Earth's Phosphides in Levant and insights into the source of Archean prebiotic phosphorus
Identifieur interne : 000126 ( Ncbi/Curation ); précédent : 000125; suivant : 000127Earth's Phosphides in Levant and insights into the source of Archean prebiotic phosphorus
Auteurs : Sergey N. Britvin [Russie] ; Michail N. Murashko [Russie] ; Yevgeny Vapnik [Israël] ; Yury S. Polekhovsky [Russie] ; Sergey V. Krivovichev [Russie]Source :
- Scientific Reports [ 2045-2322 ] ; 2015.
Abstract
Natural phosphides - the minerals containing phosphorus in a redox state lower than zero – are common constituents of meteorites but virtually unknown on the Earth. Herein we present the first rich occurrence of iron-nickel phosphides of terrestrial origin. Phosphide-bearing rocks are exposed in three localities in the surroundings of the Dead Sea, Levant: in the northern Negev Desert, Israel and Transjordan Plateau, south of Amman, Jordan. Seven minerals from the ternary Fe-Ni-P system have been identified with five of them, NiP2, Ni5P4, Ni2P, FeP and FeP2, previously unknown in nature. The results of the present study could provide a new insight on the terrestrial origin of natural phosphides – the most likely source of reactive prebiotic phosphorus at the times of the early Earth.
Url:
DOI: 10.1038/srep08355
PubMed: 25667163
PubMed Central: 4322360
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PMC:4322360Le document en format XML
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<front><div type="abstract" xml:lang="en"><p>Natural phosphides - the minerals containing phosphorus in a redox state lower than zero – are common constituents of meteorites but virtually unknown on the Earth. Herein we present the first rich occurrence of iron-nickel phosphides of terrestrial origin. Phosphide-bearing rocks are exposed in three localities in the surroundings of the Dead Sea, Levant: in the northern Negev Desert, Israel and Transjordan Plateau, south of Amman, Jordan. Seven minerals from the ternary Fe-Ni-P system have been identified with five of them, NiP<sub>2</sub>
, Ni<sub>5</sub>
P<sub>4</sub>
, Ni<sub>2</sub>
P, FeP and FeP<sub>2</sub>
, previously unknown in nature. The results of the present study could provide a new insight on the terrestrial origin of natural phosphides – the most likely source of reactive prebiotic phosphorus at the times of the early Earth.</p>
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