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The effect of the temperature on the electrochemical properties of the hydrogen storage alloy for nickel-metal hydride accumulators

Identifieur interne : 000022 ( Hal/Corpus ); précédent : 000021; suivant : 000023

The effect of the temperature on the electrochemical properties of the hydrogen storage alloy for nickel-metal hydride accumulators

Auteurs : C. Khaldi ; S. Boussami ; M. Tliha ; A. Azizi ; N. Fenineche ; Omar El Kedim ; H. Mathlouthi ; J. Lamloumi

Source :

RBID : Hal:hal-00930877

Abstract

The electrochemical properties of The LaNi3.55Mn0.4Al0.3Co0.75 alloy as a negative electrode material of a nickel-metal hydride accumulator have been investigated at different temperatures. The Activation of the alloy becomes faster with an increasing temperature. The enthalpy, the entropy and the apparent activation energy of the LaNi3.55Mn0.4Al0.3Co0.75Hx hydride formation are evaluated. The calculated results show that the enthalpy change, the entropy change and the activation energy are (29 kJ mol1), (26.5 JK1 mol1) and (24.6 kJ mol1), respectively. The corrosion current density increases with increasing the temperature and the corrosion potential becomes more positive and increases linearly with the temperature. This result is confirmed by the values of corrosion film resistance and the corrosion film capacitance determined through the electrochemical spectroscopy impedance modeling.

Url:
DOI: 10.1016/j.jallcom.2013.04.046

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Hal:hal-00930877

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<div type="abstract" xml:lang="en">The electrochemical properties of The LaNi3.55Mn0.4Al0.3Co0.75 alloy as a negative electrode material of a nickel-metal hydride accumulator have been investigated at different temperatures. The Activation of the alloy becomes faster with an increasing temperature. The enthalpy, the entropy and the apparent activation energy of the LaNi3.55Mn0.4Al0.3Co0.75Hx hydride formation are evaluated. The calculated results show that the enthalpy change, the entropy change and the activation energy are (29 kJ mol1), (26.5 JK1 mol1) and (24.6 kJ mol1), respectively. The corrosion current density increases with increasing the temperature and the corrosion potential becomes more positive and increases linearly with the temperature. This result is confirmed by the values of corrosion film resistance and the corrosion film capacitance determined through the electrochemical spectroscopy impedance modeling.</div>
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<abstract xml:lang="en">The electrochemical properties of The LaNi3.55Mn0.4Al0.3Co0.75 alloy as a negative electrode material of a nickel-metal hydride accumulator have been investigated at different temperatures. The Activation of the alloy becomes faster with an increasing temperature. The enthalpy, the entropy and the apparent activation energy of the LaNi3.55Mn0.4Al0.3Co0.75Hx hydride formation are evaluated. The calculated results show that the enthalpy change, the entropy change and the activation energy are (29 kJ mol1), (26.5 JK1 mol1) and (24.6 kJ mol1), respectively. The corrosion current density increases with increasing the temperature and the corrosion potential becomes more positive and increases linearly with the temperature. This result is confirmed by the values of corrosion film resistance and the corrosion film capacitance determined through the electrochemical spectroscopy impedance modeling.</abstract>
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