Spectrophotometric Determination of Cu2+ and Monitoring of Hg2+ and Ni2+ in some Iranian Vegetables Using 6-(2-Naphthyl)-2, 3-Dihydro-as-triazine-3-thione
Identifieur interne : 000124 ( Main/Exploration ); précédent : 000123; suivant : 000125Spectrophotometric Determination of Cu2+ and Monitoring of Hg2+ and Ni2+ in some Iranian Vegetables Using 6-(2-Naphthyl)-2, 3-Dihydro-as-triazine-3-thione
Auteurs : Fazel Shamsa ; Malehe Barazande Tehrani ; Hamid Mehravar ; Elaheh MohammadiSource :
- Iranian Journal of Pharmaceutical Research : IJPR [ 1735-0328 ] ; 2013.
Abstract
Recently, 6-(2-naphthyl)-2, 3-dihydro-as-triazine-3-thione (NDTT) was synthesized in laboratory and used successfully for the spectrophotometric determination of nanogram levels of Cu2+ in aqueous solution. This reagent forms a specific red complex with Cu2+ ions after the extraction by chloroform at alkaline pH. The absorption of the complex in the UV region (313 nm) is about 8 times as strong as in the visible one (510 nm). Mercury and nickel ions form yellow complexes with NDTT under the same conditions which interfere in the UV region and without effect on Cu (II) absorbance in the visible region. The studied vegetables include
Url:
PubMed: 24250566
PubMed Central: 3813219
Affiliations:
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Le document en format XML
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and Monitoring of Hg<sup>2+</sup>
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in some Iranian Vegetables Using 6-(2-Naphthyl)-2, 3-Dihydro-as-triazine-3-thione </title>
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in some Iranian Vegetables Using 6-(2-Naphthyl)-2, 3-Dihydro-as-triazine-3-thione </title>
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<front><div type="abstract" xml:lang="en"><p>Recently, 6-(2-naphthyl)-2, 3-dihydro-as-triazine-3-thione (NDTT) was synthesized in laboratory and used successfully for the spectrophotometric determination of nanogram levels of Cu<sup>2+</sup>
in aqueous solution. This reagent forms a specific red complex with Cu<sup>2+</sup>
ions after the extraction by chloroform at alkaline pH. The absorption of the complex in the UV region (313 nm) is about 8 times as strong as in the visible one (510 nm). Mercury and nickel ions form yellow complexes with NDTT under the same conditions which interfere in the UV region and without effect on Cu (II) absorbance in the visible region. The studied vegetables include <italic>Mentha pipereta </italic>
L., <italic>Anethum graveolens </italic>
L., <italic>Beta vulgaris </italic>
L., <italic>Coriandrum sativum</italic>
, <italic>Petroselinum hortense </italic>
H., <italic>Ocimum basilicum </italic>
L., <italic>Spinacia oleracea </italic>
L., <italic>Lactuca sativa </italic>
L., and <italic>Brassica oleracea </italic>
L. </p>
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