Poly(mercaptoimidazolyl)borate Complexes of Cadmium and Mercury
Identifieur interne : 000679 ( Main/Exploration ); précédent : 000678; suivant : 000680Poly(mercaptoimidazolyl)borate Complexes of Cadmium and Mercury
Auteurs : Daniel Rabinovich [États-Unis]Source :
- Structure and Bonding [ 0081-5993 ] ; 2006.
Abstract
Abstract: The coordination chemistry of bis- and tris(mercaptoimidazolyl)borate ligands with both main-group and transition metals is rapidly expanding. Usually regarded as soft analogues of the popular poly(pyrazolyl)borates (scorpionates), these sulfur-donor ligands display a good affinity for soft metals such as cadmium and mercury. They are readily prepared in high yield and their metal complexes are usually air-stable and exhibit good solubility and simple spectroscopic features in solution and good crystallinity in the solid state. This review will describe the syntheses, structures and reactivity of cadmium and mercury compounds supported by this family of ligands, ranging from simple homoleptic M(BmR)2 and M(TmR)2 derivatives (M = Cd, Hg) to a variety of well-defined (TmR)MX complexes (X = halide, thiolate, etc.). Comparisons with known zinc analogues will also be drawn whenever appropriate, particularly with the goal of establishing trends in structural features, reactivity and physical or spectroscopic properties.
Url:
DOI: 10.1007/430_031
Affiliations:
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<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Poly(mercaptoimidazolyl)borate Complexes of Cadmium and Mercury</title><author><name sortKey="Rabinovich, Daniel" sort="Rabinovich, Daniel" uniqKey="Rabinovich D" first="Daniel" last="Rabinovich">Daniel Rabinovich</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:5D5F8F57364075C6F744442F9816AC31BB5DBD4F</idno><date when="2006" year="2006">2006</date><idno type="doi">10.1007/430_031</idno><idno type="url">https://api.istex.fr/document/5D5F8F57364075C6F744442F9816AC31BB5DBD4F/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">001819</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001819</idno><idno type="wicri:Area/Istex/Curation">001267</idno><idno type="wicri:Area/Istex/Checkpoint">000273</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000273</idno><idno type="wicri:doubleKey">0081-5993:2006:Rabinovich D:poly:mercaptoimidazolyl:borate</idno><idno type="wicri:Area/Main/Merge">000698</idno><idno type="wicri:Area/Main/Curation">000679</idno><idno type="wicri:Area/Main/Exploration">000679</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Poly(mercaptoimidazolyl)borate Complexes of Cadmium and Mercury</title><author><name sortKey="Rabinovich, Daniel" sort="Rabinovich, Daniel" uniqKey="Rabinovich D" first="Daniel" last="Rabinovich">Daniel Rabinovich</name><affiliation wicri:level="2"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Chemistry, The University of North Carolina at Charlotte, 9201 University City Boulevard, 28223, Charlotte, North Carolina</wicri:regionArea><placeName><region type="state">Caroline du Nord</region></placeName></affiliation><affiliation wicri:level="1"><country wicri:rule="url">États-Unis</country></affiliation></author></analytic><monogr></monogr><series><title level="s">Structure and Bonding</title><imprint><date>2006</date></imprint><idno type="ISSN">0081-5993</idno><idno type="ISSN">0081-5993</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0081-5993</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: The coordination chemistry of bis- and tris(mercaptoimidazolyl)borate ligands with both main-group and transition metals is rapidly expanding. Usually regarded as soft analogues of the popular poly(pyrazolyl)borates (scorpionates), these sulfur-donor ligands display a good affinity for soft metals such as cadmium and mercury. They are readily prepared in high yield and their metal complexes are usually air-stable and exhibit good solubility and simple spectroscopic features in solution and good crystallinity in the solid state. This review will describe the syntheses, structures and reactivity of cadmium and mercury compounds supported by this family of ligands, ranging from simple homoleptic M(BmR)2 and M(TmR)2 derivatives (M = Cd, Hg) to a variety of well-defined (TmR)MX complexes (X = halide, thiolate, etc.). Comparisons with known zinc analogues will also be drawn whenever appropriate, particularly with the goal of establishing trends in structural features, reactivity and physical or spectroscopic properties.</div></front></TEI><affiliations><list><country><li>États-Unis</li></country><region><li>Caroline du Nord</li></region></list><tree><country name="États-Unis"><region name="Caroline du Nord"><name sortKey="Rabinovich, Daniel" sort="Rabinovich, Daniel" uniqKey="Rabinovich D" first="Daniel" last="Rabinovich">Daniel Rabinovich</name></region><name sortKey="Rabinovich, Daniel" sort="Rabinovich, Daniel" uniqKey="Rabinovich D" first="Daniel" last="Rabinovich">Daniel Rabinovich</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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