Study of ion-selective evaporated calixarene film used as a sensitive layer on ISFET sensors
Identifieur interne : 000676 ( Istex/Checkpoint ); précédent : 000675; suivant : 000677Study of ion-selective evaporated calixarene film used as a sensitive layer on ISFET sensors
Auteurs : R. Mlika [Tunisie, France] ; H. Ben Ouada [Tunisie] ; N. Jaffrezic-Renault [France] ; I. Dumazet [France] ; R. Lamartine [France] ; M. Gamoudi [France] ; G. Guillaud [France]Source :
- Sensors & Actuators: B. Chemical [ 0925-4005 ] ; 1998.
Abstract
Thin calix[4]arene and calix[6]arene films were deposited using the technique of thermal evaporation under vacuum to fabricate chemical ion-selective field effect transistor (ISFET) microsensors. A high-performance liquid-phase chromatography (HPLC) method was used to verify the non-degradation of the calixarene layers, after the evaporation process. The sensing properties of these ionophores towards alkaline and heavy metal ions were tested. Both devices have shown Nernstian response and a wide working pH range. The former responded well to sodium ions and the latter to nickel ions, thus partial selectivity for these ions is shown. The improved lifetime membranes and sensitivity observed for these films indicates that these structures are worthy of further developments.
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DOI: 10.1016/S0925-4005(98)00006-9
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<front><div type="abstract" xml:lang="en">Thin calix[4]arene and calix[6]arene films were deposited using the technique of thermal evaporation under vacuum to fabricate chemical ion-selective field effect transistor (ISFET) microsensors. A high-performance liquid-phase chromatography (HPLC) method was used to verify the non-degradation of the calixarene layers, after the evaporation process. The sensing properties of these ionophores towards alkaline and heavy metal ions were tested. Both devices have shown Nernstian response and a wide working pH range. The former responded well to sodium ions and the latter to nickel ions, thus partial selectivity for these ions is shown. The improved lifetime membranes and sensitivity observed for these films indicates that these structures are worthy of further developments.</div>
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