Porphyrins from Messel oil shale (Eocene, Germany): Structure elucidation, geochemical and biological significance, and distribution as a function of depth
Identifieur interne : 000E02 ( Istex/Curation ); précédent : 000E01; suivant : 000E03Porphyrins from Messel oil shale (Eocene, Germany): Structure elucidation, geochemical and biological significance, and distribution as a function of depth
Auteurs : Rubén Ocampo [France] ; Claude Bauder [France] ; Henry J. Callot [France] ; Pierre Albrecht [France]Source :
- Geochimica et Cosmochimica Acta [ 0016-7037 ] ; 1992.
Abstract
The extraction and isolation procedures of twenty nickel porphyrins (seven alkylporphyrins, thirteen carboxylic acids) from lacustrine Messel shale (Eocene, Germany), as well as the unequivocal structural assignments (obtained using 200 and 400 MHz nuclear magnetic resonance (NMR), nuclear Overhauser effect, mass spectrometry and total or partial synthesis of six reference compounds) are described. Ten porphyrins could be specifically correlated with biological precursors: algal chlorophyll c (4), bacteriochlorophylls d (3) and heme (3), while the remaining ones may arise from several chlorophylls. The structures of these fossil pigments mostly confirm the classical “Treibs scheme,” including the origin of some porphyrins from nonchlorophyll sources. They also show that, even in a very immature sediment, deep modifications occur, including, in particular, extensive degradation of chlorophyll E ring. The composition of the porphyrin fractions of Messel oil shale was also studied as a function of depth. A porphyrin acids/alkylporphyrins ratio varying from 0.35 to 24.8 demonstrated that the apparent homogeneity of the shale is not reflected on the molecular scale. This was confirmed when the abundance of the twenty individual porphyrins of known structure was measured along the core. Significant correlations between individual porphyrins were found: fossils of bacteriochlorophylls d, homolog pairs of porphyrins (3-H/3-ethyl), etc.
Url:
DOI: 10.1016/0016-7037(92)90095-Z
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: Pour aller vers cette notice dans l'étape Curation :001270
Links to Exploration step
ISTEX:612658385E9479E1ECABF89367CC6DD2674EDB93Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title>Porphyrins from Messel oil shale (Eocene, Germany): Structure elucidation, geochemical and biological significance, and distribution as a function of depth</title><author><name sortKey="Ocampo, Ruben" sort="Ocampo, Ruben" uniqKey="Ocampo R" first="Rubén" last="Ocampo">Rubén Ocampo</name><affiliation wicri:level="1"><mods:affiliation>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg</wicri:regionArea></affiliation></author><author><name sortKey="Bauder, Claude" sort="Bauder, Claude" uniqKey="Bauder C" first="Claude" last="Bauder">Claude Bauder</name><affiliation wicri:level="1"><mods:affiliation>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg</wicri:regionArea></affiliation></author><author><name sortKey="Callot, Henry J" sort="Callot, Henry J" uniqKey="Callot H" first="Henry J." last="Callot">Henry J. Callot</name><affiliation wicri:level="1"><mods:affiliation>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg</wicri:regionArea></affiliation></author><author><name sortKey="Albrecht, Pierre" sort="Albrecht, Pierre" uniqKey="Albrecht P" first="Pierre" last="Albrecht">Pierre Albrecht</name><affiliation wicri:level="1"><mods:affiliation>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:612658385E9479E1ECABF89367CC6DD2674EDB93</idno><date when="1992" year="1992">1992</date><idno type="doi">10.1016/0016-7037(92)90095-Z</idno><idno type="url">https://api.istex.fr/document/612658385E9479E1ECABF89367CC6DD2674EDB93/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">001270</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001270</idno><idno type="wicri:Area/Istex/Curation">000E02</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a">Porphyrins from Messel oil shale (Eocene, Germany): Structure elucidation, geochemical and biological significance, and distribution as a function of depth</title><author><name sortKey="Ocampo, Ruben" sort="Ocampo, Ruben" uniqKey="Ocampo R" first="Rubén" last="Ocampo">Rubén Ocampo</name><affiliation wicri:level="1"><mods:affiliation>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg</wicri:regionArea></affiliation></author><author><name sortKey="Bauder, Claude" sort="Bauder, Claude" uniqKey="Bauder C" first="Claude" last="Bauder">Claude Bauder</name><affiliation wicri:level="1"><mods:affiliation>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg</wicri:regionArea></affiliation></author><author><name sortKey="Callot, Henry J" sort="Callot, Henry J" uniqKey="Callot H" first="Henry J." last="Callot">Henry J. Callot</name><affiliation wicri:level="1"><mods:affiliation>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg</wicri:regionArea></affiliation></author><author><name sortKey="Albrecht, Pierre" sort="Albrecht, Pierre" uniqKey="Albrecht P" first="Pierre" last="Albrecht">Pierre Albrecht</name><affiliation wicri:level="1"><mods:affiliation>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>URA 31 du CNRS, Institut de Chimie, Université Louis Pasteur, 1 rue Blaise Pascal, 67008 Strasbourg</wicri:regionArea></affiliation></author></analytic><monogr></monogr><series><title level="j">Geochimica et Cosmochimica Acta</title><title level="j" type="abbrev">GCA</title><idno type="ISSN">0016-7037</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1992">1992</date><biblScope unit="volume">56</biblScope><biblScope unit="issue">2</biblScope><biblScope unit="page" from="745">745</biblScope><biblScope unit="page" to="761">761</biblScope></imprint><idno type="ISSN">0016-7037</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0016-7037</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The extraction and isolation procedures of twenty nickel porphyrins (seven alkylporphyrins, thirteen carboxylic acids) from lacustrine Messel shale (Eocene, Germany), as well as the unequivocal structural assignments (obtained using 200 and 400 MHz nuclear magnetic resonance (NMR), nuclear Overhauser effect, mass spectrometry and total or partial synthesis of six reference compounds) are described. Ten porphyrins could be specifically correlated with biological precursors: algal chlorophyll c (4), bacteriochlorophylls d (3) and heme (3), while the remaining ones may arise from several chlorophylls. The structures of these fossil pigments mostly confirm the classical “Treibs scheme,” including the origin of some porphyrins from nonchlorophyll sources. They also show that, even in a very immature sediment, deep modifications occur, including, in particular, extensive degradation of chlorophyll E ring. The composition of the porphyrin fractions of Messel oil shale was also studied as a function of depth. A porphyrin acids/alkylporphyrins ratio varying from 0.35 to 24.8 demonstrated that the apparent homogeneity of the shale is not reflected on the molecular scale. This was confirmed when the abundance of the twenty individual porphyrins of known structure was measured along the core. Significant correlations between individual porphyrins were found: fossils of bacteriochlorophylls d, homolog pairs of porphyrins (3-H/3-ethyl), etc.</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/NickelMaghrebV1/Data/Istex/Curation
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000E02 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Istex/Curation/biblio.hfd -nk 000E02 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Terre
|area= NickelMaghrebV1
|flux= Istex
|étape= Curation
|type= RBID
|clé= ISTEX:612658385E9479E1ECABF89367CC6DD2674EDB93
|texte= Porphyrins from Messel oil shale (Eocene, Germany): Structure elucidation, geochemical and biological significance, and distribution as a function of depth
}}
| This area was generated with Dilib version V0.6.27. |  |