Serveur d'exploration sur le nickel au Maghreb

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Microcalorimetric studies and methane reforming by CO2 on Ni-based zeolite catalysts

Identifieur interne : 000298 ( PascalFrancis/Corpus ); précédent : 000297; suivant : 000299

Microcalorimetric studies and methane reforming by CO2 on Ni-based zeolite catalysts

Auteurs : D. Halliche ; O. Cherifi ; A. Auroux

Source :

RBID : Pascal:06-0044720

Descripteurs français

English descriptors

Abstract

A series of catalysts containing nickel, based on HZSM-5 and USY zeolites, have been prepared by ionic exchange; a Ni/γ-Al2O3 catalyst has been prepared by impregnation, for comparison. Ammonia and CO adsorption microcalorimetry and temperature programmed reduction experiments have shown that NiZSM-5 is the most acidic and the most reducible catalyst. The study of the reaction of methane reforming by carbon dioxide in presence of these catalysts has shown that the catalytic performance depends simultaneously on the acidity, reducibility, and structure of the zeolite. Globally, it appears that the catalytic properties of NiUSY are superior to those of NiZSM-5 and Ni/γ-Al2O3.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0040-6031
A02 01      @0 THACAS
A03   1    @0 Thermochim. acta
A05       @2 434
A06       @2 1-2
A08 01  1  ENG  @1 Microcalorimetric studies and methane reforming by CO2 on Ni-based zeolite catalysts
A09 01  1  ENG  @1 Calorimetry and Thermal Effects in Catalysis: A Collection of Papers from the Third International Symposium on Calorimetry and Thermal Effects in Catalysis held in Lyon, France, July 6-9, 2004
A11 01  1    @1 HALLICHE (D.)
A11 02  1    @1 CHERIFI (O.)
A11 03  1    @1 AUROUX (A.)
A12 01  1    @1 AUROUX (Aline) @9 ed.
A14 01      @1 Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, USTHB, BP32 @2 El-Alia, Alger @3 DZA @Z 1 aut. @Z 2 aut.
A14 02      @1 Institut de Recherches sur la Catalyse, CNRS, 2 av. Albert Einstein @2 69626 Villeurbanne @3 FRA @Z 3 aut.
A15 01      @1 CNRS, Institut de Recherches sur la Catalyse, 2 avenue A. Einstein @2 69626 Villeurbanne @3 FRA @Z 1 aut.
A20       @1 125-131
A21       @1 2005
A23 01      @0 ENG
A43 01      @1 INIST @2 14753 @5 354000131483590200
A44       @0 0000 @1 © 2006 INIST-CNRS. All rights reserved.
A45       @0 46 ref.
A47 01  1    @0 06-0044720
A60       @1 P @2 C
A61       @0 A
A64 01  1    @0 Thermochimica acta
A66 01      @0 NLD
C01 01    ENG  @0 A series of catalysts containing nickel, based on HZSM-5 and USY zeolites, have been prepared by ionic exchange; a Ni/γ-Al2O3 catalyst has been prepared by impregnation, for comparison. Ammonia and CO adsorption microcalorimetry and temperature programmed reduction experiments have shown that NiZSM-5 is the most acidic and the most reducible catalyst. The study of the reaction of methane reforming by carbon dioxide in presence of these catalysts has shown that the catalytic performance depends simultaneously on the acidity, reducibility, and structure of the zeolite. Globally, it appears that the catalytic properties of NiUSY are superior to those of NiZSM-5 and Ni/γ-Al2O3.
C02 01  X    @0 001C01A03B
C03 01  X  FRE  @0 Microcalorimétrie @5 01
C03 01  X  ENG  @0 Microcalorimetry @5 01
C03 01  X  SPA  @0 Microcalorimetría @5 01
C03 02  X  FRE  @0 Méthane @2 NK @2 FX @5 02
C03 02  X  ENG  @0 Methane @2 NK @2 FX @5 02
C03 02  X  SPA  @0 Metano @2 NK @2 FX @5 02
C03 03  X  FRE  @0 Reformage @5 03
C03 03  X  ENG  @0 Reforming @5 03
C03 03  X  SPA  @0 Reformación @5 03
C03 04  X  FRE  @0 Carbone dioxyde @2 NK @2 FX @5 04
C03 04  X  ENG  @0 Carbon dioxide @2 NK @2 FX @5 04
C03 04  X  SPA  @0 Carbono dióxido @2 NK @2 FX @5 04
C03 05  X  FRE  @0 Zéolite @5 05
C03 05  X  ENG  @0 Zeolite @5 05
C03 05  X  SPA  @0 Zeolita @5 05
C03 06  X  FRE  @0 Catalyseur @5 06
C03 06  X  ENG  @0 Catalyst @5 06
C03 06  X  SPA  @0 Catalizador @5 06
C03 07  X  FRE  @0 Tamis moléculaire @5 07
C03 07  X  ENG  @0 Molecular sieve @5 07
C03 07  X  SPA  @0 Tamiz molecular @5 07
C03 08  X  FRE  @0 Catalyse hétérogène @5 08
C03 08  X  ENG  @0 Heterogeneous catalysis @5 08
C03 08  X  SPA  @0 Catálisis heterogénea @5 08
C03 09  X  FRE  @0 Isotherme adsorption @5 09
C03 09  X  ENG  @0 Adsorption isotherm @5 09
C03 09  X  SPA  @0 Isotermo adsorción @5 09
C03 10  X  FRE  @0 Analyse thermique @5 32
C03 10  X  ENG  @0 Thermal analysis @5 32
C03 10  X  SPA  @0 Análisis térmico @5 32
N21       @1 023
pR  
A30 01  1  ENG  @1 International Symposium on Calorimetry and Thermal Effects in Catalysis @2 3 @3 Lyon FRA @4 2004-07-06

Format Inist (serveur)

NO : PASCAL 06-0044720 INIST
ET : Microcalorimetric studies and methane reforming by CO2 on Ni-based zeolite catalysts
AU : HALLICHE (D.); CHERIFI (O.); AUROUX (A.); AUROUX (Aline)
AF : Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, USTHB, BP32/El-Alia, Alger/Algérie (1 aut., 2 aut.); Institut de Recherches sur la Catalyse, CNRS, 2 av. Albert Einstein/69626 Villeurbanne/France (3 aut.); CNRS, Institut de Recherches sur la Catalyse, 2 avenue A. Einstein/69626 Villeurbanne/France (1 aut.)
DT : Publication en série; Congrès; Niveau analytique
SO : Thermochimica acta; ISSN 0040-6031; Coden THACAS; Pays-Bas; Da. 2005; Vol. 434; No. 1-2; Pp. 125-131; Bibl. 46 ref.
LA : Anglais
EA : A series of catalysts containing nickel, based on HZSM-5 and USY zeolites, have been prepared by ionic exchange; a Ni/γ-Al2O3 catalyst has been prepared by impregnation, for comparison. Ammonia and CO adsorption microcalorimetry and temperature programmed reduction experiments have shown that NiZSM-5 is the most acidic and the most reducible catalyst. The study of the reaction of methane reforming by carbon dioxide in presence of these catalysts has shown that the catalytic performance depends simultaneously on the acidity, reducibility, and structure of the zeolite. Globally, it appears that the catalytic properties of NiUSY are superior to those of NiZSM-5 and Ni/γ-Al2O3.
CC : 001C01A03B
FD : Microcalorimétrie; Méthane; Reformage; Carbone dioxyde; Zéolite; Catalyseur; Tamis moléculaire; Catalyse hétérogène; Isotherme adsorption; Analyse thermique
ED : Microcalorimetry; Methane; Reforming; Carbon dioxide; Zeolite; Catalyst; Molecular sieve; Heterogeneous catalysis; Adsorption isotherm; Thermal analysis
SD : Microcalorimetría; Metano; Reformación; Carbono dióxido; Zeolita; Catalizador; Tamiz molecular; Catálisis heterogénea; Isotermo adsorción; Análisis térmico
LO : INIST-14753.354000131483590200
ID : 06-0044720

Links to Exploration step

Pascal:06-0044720

Le document en format XML

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<div type="abstract" xml:lang="en">A series of catalysts containing nickel, based on HZSM-5 and USY zeolites, have been prepared by ionic exchange; a Ni/γ-Al
<sub>2</sub>
O
<sub>3</sub>
catalyst has been prepared by impregnation, for comparison. Ammonia and CO adsorption microcalorimetry and temperature programmed reduction experiments have shown that NiZSM-5 is the most acidic and the most reducible catalyst. The study of the reaction of methane reforming by carbon dioxide in presence of these catalysts has shown that the catalytic performance depends simultaneously on the acidity, reducibility, and structure of the zeolite. Globally, it appears that the catalytic properties of NiUSY are superior to those of NiZSM-5 and Ni/γ-Al
<sub>2</sub>
O
<sub>3</sub>
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<s1>Institut de Recherches sur la Catalyse, CNRS, 2 av. Albert Einstein</s1>
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<s0>A series of catalysts containing nickel, based on HZSM-5 and USY zeolites, have been prepared by ionic exchange; a Ni/γ-Al
<sub>2</sub>
O
<sub>3</sub>
catalyst has been prepared by impregnation, for comparison. Ammonia and CO adsorption microcalorimetry and temperature programmed reduction experiments have shown that NiZSM-5 is the most acidic and the most reducible catalyst. The study of the reaction of methane reforming by carbon dioxide in presence of these catalysts has shown that the catalytic performance depends simultaneously on the acidity, reducibility, and structure of the zeolite. Globally, it appears that the catalytic properties of NiUSY are superior to those of NiZSM-5 and Ni/γ-Al
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<ET>Microcalorimetric studies and methane reforming by CO
<sub>2</sub>
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<AU>HALLICHE (D.); CHERIFI (O.); AUROUX (A.); AUROUX (Aline)</AU>
<AF>Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, USTHB, BP32/El-Alia, Alger/Algérie (1 aut., 2 aut.); Institut de Recherches sur la Catalyse, CNRS, 2 av. Albert Einstein/69626 Villeurbanne/France (3 aut.); CNRS, Institut de Recherches sur la Catalyse, 2 avenue A. Einstein/69626 Villeurbanne/France (1 aut.)</AF>
<DT>Publication en série; Congrès; Niveau analytique</DT>
<SO>Thermochimica acta; ISSN 0040-6031; Coden THACAS; Pays-Bas; Da. 2005; Vol. 434; No. 1-2; Pp. 125-131; Bibl. 46 ref.</SO>
<LA>Anglais</LA>
<EA>A series of catalysts containing nickel, based on HZSM-5 and USY zeolites, have been prepared by ionic exchange; a Ni/γ-Al
<sub>2</sub>
O
<sub>3</sub>
catalyst has been prepared by impregnation, for comparison. Ammonia and CO adsorption microcalorimetry and temperature programmed reduction experiments have shown that NiZSM-5 is the most acidic and the most reducible catalyst. The study of the reaction of methane reforming by carbon dioxide in presence of these catalysts has shown that the catalytic performance depends simultaneously on the acidity, reducibility, and structure of the zeolite. Globally, it appears that the catalytic properties of NiUSY are superior to those of NiZSM-5 and Ni/γ-Al
<sub>2</sub>
O
<sub>3</sub>
.</EA>
<CC>001C01A03B</CC>
<FD>Microcalorimétrie; Méthane; Reformage; Carbone dioxyde; Zéolite; Catalyseur; Tamis moléculaire; Catalyse hétérogène; Isotherme adsorption; Analyse thermique</FD>
<ED>Microcalorimetry; Methane; Reforming; Carbon dioxide; Zeolite; Catalyst; Molecular sieve; Heterogeneous catalysis; Adsorption isotherm; Thermal analysis</ED>
<SD>Microcalorimetría; Metano; Reformación; Carbono dióxido; Zeolita; Catalizador; Tamiz molecular; Catálisis heterogénea; Isotermo adsorción; Análisis térmico</SD>
<LO>INIST-14753.354000131483590200</LO>
<ID>06-0044720</ID>
</server>
</inist>
</record>

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