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Synthesis and characterization of metallic complexes of 3-(2-furyl) 2-propenal semicarbazone with d element dihalides

Identifieur interne : 000D08 ( Istex/Corpus ); précédent : 000D07; suivant : 000D09

Synthesis and characterization of metallic complexes of 3-(2-furyl) 2-propenal semicarbazone with d element dihalides

Auteurs : G. Ibrahim ; M. A. Khan ; P. Richomme ; O. Benali-Baïtich ; G. Bouet

Source :

RBID : ISTEX:41D1A153EF02E2728BA8DF8AF1E7A54FF3AB4539

Abstract

3-(2-Furyl) 2-propenal semicarbazone (FASC) and CoII, NiII, CuII, ZnII and CdII chlorides or bromides gave the complexes: [M(FASC)2X2], [M(FASC)2]X2 or [M(FASC)X2] which were characterized starting from elemental analysis and molar conductances. Their structures are discussed on the basis of magnetic moments, infrared and electronic spectra; in addition, the NMR data are used in the case of ZnII and CdII species. The main cell parameters are given using X-ray diffraction powder diagrams.

Url:
DOI: 10.1016/S0277-5387(97)00063-6

Links to Exploration step

ISTEX:41D1A153EF02E2728BA8DF8AF1E7A54FF3AB4539

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<div type="abstract" xml:lang="en">3-(2-Furyl) 2-propenal semicarbazone (FASC) and CoII, NiII, CuII, ZnII and CdII chlorides or bromides gave the complexes: [M(FASC)2X2], [M(FASC)2]X2 or [M(FASC)X2] which were characterized starting from elemental analysis and molar conductances. Their structures are discussed on the basis of magnetic moments, infrared and electronic spectra; in addition, the NMR data are used in the case of ZnII and CdII species. The main cell parameters are given using X-ray diffraction powder diagrams.</div>
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<ce:simple-para>3-(2-Furyl) 2-propenal semicarbazone (FASC) and Co
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X
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<ce:sup>II</ce:sup>
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<ce:sup>II</ce:sup>
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<affiliation>Laboratoire de Chimie de Coordination, Faculté de Pharmacie, 16 Boulevard Daviers, F-49100 Angers, France</affiliation>
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<affiliation>Laboratoire de Chimie de Coordination, Faculté de Pharmacie, 16 Boulevard Daviers, F-49100 Angers, France</affiliation>
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<namePart type="family">Richomme</namePart>
<affiliation>Service commun de R.M.N., Faculté de Pharmacie, 16 Boulevard Daviers, F-49100 Angers, France</affiliation>
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<name type="personal">
<namePart type="given">O.</namePart>
<namePart type="family">Benali-Baïtich</namePart>
<affiliation>Laboratoire de Chimie de Cooridination, Institu de Chimie, U.S.T.H.B., B.P. 22 El Alia, Bab Ezzouar, DZ-16111 Alger, Algeria</affiliation>
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<name type="personal">
<namePart type="given">G.</namePart>
<namePart type="family">Bouet</namePart>
<affiliation>Author to whom correspondence should be addressed.</affiliation>
<affiliation>Laboratoire de Chimie de Coordination, Faculté de Pharmacie, 16 Boulevard Daviers, F-49100 Angers, France</affiliation>
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<dateIssued encoding="w3cdtf">1997</dateIssued>
<copyrightDate encoding="w3cdtf">1997</copyrightDate>
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<languageTerm type="code" authority="iso639-2b">eng</languageTerm>
<languageTerm type="code" authority="rfc3066">en</languageTerm>
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<abstract lang="en">3-(2-Furyl) 2-propenal semicarbazone (FASC) and CoII, NiII, CuII, ZnII and CdII chlorides or bromides gave the complexes: [M(FASC)2X2], [M(FASC)2]X2 or [M(FASC)X2] which were characterized starting from elemental analysis and molar conductances. Their structures are discussed on the basis of magnetic moments, infrared and electronic spectra; in addition, the NMR data are used in the case of ZnII and CdII species. The main cell parameters are given using X-ray diffraction powder diagrams.</abstract>
<subject>
<genre>Keywords</genre>
<topic>complexes</topic>
<topic>d element</topic>
<topic>semicarbazone</topic>
<topic>spectroscopy</topic>
<topic>furan</topic>
<topic>X-ray powder diffraction</topic>
</subject>
<relatedItem type="host">
<titleInfo>
<title>Polyhedron</title>
</titleInfo>
<titleInfo type="abbreviated">
<title>POLY</title>
</titleInfo>
<genre type="journal">journal</genre>
<originInfo>
<dateIssued encoding="w3cdtf">1997</dateIssued>
</originInfo>
<identifier type="ISSN">0277-5387</identifier>
<identifier type="PII">S0277-5387(00)X0067-8</identifier>
<part>
<date>1997</date>
<detail type="volume">
<number>16</number>
<caption>vol.</caption>
</detail>
<detail type="issue">
<number>19</number>
<caption>no.</caption>
</detail>
<extent unit="issue pages">
<start>3247</start>
<end>3483</end>
</extent>
<extent unit="pages">
<start>3455</start>
<end>3461</end>
</extent>
</part>
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<identifier type="istex">41D1A153EF02E2728BA8DF8AF1E7A54FF3AB4539</identifier>
<identifier type="DOI">10.1016/S0277-5387(97)00063-6</identifier>
<identifier type="PII">S0277-5387(97)00063-6</identifier>
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