Comparison of the electrodialytic properties on NiSO4 and NiCl2: Influence of the salt nature in electrodialysis
Identifieur interne : 000B04 ( Istex/Corpus ); précédent : 000B03; suivant : 000B05Comparison of the electrodialytic properties on NiSO4 and NiCl2: Influence of the salt nature in electrodialysis
Auteurs : Kamel-Eddine Bouhidel ; Michel RumeauSource :
- Desalination [ 0011-9164 ] ; 2000.
Abstract
This research work compares the electrodialytic properties of NiSO4 and NiCl2 during a batch process. The current intensity-time, pH-time, water transport-time plottings are investigated. We try to answer the following questions: (1) Why do NiSO4 and NiCl2 present very different electrodialytic properties? (2) Is it possible to anticipate the electrodialytic behavior and properties of a given salt? (3) What are the salt basic properties that influence directly its electrodialytic behavior? The pH-time curves are the more interesting results: the pH decreases with NiSO4 and increases with NiCl2. The classical approaches do not explain this difference. In this study we try to defend this idea: the difference of the counterions mobilities in their respective membranes explains the pH changes.
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DOI: 10.1016/S0011-9164(00)00149-1
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The current intensity-time, pH-time, water transport-time plottings are investigated. We try to answer the following questions: (1) Why do NiSO4 and NiCl2 present very different electrodialytic properties? (2) Is it possible to anticipate the electrodialytic behavior and properties of a given salt? (3) What are the salt basic properties that influence directly its electrodialytic behavior? The pH-time curves are the more interesting results: the pH decreases with NiSO4 and increases with NiCl2. The classical approaches do not explain this difference. In this study we try to defend this idea: the difference of the counterions mobilities in their respective membranes explains the pH changes.</div></front></TEI><istex><corpusName>elsevier</corpusName><author><json:item><name>Kamel-Eddine Bouhidel</name><affiliations><json:string>Water Chemistry and Separation Techniques Laboratory, Science Faculty, Department of Chemistry, University of Batna, Algeria Fax +213 (4) 81 5375, +213 (4) 81 2480</json:string></affiliations></json:item><json:item><name>Michel Rumeau</name><affiliations><json:string>USTL Montpellier, France</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>Electrodialysis</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>pH changes</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Selectivity</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Cl− and SO4= comparison</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Mobilities</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>Non-electroneutrality</value></json:item></subject><language><json:string>eng</json:string></language><originalGenre><json:string>Full-length article</json:string></originalGenre><abstract>This research work compares the electrodialytic properties of NiSO4 and NiCl2 during a batch process. 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In this study we try to defend this idea: the difference of the counterions mobilities in their respective membranes explains the pH changes.</abstract><qualityIndicators><score>2.166</score><pdfVersion>1.2</pdfVersion><pdfPageSize>548 x 749 pts</pdfPageSize><refBibsNative>true</refBibsNative><keywordCount>6</keywordCount><abstractCharCount>800</abstractCharCount><pdfWordCount>750</pdfWordCount><pdfCharCount>4655</pdfCharCount><pdfPageCount>3</pdfPageCount><abstractWordCount>118</abstractWordCount></qualityIndicators><title>Comparison of the electrodialytic properties on NiSO4 and NiCl2: Influence of the salt nature in 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5375, +213 (4) 81 2480</affiliation></author><author xml:id="author-0001"><persName><forename type="first">Michel</forename><surname>Rumeau</surname></persName><affiliation>USTL Montpellier, France</affiliation></author><idno type="istex">565B3C27DF0A5704360557BCD6382E14FEC95EA0</idno><idno type="DOI">10.1016/S0011-9164(00)00149-1</idno><idno type="PII">S0011-9164(00)00149-1</idno></analytic><monogr><title level="j">Desalination</title><title level="j" type="abbrev">DES</title><idno type="pISSN">0011-9164</idno><idno type="PII">S0011-9164(00)X0112-9</idno><meeting><addName>Membranes in Drinking and Industrial Water Production, Paris, France</addName><date>20001003</date><date>20001006</date></meeting><imprint><publisher>ELSEVIER</publisher><date type="published" when="2000"></date><biblScope unit="volume">132</biblScope><biblScope unit="issue">1–3</biblScope><biblScope unit="page" from="195">195</biblScope><biblScope unit="page" 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The current intensity-time, pH-time, water transport-time plottings are investigated. We try to answer the following questions: (1) Why do NiSO4 and NiCl2 present very different electrodialytic properties? (2) Is it possible to anticipate the electrodialytic behavior and properties of a given salt? (3) What are the salt basic properties that influence directly its electrodialytic behavior? The pH-time curves are the more interesting results: the pH decreases with NiSO4 and increases with NiCl2. The classical approaches do not explain this difference. In this study we try to defend this idea: the difference of the counterions mobilities in their respective membranes explains the pH changes.</p></abstract><textClass><keywords scheme="keyword"><list><head>Keywords</head><item><term>Electrodialysis</term></item><item><term>pH changes</term></item><item><term>Selectivity</term></item><item><term>Cl− and SO4= comparison</term></item><item><term>Mobilities</term></item><item><term>Non-electroneutrality</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="2000">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/565B3C27DF0A5704360557BCD6382E14FEC95EA0/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: tail"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="fla"><item-info><jid>DES</jid><aid>00001491</aid><ce:pii>S0011-9164(00)00149-1</ce:pii><ce:doi>10.1016/S0011-9164(00)00149-1</ce:doi><ce:copyright type="unknown" year="2000"></ce:copyright></item-info><head><ce:article-footnote><ce:label>☆</ce:label><ce:note-para>Presented at the Conference on Membranes in Drinking and Industrial Water Production, Paris, France, 3–6 October 2000 International Water Association, European Desalination Society, American Water Works Association, Japan Water Works Association</ce:note-para></ce:article-footnote><ce:title>Comparison of the electrodialytic properties on NiSO<ce:inf>4</ce:inf> and NiCl<ce:inf>2</ce:inf>: Influence of the salt nature in electrodialysis</ce:title><ce:author-group><ce:author><ce:given-name>Kamel-Eddine</ce:given-name><ce:surname>Bouhidel</ce:surname><ce:cross-ref refid="COR1"><ce:sup>∗</ce:sup></ce:cross-ref><ce:cross-ref refid="AFF1"><ce:sup>a</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>Michel</ce:given-name><ce:surname>Rumeau</ce:surname><ce:cross-ref refid="AFF2"><ce:sup>b</ce:sup></ce:cross-ref></ce:author><ce:affiliation id="AFF1"><ce:label>a</ce:label><ce:textfn>Water Chemistry and Separation Techniques Laboratory, Science Faculty, Department of Chemistry, University of Batna, Algeria Fax +213 (4) 81 5375, +213 (4) 81 2480</ce:textfn></ce:affiliation><ce:affiliation id="AFF2"><ce:label>b</ce:label><ce:textfn>USTL Montpellier, France</ce:textfn></ce:affiliation><ce:correspondence id="COR1"><ce:label>∗</ce:label><ce:text>Corresponding author.</ce:text></ce:correspondence></ce:author-group><ce:date-received day="21" month="6" year="2000"></ce:date-received><ce:date-accepted day="5" month="7" year="2000"></ce:date-accepted><ce:abstract><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para>This research work compares the electrodialytic properties of NiSO<ce:inf>4</ce:inf> and NiCl<ce:inf>2</ce:inf> during a batch process. The current intensity-time, pH-time, water transport-time plottings are investigated. We try to answer the following questions: (1) Why do NiSO<ce:inf>4</ce:inf> and NiCl<ce:inf>2</ce:inf> present very different electrodialytic properties? (2) Is it possible to anticipate the electrodialytic behavior and properties of a given salt? (3) What are the salt basic properties that influence directly its electrodialytic behavior? The pH-time curves are the more interesting results: the pH decreases with NiSO<ce:inf>4</ce:inf> and increases with NiCl<ce:inf>2</ce:inf>. The classical approaches do not explain this difference. In this study we try to defend this idea: the difference of the counterions mobilities in their respective membranes explains the pH changes.</ce:simple-para></ce:abstract-sec></ce:abstract><ce:keywords><ce:section-title>Keywords</ce:section-title><ce:keyword><ce:text>Electrodialysis</ce:text></ce:keyword><ce:keyword><ce:text>pH changes</ce:text></ce:keyword><ce:keyword><ce:text>Selectivity</ce:text></ce:keyword><ce:keyword><ce:text>Cl<ce:sup>−</ce:sup> and SO<ce:inf>4</ce:inf><ce:sup>=</ce:sup> comparison</ce:text></ce:keyword><ce:keyword><ce:text>Mobilities</ce:text></ce:keyword><ce:keyword><ce:text>Non-electroneutrality</ce:text></ce:keyword></ce:keywords></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo><title>Comparison of the electrodialytic properties on NiSO4 and NiCl2: Influence of the salt nature in electrodialysis</title></titleInfo><titleInfo type="alternative" contentType="CDATA"><title>Comparison of the electrodialytic properties on NiSO</title></titleInfo><name type="personal"><namePart type="given">Kamel-Eddine</namePart><namePart type="family">Bouhidel</namePart><affiliation>Water Chemistry and Separation Techniques Laboratory, Science Faculty, Department of Chemistry, University of Batna, Algeria Fax +213 (4) 81 5375, +213 (4) 81 2480</affiliation><description>Corresponding author.</description><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Michel</namePart><namePart type="family">Rumeau</namePart><affiliation>USTL Montpellier, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article"></genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">2000</dateIssued><copyrightDate encoding="w3cdtf">2000</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="en">This research work compares the electrodialytic properties of NiSO4 and NiCl2 during a batch process. The current intensity-time, pH-time, water transport-time plottings are investigated. We try to answer the following questions: (1) Why do NiSO4 and NiCl2 present very different electrodialytic properties? (2) Is it possible to anticipate the electrodialytic behavior and properties of a given salt? (3) What are the salt basic properties that influence directly its electrodialytic behavior? The pH-time curves are the more interesting results: the pH decreases with NiSO4 and increases with NiCl2. The classical approaches do not explain this difference. In this study we try to defend this idea: the difference of the counterions mobilities in their respective membranes explains the pH changes.</abstract><note>Presented at the Conference on Membranes in Drinking and Industrial Water Production, Paris, France, 3–6 October 2000 International Water Association, European Desalination Society, American Water Works Association, Japan Water Works Association</note><subject><genre>Keywords</genre><topic>Electrodialysis</topic><topic>pH changes</topic><topic>Selectivity</topic><topic>Cl− and SO4= comparison</topic><topic>Mobilities</topic><topic>Non-electroneutrality</topic></subject><relatedItem type="host"><titleInfo><title>Desalination</title></titleInfo><titleInfo type="abbreviated"><title>DES</title></titleInfo><name type="conference"><namePart>Membranes in Drinking and Industrial Water Production, Paris, France</namePart><namePart type="date">20001003</namePart><namePart type="date">20001006</namePart></name><genre type="journal">journal</genre><originInfo><dateIssued encoding="w3cdtf">20001220</dateIssued></originInfo><identifier type="ISSN">0011-9164</identifier><identifier type="PII">S0011-9164(00)X0112-9</identifier><part><date>20001220</date><detail type="issue"><title>Membranes in Drinking and Industrial Water Production, Paris, France</title></detail><detail type="volume"><number>132</number><caption>vol.</caption></detail><detail type="issue"><number>1–3</number><caption>no.</caption></detail><extent unit="issue pages"><start>1</start><end>358</end></extent><extent unit="pages"><start>195</start><end>197</end></extent></part></relatedItem><identifier type="istex">565B3C27DF0A5704360557BCD6382E14FEC95EA0</identifier><identifier type="DOI">10.1016/S0011-9164(00)00149-1</identifier><identifier type="PII">S0011-9164(00)00149-1</identifier><recordInfo><recordContentSource>ELSEVIER</recordContentSource></recordInfo></mods></metadata></istex></record>Pour manipuler ce document sous Unix (Dilib)
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