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Structural investigation and solid-H2 reaction of Mg2Ni rich nanocomposite materials elaborated by mechanical alloying

Identifieur interne : 000445 ( PascalFrancis/Checkpoint ); précédent : 000444; suivant : 000446

Structural investigation and solid-H2 reaction of Mg2Ni rich nanocomposite materials elaborated by mechanical alloying

Auteurs : M. Abdellaoui [Tunisie] ; D. Cracco [France] ; A. Percheron-Guegan [France]

Source :

RBID : Pascal:00-0062549

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Abstract

Using a planetary ball mill and starting from a mixture of Mg and Ni with an atomic ration of 2:1, we have successfully elaborated a nanocomposite material formed by the Mg2Ni phase in high proportion, some residual Ni and an amorphous phase. The synthesis of this composite proceeded at milling intensities 7 and 10, corresponding respectively to 3.5 and 10 W g-1 shock power, respectively after 18 and 4 h. The best hydrogen absorption capacity reported, 3.75 H mole-1 (3.53 wt.%), is for the composite synthesized for 24 h at 3.5 W g-1 shock power.


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Pascal:00-0062549

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<div type="abstract" xml:lang="en">Using a planetary ball mill and starting from a mixture of Mg and Ni with an atomic ration of 2:1, we have successfully elaborated a nanocomposite material formed by the Mg
<sub>2</sub>
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<sup>-1</sup>
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<sup>-1</sup>
shock power, respectively after 18 and 4 h. The best hydrogen absorption capacity reported, 3.75 H mole
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<s5>92</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE">
<s0>Mg Ni</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE">
<s0>Métal transition alliage</s0>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG">
<s0>Transition metal alloy</s0>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="X" l="GER">
<s0>Uebergangsmetallegierung</s0>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA">
<s0>Metal transición aleación</s0>
<s5>16</s5>
</fC07>
<fN21>
<s1>045</s1>
</fN21>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>International Symposium on Metal-Hydrogen Systems - Fundamentals and Applications</s1>
<s3>Hangzhou CHN</s3>
<s4>1998-10-04</s4>
</fA30>
</pR>
</standard>
</inist>
<affiliations>
<list>
<country>
<li>France</li>
<li>Tunisie</li>
</country>
<region>
<li>Gouvernorat de Tunis</li>
<li>Île-de-France</li>
</region>
<settlement>
<li>Thiais</li>
<li>Tunis</li>
</settlement>
</list>
<tree>
<country name="Tunisie">
<region name="Gouvernorat de Tunis">
<name sortKey="Abdellaoui, M" sort="Abdellaoui, M" uniqKey="Abdellaoui M" first="M." last="Abdellaoui">M. Abdellaoui</name>
</region>
</country>
<country name="France">
<region name="Île-de-France">
<name sortKey="Cracco, D" sort="Cracco, D" uniqKey="Cracco D" first="D." last="Cracco">D. Cracco</name>
</region>
<name sortKey="Percheron Guegan, A" sort="Percheron Guegan, A" uniqKey="Percheron Guegan A" first="A." last="Percheron-Guegan">A. Percheron-Guegan</name>
</country>
</tree>
</affiliations>
</record>

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