The origin of molecular mobility during biomass pyrolysis as revealed by in situ (1)H NMR spectroscopy.
Identifieur interne : 000060 ( PubMed/Checkpoint ); précédent : 000059; suivant : 000061The origin of molecular mobility during biomass pyrolysis as revealed by in situ (1)H NMR spectroscopy.
Auteurs : Anthony Dufour (génie des procédés) [France] ; Miguel Castro-Diaz ; Nicolas Brosse ; Mohamed Bouroukba ; Colin SnapeSource :
- ChemSusChem [ 1864-564X ] ; 2012.
Descripteurs français
- KwdFr :
- MESH :
- métabolisme : Biopolymères, Cellulose, Lignine, Minéraux, Xylanes.
- Biomasse, Biopolymères, Cellulose, Lignine, Minéraux, Poaceae, Protons, Spectroscopie par résonance magnétique, Température, Xylanes.
English descriptors
- KwdEn :
- Biomass, Biopolymers (chemistry), Biopolymers (metabolism), Cellulose (chemistry), Cellulose (metabolism), Lignin (chemistry), Lignin (metabolism), Magnetic Resonance Spectroscopy, Minerals (chemistry), Minerals (metabolism), Poaceae (chemistry), Protons, Temperature, Xylans (chemistry), Xylans (metabolism).
- MESH :
- chemical , chemistry : Biopolymers, Cellulose, Lignin, Minerals, Xylans.
- chemical , metabolism : Biopolymers, Cellulose, Lignin, Minerals, Xylans.
- chemistry : Poaceae.
- Biomass, Magnetic Resonance Spectroscopy, Protons, Temperature.
Abstract
The thermochemical conversion of lignocellulosic biomass feedstocks offers an important potential route for the production of biofuels and value-added green chemicals. Pyrolysis is the first phenomenon involved in all biomass thermochemical processes and it controls to a major extent the product composition. The composition of pyrolysis products can be affected markedly by the extent of softening that occurs. In spite of extensive work on biomass pyrolysis, the development of fluidity during the pyrolysis of biomass has not been quantified. This paper provides the first experimental investigation of proton mobility during biomass pyrolysis by in situ (1)H NMR spectroscopy. The origin of mobility is discussed for cellulose, lignin and xylan. The effect of minerals on cellulose mobility is also investigated. Interactions between polymers in the native biomass network are revealed by in situ (1)H NMR analysis.
DOI: 10.1002/cssc.201100442
PubMed: 22573541
Affiliations:
- France
- Grand Est, Lorraine (région)
- Nancy
- Centre national de la recherche scientifique, Laboratoire réactions et génie des procédés, Nancy-Université, Université de Lorraine
Links toward previous steps (curation, corpus...)
Links to Exploration step
pubmed:22573541Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">The origin of molecular mobility during biomass pyrolysis as revealed by in situ (1)H NMR spectroscopy.</title><author><name sortKey="Dufour, Anthony" sort="Dufour, Anthony" uniqKey="Dufour A" first="Anthony" last="Dufour">Anthony Dufour (génie des procédés)</name><affiliation wicri:level="4"><nlm:affiliation>Reactions and Processes Engineering Laboratory, CNRS, Nancy Université, ENSIC, 1 rue Grandville, B.P.20451, 54000 Nancy Cedex, France. anthony.dufour@ensic.inpl-nancy.fr</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Reactions and Processes Engineering Laboratory, CNRS, Nancy Université, ENSIC, 1 rue Grandville, B.P.20451, 54000 Nancy Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName><orgName type="university">Nancy-Université</orgName><placeName><settlement type="city">Nancy</settlement><region type="region" nuts="2">Grand Est</region><region type="region" nuts="2">Lorraine (région)</region></placeName><orgName type="laboratoire" n="5">Laboratoire réactions et génie des procédés</orgName><orgName type="university">Université de Lorraine</orgName><orgName type="institution">Centre national de la recherche scientifique</orgName></affiliation></author><author><name sortKey="Castro Diaz, Miguel" sort="Castro Diaz, Miguel" uniqKey="Castro Diaz M" first="Miguel" last="Castro-Diaz">Miguel Castro-Diaz</name></author><author><name sortKey="Brosse, Nicolas" sort="Brosse, Nicolas" uniqKey="Brosse N" first="Nicolas" last="Brosse">Nicolas Brosse</name></author><author><name sortKey="Bouroukba, Mohamed" sort="Bouroukba, Mohamed" uniqKey="Bouroukba M" first="Mohamed" last="Bouroukba">Mohamed Bouroukba</name></author><author><name sortKey="Snape, Colin" sort="Snape, Colin" uniqKey="Snape C" first="Colin" last="Snape">Colin Snape</name></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2012">2012</date><idno type="doi">10.1002/cssc.201100442</idno><idno type="RBID">pubmed:22573541</idno><idno type="pmid">22573541</idno><idno type="wicri:Area/PubMed/Corpus">000066</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000066</idno><idno type="wicri:Area/PubMed/Curation">000066</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000066</idno><idno type="wicri:Area/PubMed/Checkpoint">000066</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">000066</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">The origin of molecular mobility during biomass pyrolysis as revealed by in situ (1)H NMR spectroscopy.</title><author><name sortKey="Dufour, Anthony" sort="Dufour, Anthony" uniqKey="Dufour A" first="Anthony" last="Dufour">Anthony Dufour (génie des procédés)</name><affiliation wicri:level="4"><nlm:affiliation>Reactions and Processes Engineering Laboratory, CNRS, Nancy Université, ENSIC, 1 rue Grandville, B.P.20451, 54000 Nancy Cedex, France. anthony.dufour@ensic.inpl-nancy.fr</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Reactions and Processes Engineering Laboratory, CNRS, Nancy Université, ENSIC, 1 rue Grandville, B.P.20451, 54000 Nancy Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName><orgName type="university">Nancy-Université</orgName><placeName><settlement type="city">Nancy</settlement><region type="region" nuts="2">Grand Est</region><region type="region" nuts="2">Lorraine (région)</region></placeName><orgName type="laboratoire" n="5">Laboratoire réactions et génie des procédés</orgName><orgName type="university">Université de Lorraine</orgName><orgName type="institution">Centre national de la recherche scientifique</orgName></affiliation></author><author><name sortKey="Castro Diaz, Miguel" sort="Castro Diaz, Miguel" uniqKey="Castro Diaz M" first="Miguel" last="Castro-Diaz">Miguel Castro-Diaz</name></author><author><name sortKey="Brosse, Nicolas" sort="Brosse, Nicolas" uniqKey="Brosse N" first="Nicolas" last="Brosse">Nicolas Brosse</name></author><author><name sortKey="Bouroukba, Mohamed" sort="Bouroukba, Mohamed" uniqKey="Bouroukba M" first="Mohamed" last="Bouroukba">Mohamed Bouroukba</name></author><author><name sortKey="Snape, Colin" sort="Snape, Colin" uniqKey="Snape C" first="Colin" last="Snape">Colin Snape</name></author></analytic><series><title level="j">ChemSusChem</title><idno type="eISSN">1864-564X</idno><imprint><date when="2012" type="published">2012</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Biomass</term><term>Biopolymers (chemistry)</term><term>Biopolymers (metabolism)</term><term>Cellulose (chemistry)</term><term>Cellulose (metabolism)</term><term>Lignin (chemistry)</term><term>Lignin (metabolism)</term><term>Magnetic Resonance Spectroscopy</term><term>Minerals (chemistry)</term><term>Minerals (metabolism)</term><term>Poaceae (chemistry)</term><term>Protons</term><term>Temperature</term><term>Xylans (chemistry)</term><term>Xylans (metabolism)</term></keywords><keywords scheme="KwdFr" xml:lang="fr"><term>Biomasse</term><term>Biopolymères ()</term><term>Biopolymères (métabolisme)</term><term>Cellulose ()</term><term>Cellulose (métabolisme)</term><term>Lignine ()</term><term>Lignine (métabolisme)</term><term>Minéraux ()</term><term>Minéraux (métabolisme)</term><term>Poaceae ()</term><term>Protons</term><term>Spectroscopie par résonance magnétique</term><term>Température</term><term>Xylanes ()</term><term>Xylanes (métabolisme)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Biopolymers</term><term>Cellulose</term><term>Lignin</term><term>Minerals</term><term>Xylans</term></keywords><keywords scheme="MESH" type="chemical" qualifier="metabolism" xml:lang="en"><term>Biopolymers</term><term>Cellulose</term><term>Lignin</term><term>Minerals</term><term>Xylans</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Poaceae</term></keywords><keywords scheme="MESH" qualifier="métabolisme" xml:lang="fr"><term>Biopolymères</term><term>Cellulose</term><term>Lignine</term><term>Minéraux</term><term>Xylanes</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Biomass</term><term>Magnetic Resonance Spectroscopy</term><term>Protons</term><term>Temperature</term></keywords><keywords scheme="MESH" xml:lang="fr"><term>Biomasse</term><term>Biopolymères</term><term>Cellulose</term><term>Lignine</term><term>Minéraux</term><term>Poaceae</term><term>Protons</term><term>Spectroscopie par résonance magnétique</term><term>Température</term><term>Xylanes</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The thermochemical conversion of lignocellulosic biomass feedstocks offers an important potential route for the production of biofuels and value-added green chemicals. Pyrolysis is the first phenomenon involved in all biomass thermochemical processes and it controls to a major extent the product composition. The composition of pyrolysis products can be affected markedly by the extent of softening that occurs. In spite of extensive work on biomass pyrolysis, the development of fluidity during the pyrolysis of biomass has not been quantified. This paper provides the first experimental investigation of proton mobility during biomass pyrolysis by in situ (1)H NMR spectroscopy. The origin of mobility is discussed for cellulose, lignin and xylan. The effect of minerals on cellulose mobility is also investigated. Interactions between polymers in the native biomass network are revealed by in situ (1)H NMR analysis.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="MEDLINE"><PMID Version="1">22573541</PMID><DateCreated><Year>2012</Year><Month>07</Month><Day>04</Day></DateCreated><DateCompleted><Year>2012</Year><Month>11</Month><Day>23</Day></DateCompleted><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1864-564X</ISSN><JournalIssue CitedMedium="Internet"><Volume>5</Volume><Issue>7</Issue><PubDate><Year>2012</Year><Month>Jul</Month></PubDate></JournalIssue><Title>ChemSusChem</Title><ISOAbbreviation>ChemSusChem</ISOAbbreviation></Journal><ArticleTitle>The origin of molecular mobility during biomass pyrolysis as revealed by in situ (1)H NMR spectroscopy.</ArticleTitle><Pagination><MedlinePgn>1258-65</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1002/cssc.201100442</ELocationID><Abstract><AbstractText>The thermochemical conversion of lignocellulosic biomass feedstocks offers an important potential route for the production of biofuels and value-added green chemicals. Pyrolysis is the first phenomenon involved in all biomass thermochemical processes and it controls to a major extent the product composition. The composition of pyrolysis products can be affected markedly by the extent of softening that occurs. In spite of extensive work on biomass pyrolysis, the development of fluidity during the pyrolysis of biomass has not been quantified. This paper provides the first experimental investigation of proton mobility during biomass pyrolysis by in situ (1)H NMR spectroscopy. The origin of mobility is discussed for cellulose, lignin and xylan. The effect of minerals on cellulose mobility is also investigated. Interactions between polymers in the native biomass network are revealed by in situ (1)H NMR analysis.</AbstractText><CopyrightInformation>Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Dufour</LastName><ForeName>Anthony</ForeName><Initials>A</Initials><AffiliationInfo><Affiliation>Reactions and Processes Engineering Laboratory, CNRS, Nancy Université, ENSIC, 1 rue Grandville, B.P.20451, 54000 Nancy Cedex, France. anthony.dufour@ensic.inpl-nancy.fr</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Castro-Diaz</LastName><ForeName>Miguel</ForeName><Initials>M</Initials></Author><Author ValidYN="Y"><LastName>Brosse</LastName><ForeName>Nicolas</ForeName><Initials>N</Initials></Author><Author ValidYN="Y"><LastName>Bouroukba</LastName><ForeName>Mohamed</ForeName><Initials>M</Initials></Author><Author ValidYN="Y"><LastName>Snape</LastName><ForeName>Colin</ForeName><Initials>C</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType><PublicationType UI="D013485">Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2012</Year><Month>05</Month><Day>09</Day></ArticleDate></Article><MedlineJournalInfo><Country>Germany</Country><MedlineTA>ChemSusChem</MedlineTA><NlmUniqueID>101319536</NlmUniqueID><ISSNLinking>1864-5631</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D001704">Biopolymers</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D008903">Minerals</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D011522">Protons</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D014990">Xylans</NameOfSubstance></Chemical><Chemical><RegistryNumber>9004-34-6</RegistryNumber><NameOfSubstance UI="D002482">Cellulose</NameOfSubstance></Chemical><Chemical><RegistryNumber>9005-53-2</RegistryNumber><NameOfSubstance UI="D008031">Lignin</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName MajorTopicYN="Y" UI="D018533">Biomass</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D001704">Biopolymers</DescriptorName><QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName><QualifierName MajorTopicYN="N" UI="Q000378">metabolism</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D002482">Cellulose</DescriptorName><QualifierName MajorTopicYN="N" UI="Q000737">chemistry</QualifierName><QualifierName MajorTopicYN="N" UI="Q000378">metabolism</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D008031">Lignin</DescriptorName><QualifierName MajorTopicYN="N" UI="Q000737">chemistry</QualifierName><QualifierName MajorTopicYN="N" UI="Q000378">metabolism</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D009682">Magnetic Resonance Spectroscopy</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D008903">Minerals</DescriptorName><QualifierName MajorTopicYN="N" UI="Q000737">chemistry</QualifierName><QualifierName MajorTopicYN="N" UI="Q000378">metabolism</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D006109">Poaceae</DescriptorName><QualifierName MajorTopicYN="N" UI="Q000737">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D011522">Protons</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D013696">Temperature</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D014990">Xylans</DescriptorName><QualifierName MajorTopicYN="N" UI="Q000737">chemistry</QualifierName><QualifierName MajorTopicYN="N" UI="Q000378">metabolism</QualifierName></MeshHeading></MeshHeadingList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2011</Year><Month>8</Month><Day>9</Day></PubMedPubDate><PubMedPubDate PubStatus="revised"><Year>2011</Year><Month>12</Month><Day>12</Day></PubMedPubDate><PubMedPubDate PubStatus="aheadofprint"><Year>2012</Year><Month>5</Month><Day>9</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2012</Year><Month>5</Month><Day>11</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2012</Year><Month>5</Month><Day>11</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2012</Year><Month>12</Month><Day>10</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1002/cssc.201100442</ArticleId><ArticleId IdType="pubmed">22573541</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>France</li></country><region><li>Grand Est</li><li>Lorraine (région)</li></region><settlement><li>Nancy</li></settlement><orgName><li>Centre national de la recherche scientifique</li><li>Laboratoire réactions et génie des procédés</li><li>Nancy-Université</li><li>Université de Lorraine</li></orgName></list><tree><noCountry><name sortKey="Bouroukba, Mohamed" sort="Bouroukba, Mohamed" uniqKey="Bouroukba M" first="Mohamed" last="Bouroukba">Mohamed Bouroukba</name><name sortKey="Brosse, Nicolas" sort="Brosse, Nicolas" uniqKey="Brosse N" first="Nicolas" last="Brosse">Nicolas Brosse</name><name sortKey="Castro Diaz, Miguel" sort="Castro Diaz, Miguel" uniqKey="Castro Diaz M" first="Miguel" last="Castro-Diaz">Miguel Castro-Diaz</name><name sortKey="Snape, Colin" sort="Snape, Colin" uniqKey="Snape C" first="Colin" last="Snape">Colin Snape</name></noCountry><country name="France"><region name="Grand Est"><name sortKey="Dufour, Anthony" sort="Dufour, Anthony" uniqKey="Dufour A" first="Anthony" last="Dufour">Anthony Dufour (génie des procédés)</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Lorraine/explor/LrgpV1/Data/PubMed/Checkpoint
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000060 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/PubMed/Checkpoint/biblio.hfd -nk 000060 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Lorraine
|area= LrgpV1
|flux= PubMed
|étape= Checkpoint
|type= RBID
|clé= pubmed:22573541
|texte= The origin of molecular mobility during biomass pyrolysis as revealed by in situ (1)H NMR spectroscopy.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/PubMed/Checkpoint/RBID.i -Sk "pubmed:22573541" \
| HfdSelect -Kh $EXPLOR_AREA/Data/PubMed/Checkpoint/biblio.hfd \
| NlmPubMed2Wicri -a LrgpV1
| This area was generated with Dilib version V0.6.32. |  |