition chimique</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG">
<s0>Chemical composition</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Cuivre Diphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>11</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>Copper Pyrophosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>11</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE">
<s0>Nickel Diphosphate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>13</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG">
<s0>Nickel Pyrophosphates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>13</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Synthèse</s0>
<s5>14</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Synthesis</s0>
<s5>14</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>Dépendance température</s0>
<s5>15</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG">
<s0>Temperature dependence</s0>
<s5>15</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Substitution ion</s0>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Ion substitution</s0>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Sustitución ión</s0>
<s5>16</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>Susceptibilité magnétique</s0>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG">
<s0>Magnetic susceptibility</s0>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE">
<s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>6110M</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE">
<s0>7530C</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>58</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE">
<s0>Cu2-xNixP2O7</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>Cu Ni O P</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE">
<s0>Composé minéral</s0>
<s5>05</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG">
<s0>Inorganic compounds</s0>
<s5>05</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE">
<s0>Métal transition composé</s0>
<s5>09</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG">
<s0>Transition element compounds</s0>
<s5>09</s5>
</fC07>
<fC07 i1="03" i2="3" l="FRE">
<s0>Cuivre phosphate</s0>
<s2>NK</s2>
<s5>10</s5>
</fC07>
<fC07 i1="03" i2="3" l="ENG">
<s0>Copper phosphates</s0>
<s2>NK</s2>
<s5>10</s5>
</fC07>
<fC07 i1="04" i2="3" l="FRE">
<s0>Nickel phosphate</s0>
<s2>NK</s2>
<s5>12</s5>
</fC07>
<fC07 i1="04" i2="3" l="ENG">
<s0>Nickel phosphates</s0>
<s2>NK</s2>
<s5>12</s5>
</fC07>
<fN21>
<s1>061</s1>
</fN21>
</pA>
</standard>
<server>
<NO>PASCAL 94-0131881 INIST</NO>
<ET>Synthesis, structural characterization and magnetism of the solid solution : copper nickel pyrophosphate</ET>
<AU>HANDIZI (A.); BOUKHARI (A.); HOLT (E. M.); ARIDE (J.); FLANDOIS (S.)</AU>
<AF>Univ. Mohammed V, fac. sci., lab. chimie solide appliquée/Rabat/Maroc (1 aut., 2 aut.); Cent. rech. Paul Pascal/33405 Talence/France (5 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Materials research bulletin; ISSN 0025-5408; Coden MRBUAC; Etats-Unis; Da. 1993; Vol. 28; No. 12; Pp. 1241-1247; Bibl. 23 ref.</SO>
<LA>Anglais</LA>
<EA>The solid solution, Cu
<sub>2-x</sub>
Ni
<sub>x</sub>
P
<sub>2</sub>
O
<sub>7</sub>
(0≤x≤2), has been synthesized and characterized by X-ray diffraction on powder. A study of the crystal chemistry of this system has revealed the existence of a phase, Cu
<sub>2-x</sub>
Ni
<sub>x</sub>
P
<sub>2</sub>
O
<sub>7</sub>
(0.04≤x≤1.75), isomorphous with the high temperature forms: β-Cu
<sub>2</sub>
P
<sub>2</sub>
O
<sub>7</sub>
and β-Ni
<sub>2</sub>
P
<sub>2</sub>
O
<sub>7</sub>
. The magnetism of this phase has been measured at x=0.25, 0.5, 1.0, 1.5 and 1.75 between 5.2 and 300 K. Antiferromagnetic interactions between ions weaken with the substitution of Ni
<sup>2+</sup>
for Cu
<sup>2+</sup>
in the solid state lattice of Cu
<sub>2</sub>
P
<sub>2</sub>
O
<sub>7</sub>
</EA>
<CC>001B60A66F; 001B60A10M; 001B70E30C</CC>
<FD>Etude expérimentale; XRD; Structure cristalline; Matériau magnétique; Composé quaternaire; Solution solide; Composition chimique; Cuivre Diphosphate; Nickel Diphosphate; Synthèse; Dépendance température; Substitution ion; Susceptibilité magnétique; 6166F; 6110M; 7530C; Cu2-xNixP2O7; Cu Ni O P</FD>
<FG>Composé minéral; Métal transition composé; Cuivre phosphate; Nickel phosphate</FG>
<ED>Experimental study; XRD; Crystal structure; Magnetic materials; Quaternary compounds; Solid solutions; Chemical composition; Copper Pyrophosphates; Nickel Pyrophosphates; Synthesis; Temperature dependence; Ion substitution; Magnetic susceptibility</ED>
<EG>Inorganic compounds; Transition element compounds; Copper phosphates; Nickel phosphates</EG>
<SD>Sustitución ión</SD>
<LO>INIST-13343.354000023929500030</LO>
<ID>94-0131881</ID>
</server>
</inist>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/NickelMaghrebV1/Data/PascalFrancis/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000571 | SxmlIndent | more

Ou

HfdSelect -h $EXPLOR_AREA/Data/PascalFrancis/Corpus/biblio.hfd -nk 000571 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    NickelMaghrebV1
   |flux=    PascalFrancis
   |étape=   Corpus
   |type=    RBID
   |clé=     Pascal:94-0131881
   |texte=   Synthesis, structural characterization and magnetism of the solid solution : copper nickel pyrophosphate
}}

Wicri

This area was generated with Dilib version V0.6.27.
Data generation: Fri Mar 24 23:14:20 2017. Site generation: Tue Mar 5 17:03:47 2024