Products from the oxidation of linear isomers of hexene.
Identifieur interne : 000045 ( PubMed/Corpus ); précédent : 000044; suivant : 000046Products from the oxidation of linear isomers of hexene.
Auteurs : Frédérique Battin-Leclerc ; Anne Rodriguez ; Benoit Husson ; Olivier Herbinet ; Pierre-Alexandre Glaude ; Zhandong Wang ; Zhanjun Cheng ; Fei QiSource :
- The journal of physical chemistry. A [ 1520-5215 ] ; 2014.
Abstract
The experimental study of the oxidation of the three linear isomers of hexene was performed in a quartz isothermal jet-stirred reactor (JSR) at temperatures ranging from 500 to 1100 K including the negative temperature coefficient (NTC) zone, at quasi-atmospheric pressure (1.07 bar), at a residence time of 2 s and with dilute stoichiometric mixtures. The fuel and reaction product mole fractions were measured using online gas chromatography. In the case of 1-hexene, the JSR has also been coupled through a molecular-beam sampling system to a reflectron time-of-flight mass spectrometer combined with tunable synchrotron vacuum ultraviolet photoionization. A difference of reactivity between the three fuels, which varies with the temperature range has been observed and is discussed according to the changes in the possible reaction pathways when the double bond is displaced. An enhanced importance of the reactions via the Waddington mechanism and of those of allylic radicals with HO2 radicals can be noted for 2- and 3-hexenes compared to 1-hexene.
DOI: 10.1021/jp4107102
PubMed: 24400665
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A</title><idno type="eISSN">1520-5215</idno><imprint><date when="2014" type="published">2014</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The experimental study of the oxidation of the three linear isomers of hexene was performed in a quartz isothermal jet-stirred reactor (JSR) at temperatures ranging from 500 to 1100 K including the negative temperature coefficient (NTC) zone, at quasi-atmospheric pressure (1.07 bar), at a residence time of 2 s and with dilute stoichiometric mixtures. The fuel and reaction product mole fractions were measured using online gas chromatography. In the case of 1-hexene, the JSR has also been coupled through a molecular-beam sampling system to a reflectron time-of-flight mass spectrometer combined with tunable synchrotron vacuum ultraviolet photoionization. A difference of reactivity between the three fuels, which varies with the temperature range has been observed and is discussed according to the changes in the possible reaction pathways when the double bond is displaced. An enhanced importance of the reactions via the Waddington mechanism and of those of allylic radicals with HO2 radicals can be noted for 2- and 3-hexenes compared to 1-hexene.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">24400665</PMID><DateCreated><Year>2014</Year><Month>01</Month><Day>30</Day></DateCreated><DateCompleted><Year>2014</Year><Month>09</Month><Day>17</Day></DateCompleted><DateRevised><Year>2014</Year><Month>09</Month><Day>17</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1520-5215</ISSN><JournalIssue CitedMedium="Internet"><Volume>118</Volume><Issue>4</Issue><PubDate><Year>2014</Year><Month>Jan</Month><Day>30</Day></PubDate></JournalIssue><Title>The journal of physical chemistry. A</Title><ISOAbbreviation>J Phys Chem A</ISOAbbreviation></Journal><ArticleTitle>Products from the oxidation of linear isomers of hexene.</ArticleTitle><Pagination><MedlinePgn>673-83</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1021/jp4107102</ELocationID><Abstract><AbstractText>The experimental study of the oxidation of the three linear isomers of hexene was performed in a quartz isothermal jet-stirred reactor (JSR) at temperatures ranging from 500 to 1100 K including the negative temperature coefficient (NTC) zone, at quasi-atmospheric pressure (1.07 bar), at a residence time of 2 s and with dilute stoichiometric mixtures. The fuel and reaction product mole fractions were measured using online gas chromatography. In the case of 1-hexene, the JSR has also been coupled through a molecular-beam sampling system to a reflectron time-of-flight mass spectrometer combined with tunable synchrotron vacuum ultraviolet photoionization. A difference of reactivity between the three fuels, which varies with the temperature range has been observed and is discussed according to the changes in the possible reaction pathways when the double bond is displaced. An enhanced importance of the reactions via the Waddington mechanism and of those of allylic radicals with HO2 radicals can be noted for 2- and 3-hexenes compared to 1-hexene.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Battin-Leclerc</LastName><ForeName>Frédérique</ForeName><Initials>F</Initials><AffiliationInfo><Affiliation>Laboratoire Réactions et Génie des Procédés, Université de Lorraine , CNRS, ENSIC, BP 20451, 1 rue Grandville, 54000 Nancy, France.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Rodriguez</LastName><ForeName>Anne</ForeName><Initials>A</Initials></Author><Author ValidYN="Y"><LastName>Husson</LastName><ForeName>Benoit</ForeName><Initials>B</Initials></Author><Author ValidYN="Y"><LastName>Herbinet</LastName><ForeName>Olivier</ForeName><Initials>O</Initials></Author><Author ValidYN="Y"><LastName>Glaude</LastName><ForeName>Pierre-Alexandre</ForeName><Initials>PA</Initials></Author><Author ValidYN="Y"><LastName>Wang</LastName><ForeName>Zhandong</ForeName><Initials>Z</Initials></Author><Author ValidYN="Y"><LastName>Cheng</LastName><ForeName>Zhanjun</ForeName><Initials>Z</Initials></Author><Author ValidYN="Y"><LastName>Qi</LastName><ForeName>Fei</ForeName><Initials>F</Initials></Author></AuthorList><Language>eng</Language><GrantList CompleteYN="Y"><Grant><GrantID>227669</GrantID><Agency>European Research Council</Agency><Country>International</Country></Grant></GrantList><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2014</Year><Month>01</Month><Day>14</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>J Phys Chem A</MedlineTA><NlmUniqueID>9890903</NlmUniqueID><ISSNLinking>1089-5639</ISSNLinking></MedlineJournalInfo><CommentsCorrectionsList><CommentsCorrections RefType="Cites"><RefSource>Angew Chem Int Ed Engl. 2010 Apr 19;49(18):3169-72</RefSource><PMID Version="1">20391420</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>J Phys Chem A. 2012 Jul 26;116(29):7603-14</RefSource><PMID Version="1">22712561</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Phys Chem Chem Phys. 2011 Jan 7;13(1):296-308</RefSource><PMID Version="1">21031192</PMID></CommentsCorrections></CommentsCorrectionsList><OtherID Source="NLM">EMS56210</OtherID><OtherID Source="NLM">PMC3908878</OtherID></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="aheadofprint"><Year>2014</Year><Month>1</Month><Day>14</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2014</Year><Month>1</Month><Day>10</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2014</Year><Month>1</Month><Day>10</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2014</Year><Month>1</Month><Day>10</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1021/jp4107102</ArticleId><ArticleId IdType="pubmed">24400665</ArticleId><ArticleId IdType="pmc">PMC3908878</ArticleId><ArticleId IdType="mid">EMS56210</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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