Electrochemical behaviour of Cu-Ni alloy in 3%NaCl medium polluted by sulphides: effect of aminotriazole
Identifieur interne : 000398 ( PascalFrancis/Corpus ); précédent : 000397; suivant : 000399Electrochemical behaviour of Cu-Ni alloy in 3%NaCl medium polluted by sulphides: effect of aminotriazole
Auteurs : A. Laachach ; A. Srhiri ; C. Fiaud ; A. BenbachirSource :
- British Corrosion Journal [ 0007-0599 ] ; 2001.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
The behaviour of 70/30 Cu-Ni alloy in 3%NaCl medium, both pure and contaminated by 1 ppm S2- ions, has been studied in the absence and in the presence of aminotriazole at a concentration of 10-4M. Potentiodynamic and electrochemical impedance measurements showed that sulphides accelerate the corrosion of the alloy in 3%NaCl. The aminotriazole inhibited both anodic and cathodic corrosion processes. The inhibiting effect was higher when the solution contained the S2- ion Analysis by scanning electron microscopy (SEM) showed that the inhibitor acts by establishing a very thin film on the metal surface. This film behaves as a barrier to the diffusion of dissolved oxygen and to the transport of the metal ions from the melt to the solution.
Notice en format standard (ISO 2709)
Pour connaître la documentation sur le format Inist Standard.
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Format Inist (serveur)
NO : | PASCAL 02-0223594 INIST |
---|---|
ET : | Electrochemical behaviour of Cu-Ni alloy in 3%NaCl medium polluted by sulphides: effect of aminotriazole |
AU : | LAACHACH (A.); SRHIRI (A.); FIAUD (C.); BENBACHIR (A.) |
AF : | High School of Technology/Salé/Maroc (1 aut.); Ability of Sciences/Kénitra/Maroc (2 aut., 4 aut.); Ecole Nationale Superieure de Chimie de Paris, 11 rue Pierre et Marie Curie/75005 Paris/France (3 aut.) |
DT : | Publication en série; Niveau analytique |
SO : | British Corrosion Journal; ISSN 0007-0599; Coden BCRJA3; Royaume-Uni; Da. 2001; Vol. 36; No. 2; Pp. 136-142; Bibl. 27 ref. |
LA : | Anglais |
EA : | The behaviour of 70/30 Cu-Ni alloy in 3%NaCl medium, both pure and contaminated by 1 ppm S2- ions, has been studied in the absence and in the presence of aminotriazole at a concentration of 10-4M. Potentiodynamic and electrochemical impedance measurements showed that sulphides accelerate the corrosion of the alloy in 3%NaCl. The aminotriazole inhibited both anodic and cathodic corrosion processes. The inhibiting effect was higher when the solution contained the S2- ion Analysis by scanning electron microscopy (SEM) showed that the inhibitor acts by establishing a very thin film on the metal surface. This film behaves as a barrier to the diffusion of dissolved oxygen and to the transport of the metal ions from the melt to the solution. |
CC : | 001D11E02; 240 |
FD : | Corrosion électrochimique; Inhibiteur corrosion; Sodium chlorure; Sulfure; Triazole dérivé; Impédance; Vitesse corrosion; Accélération; Alliage base cuivre; Protection corrosion; Nickel alliage; Alliage CuNi; Cu Ni |
ED : | Electrochemical corrosion; Corrosion inhibitor; Sodium chloride; Sulfides; Triazole derivatives; Impedance; Corrosion rate; Acceleration; Copper base alloys; Corrosion protection; Nickel alloy |
GD : | Elektrochemische Korrosion; Korrosionsinhibitor; Natriumchlorid; Sulfid; Korrosionsgeschwindigkeit; Beschleunigung; Korrosionsschutz; Nickellegierung |
SD : | Corrosión electroquímica; Inhibidor corrosión; Sodio cloruro; Sulfuro; Triazol derivado; Impedancia; Velocidad corrosión; Aceleración; Protección corrosión; Níquel aleación |
LO : | INIST-13286.354000103150010060 |
ID : | 02-0223594 |
Links to Exploration step
Pascal:02-0223594Le document en format XML
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<author><name sortKey="Laachach, A" sort="Laachach, A" uniqKey="Laachach A" first="A." last="Laachach">A. Laachach</name>
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<term>Corrosion protection</term>
<term>Corrosion rate</term>
<term>Electrochemical corrosion</term>
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<term>Nickel alloy</term>
<term>Sodium chloride</term>
<term>Sulfides</term>
<term>Triazole derivatives</term>
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<term>Inhibiteur corrosion</term>
<term>Sodium chlorure</term>
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<term>Triazole dérivé</term>
<term>Impédance</term>
<term>Vitesse corrosion</term>
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<front><div type="abstract" xml:lang="en">The behaviour of 70/30 Cu-Ni alloy in 3%NaCl medium, both pure and contaminated by 1 ppm S<sup>2-</sup>
ions, has been studied in the absence and in the presence of aminotriazole at a concentration of 10<sup>-4</sup>
M. Potentiodynamic and electrochemical impedance measurements showed that sulphides accelerate the corrosion of the alloy in 3%NaCl. The aminotriazole inhibited both anodic and cathodic corrosion processes. The inhibiting effect was higher when the solution contained the S<sup>2-</sup>
ion Analysis by scanning electron microscopy (SEM) showed that the inhibitor acts by establishing a very thin film on the metal surface. This film behaves as a barrier to the diffusion of dissolved oxygen and to the transport of the metal ions from the melt to the solution.</div>
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M. Potentiodynamic and electrochemical impedance measurements showed that sulphides accelerate the corrosion of the alloy in 3%NaCl. The aminotriazole inhibited both anodic and cathodic corrosion processes. The inhibiting effect was higher when the solution contained the S<sup>2-</sup>
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<s5>56</s5>
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<s5>56</s5>
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<s5>57</s5>
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<s5>57</s5>
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<s5>57</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Sulfure</s0>
<s2>NA</s2>
<s5>58</s5>
</fC03>
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<s2>NA</s2>
<s5>58</s5>
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<s5>58</s5>
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<s5>58</s5>
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<s5>59</s5>
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<s5>60</s5>
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<fC03 i1="06" i2="X" l="ENG"><s0>Impedance</s0>
<s5>60</s5>
</fC03>
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<s5>60</s5>
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<s5>61</s5>
</fC03>
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<s5>61</s5>
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<s5>61</s5>
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<s5>61</s5>
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<s5>62</s5>
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<s5>62</s5>
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<s5>62</s5>
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<s5>62</s5>
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<s5>65</s5>
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<s2>NK</s2>
<s5>65</s5>
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<s5>75</s5>
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<s5>75</s5>
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<s5>75</s5>
</fC03>
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<s5>75</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Nickel alliage</s0>
<s5>76</s5>
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<s5>76</s5>
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<s5>76</s5>
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<s5>76</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Alliage CuNi</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>81</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Cu Ni</s0>
<s4>INC</s4>
<s5>85</s5>
</fC03>
<fN21><s1>133</s1>
</fN21>
<fN82><s1>PSI</s1>
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<server><NO>PASCAL 02-0223594 INIST</NO>
<ET>Electrochemical behaviour of Cu-Ni alloy in 3%NaCl medium polluted by sulphides: effect of aminotriazole</ET>
<AU>LAACHACH (A.); SRHIRI (A.); FIAUD (C.); BENBACHIR (A.)</AU>
<AF>High School of Technology/Salé/Maroc (1 aut.); Ability of Sciences/Kénitra/Maroc (2 aut., 4 aut.); Ecole Nationale Superieure de Chimie de Paris, 11 rue Pierre et Marie Curie/75005 Paris/France (3 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>British Corrosion Journal; ISSN 0007-0599; Coden BCRJA3; Royaume-Uni; Da. 2001; Vol. 36; No. 2; Pp. 136-142; Bibl. 27 ref.</SO>
<LA>Anglais</LA>
<EA>The behaviour of 70/30 Cu-Ni alloy in 3%NaCl medium, both pure and contaminated by 1 ppm S<sup>2-</sup>
ions, has been studied in the absence and in the presence of aminotriazole at a concentration of 10<sup>-4</sup>
M. Potentiodynamic and electrochemical impedance measurements showed that sulphides accelerate the corrosion of the alloy in 3%NaCl. The aminotriazole inhibited both anodic and cathodic corrosion processes. The inhibiting effect was higher when the solution contained the S<sup>2-</sup>
ion Analysis by scanning electron microscopy (SEM) showed that the inhibitor acts by establishing a very thin film on the metal surface. This film behaves as a barrier to the diffusion of dissolved oxygen and to the transport of the metal ions from the melt to the solution.</EA>
<CC>001D11E02; 240</CC>
<FD>Corrosion électrochimique; Inhibiteur corrosion; Sodium chlorure; Sulfure; Triazole dérivé; Impédance; Vitesse corrosion; Accélération; Alliage base cuivre; Protection corrosion; Nickel alliage; Alliage CuNi; Cu Ni</FD>
<ED>Electrochemical corrosion; Corrosion inhibitor; Sodium chloride; Sulfides; Triazole derivatives; Impedance; Corrosion rate; Acceleration; Copper base alloys; Corrosion protection; Nickel alloy</ED>
<GD>Elektrochemische Korrosion; Korrosionsinhibitor; Natriumchlorid; Sulfid; Korrosionsgeschwindigkeit; Beschleunigung; Korrosionsschutz; Nickellegierung</GD>
<SD>Corrosión electroquímica; Inhibidor corrosión; Sodio cloruro; Sulfuro; Triazol derivado; Impedancia; Velocidad corrosión; Aceleración; Protección corrosión; Níquel aleación</SD>
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