Cu2+-ISFET type microsensors based on thermally evaporated p - tert -butylcalix[9 and 11]arene thin films
Identifieur interne : 000275 ( Istex/Curation ); précédent : 000274; suivant : 000276Cu2+-ISFET type microsensors based on thermally evaporated p - tert -butylcalix[9 and 11]arene thin films
Auteurs : R. Mlika [Tunisie] ; I. Dumazet [France] ; H. Ben Ouada [Tunisie] ; N. Jaffrezic-Renault [France] ; R. Lamartine [France] ; M. Gamoudi [France] ; G. Guillaud [France]Source :
- Sensors & Actuators: B. Chemical [ 0925-4005 ] ; 2000.
Abstract
Large size odd-numbered calixarenes were used for the first time as ionophoric agents for the functionalization of ISFET microsensors and EIS structures through thermal evaporation process. Both calixarenes have shown a nernstian sensitivity over three decades towards only copper (II) activities. Very low selectivity coefficients were observed for K+ and Ca2+ whereas Cd2+ and Pb2+ (less than 10−3) can be considered as interfering ions. Lifetime of around three months for the microsensors were obtained.
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DOI: 10.1016/S0925-4005(99)00355-X
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ISTEX:B71CAEE43C321029D47EA9EF5F713BBED7E9FF4DLe document en format XML
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<front><div type="abstract" xml:lang="en">Large size odd-numbered calixarenes were used for the first time as ionophoric agents for the functionalization of ISFET microsensors and EIS structures through thermal evaporation process. Both calixarenes have shown a nernstian sensitivity over three decades towards only copper (II) activities. Very low selectivity coefficients were observed for K+ and Ca2+ whereas Cd2+ and Pb2+ (less than 10−3) can be considered as interfering ions. Lifetime of around three months for the microsensors were obtained.</div>
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