Methyl N-(3-cyanopicolinoyl)-l-tryptophanate
Identifieur interne : 000174 ( Pmc/Curation ); précédent : 000173; suivant : 000175Methyl N-(3-cyanopicolinoyl)-l-tryptophanate
Auteurs : Olga Ovdiichuk [Ukraine] ; Olga Hordiyenko [Ukraine] ; Zoia Voitenko [Ukraine] ; Axelle Arrault [France] ; Volodymyr Medviediev [Ukraine]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.
Abstract
In the title compound, C19H16N4O3, the stereocenter has an
Url:
DOI: 10.1107/S160053681303153X
PubMed: 24454241
PubMed Central: 3885065
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Methyl <italic>N</italic>-(3-cyanopicolinoyl)-<sc>l</sc>-tryptophanate</title><author><name sortKey="Ovdiichuk, Olga" sort="Ovdiichuk, Olga" uniqKey="Ovdiichuk O" first="Olga" last="Ovdiichuk">Olga Ovdiichuk</name><affiliation wicri:level="1"><nlm:aff id="a">Kyiv National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv,<country>Ukraine</country></nlm:aff><country xml:lang="fr">Ukraine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Hordiyenko, Olga" sort="Hordiyenko, Olga" uniqKey="Hordiyenko O" first="Olga" last="Hordiyenko">Olga Hordiyenko</name><affiliation wicri:level="1"><nlm:aff id="a">Kyiv National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv,<country>Ukraine</country></nlm:aff><country xml:lang="fr">Ukraine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Voitenko, Zoia" sort="Voitenko, Zoia" uniqKey="Voitenko Z" first="Zoia" last="Voitenko">Zoia Voitenko</name><affiliation wicri:level="1"><nlm:aff id="a">Kyiv National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv,<country>Ukraine</country></nlm:aff><country xml:lang="fr">Ukraine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Arrault, Axelle" sort="Arrault, Axelle" uniqKey="Arrault A" first="Axelle" last="Arrault">Axelle Arrault</name><affiliation wicri:level="1"><nlm:aff id="b">Laboratoire de Chimie Physique Macromoleculaire, UMR 7568, ENSIC, BP 451, 54001 Nancy,<country>France</country></nlm:aff><country xml:lang="fr">France</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Medviediev, Volodymyr" sort="Medviediev, Volodymyr" uniqKey="Medviediev V" first="Volodymyr" last="Medviediev">Volodymyr Medviediev</name><affiliation wicri:level="1"><nlm:aff id="c">STC "Institute for Single Crystals", National Academy of Science of Ukraine, Lenina ave. 60, 61001, Khar’kov,<country>Ukraine</country></nlm:aff><country xml:lang="fr">Ukraine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">24454241</idno><idno type="pmc">3885065</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885065</idno><idno type="RBID">PMC:3885065</idno><idno type="doi">10.1107/S160053681303153X</idno><date when="2013">2013</date><idno type="wicri:Area/Pmc/Corpus">000174</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000174</idno><idno type="wicri:Area/Pmc/Curation">000174</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000174</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Methyl <italic>N</italic>-(3-cyanopicolinoyl)-<sc>l</sc>-tryptophanate</title><author><name sortKey="Ovdiichuk, Olga" sort="Ovdiichuk, Olga" uniqKey="Ovdiichuk O" first="Olga" last="Ovdiichuk">Olga Ovdiichuk</name><affiliation wicri:level="1"><nlm:aff id="a">Kyiv National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv,<country>Ukraine</country></nlm:aff><country xml:lang="fr">Ukraine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Hordiyenko, Olga" sort="Hordiyenko, Olga" uniqKey="Hordiyenko O" first="Olga" last="Hordiyenko">Olga Hordiyenko</name><affiliation wicri:level="1"><nlm:aff id="a">Kyiv National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv,<country>Ukraine</country></nlm:aff><country xml:lang="fr">Ukraine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Voitenko, Zoia" sort="Voitenko, Zoia" uniqKey="Voitenko Z" first="Zoia" last="Voitenko">Zoia Voitenko</name><affiliation wicri:level="1"><nlm:aff id="a">Kyiv National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv,<country>Ukraine</country></nlm:aff><country xml:lang="fr">Ukraine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Arrault, Axelle" sort="Arrault, Axelle" uniqKey="Arrault A" first="Axelle" last="Arrault">Axelle Arrault</name><affiliation wicri:level="1"><nlm:aff id="b">Laboratoire de Chimie Physique Macromoleculaire, UMR 7568, ENSIC, BP 451, 54001 Nancy,<country>France</country></nlm:aff><country xml:lang="fr">France</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Medviediev, Volodymyr" sort="Medviediev, Volodymyr" uniqKey="Medviediev V" first="Volodymyr" last="Medviediev">Volodymyr Medviediev</name><affiliation wicri:level="1"><nlm:aff id="c">STC "Institute for Single Crystals", National Academy of Science of Ukraine, Lenina ave. 60, 61001, Khar’kov,<country>Ukraine</country></nlm:aff><country xml:lang="fr">Ukraine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2013">2013</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>In the title compound, C<sub>19</sub>H<sub>16</sub>N<sub>4</sub>O<sub>3</sub>, the stereocenter has an <sc>l</sc> configuration; <sc>l</sc>-tryptophan methyl ester hydrochloride being used as a starting material. The indole ring system and the pyridine ring are inclined to one another by 13.55 (14)°. In the crystal, adjacent molecules are linked <italic>via</italic> N—H⋯O hydrogen bonds, forming chains propagating along the <italic>c</italic>-axis direction.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="iso-abbrev">Acta Crystallogr Sect E Struct Rep Online</journal-id><journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id><journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title></journal-title-group><issn pub-type="epub">1600-5368</issn><publisher><publisher-name>International Union of Crystallography</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">24454241</article-id><article-id pub-id-type="pmc">3885065</article-id><article-id pub-id-type="publisher-id">su2666</article-id><article-id pub-id-type="doi">10.1107/S160053681303153X</article-id><article-id pub-id-type="coden">ACSEBH</article-id><article-id pub-id-type="pii">S160053681303153X</article-id><article-categories><subj-group subj-group-type="heading"><subject>Organic Papers</subject></subj-group></article-categories><title-group><article-title>Methyl <italic>N</italic>-(3-cyanopicolinoyl)-<sc>l</sc>-tryptophanate</article-title><alt-title><italic>C<sub>19</sub>H<sub>16</sub>N<sub>4</sub>O<sub>3</sub></italic></alt-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Ovdiichuk</surname><given-names>Olga</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Hordiyenko</surname><given-names>Olga</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Voitenko</surname><given-names>Zoia</given-names></name><xref ref-type="aff" rid="a">a</xref></contrib><contrib contrib-type="author"><name><surname>Arrault</surname><given-names>Axelle</given-names></name><xref ref-type="aff" rid="b">b</xref></contrib><contrib contrib-type="author"><name><surname>Medviediev</surname><given-names>Volodymyr</given-names></name><xref ref-type="aff" rid="c">c</xref><xref ref-type="corresp" rid="cor">*</xref></contrib><aff id="a"><label>a</label>Kyiv National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv,<country>Ukraine</country></aff><aff id="b"><label>b</label>Laboratoire de Chimie Physique Macromoleculaire, UMR 7568, ENSIC, BP 451, 54001 Nancy,<country>France</country></aff><aff id="c"><label>c</label>STC "Institute for Single Crystals", National Academy of Science of Ukraine, Lenina ave. 60, 61001, Khar’kov,<country>Ukraine</country></aff></contrib-group><author-notes><corresp id="cor">Correspondence e-mail: <email>vmedvedev@xray.isc.kharkov.com</email></corresp></author-notes><pub-date pub-type="collection"><day>01</day><month>12</month><year>2013</year></pub-date><pub-date pub-type="epub"><day>23</day><month>11</month><year>2013</year></pub-date><pub-date pub-type="pmc-release"><day>23</day><month>11</month><year>2013</year></pub-date><volume>69</volume><issue>Pt 12</issue><issue-id pub-id-type="publisher-id">e131200</issue-id><fpage>o1810</fpage><lpage>o1810</lpage><history><date date-type="received"><day>13</day><month>11</month><year>2013</year></date><date date-type="accepted"><day>19</day><month>11</month><year>2013</year></date></history><permissions><copyright-statement>© Ovdiichuk et al. 2013</copyright-statement><copyright-year>2013</copyright-year><license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p></license></permissions><self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S160053681303153X">A full version of this article is available from Crystallography Journals Online.</self-uri><abstract><p>In the title compound, C<sub>19</sub>H<sub>16</sub>N<sub>4</sub>O<sub>3</sub>, the stereocenter has an <sc>l</sc> configuration; <sc>l</sc>-tryptophan methyl ester hydrochloride being used as a starting material. The indole ring system and the pyridine ring are inclined to one another by 13.55 (14)°. In the crystal, adjacent molecules are linked <italic>via</italic> N—H⋯O hydrogen bonds, forming chains propagating along the <italic>c</italic>-axis direction.</p></abstract></article-meta></front><floats-group><table-wrap id="table1" position="float"><label>Table 1</label><caption><title>Hydrogen-bond geometry (Å, °)</title></caption><table frame="hsides" rules="groups"><thead valign="bottom"><tr><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H</th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom">H⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>⋯<italic>A</italic></th><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>—H⋯<italic>A</italic></th></tr></thead><tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">N4—H4⋯O1<sup>i</sup></td><td style="" rowspan="1" colspan="1" align="left" valign="top">0.86</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.29</td><td style="" rowspan="1" colspan="1" align="left" valign="top">2.987 (3)</td><td style="" rowspan="1" colspan="1" align="left" valign="top">138</td></tr></tbody></table><table-wrap-foot><p>Symmetry code: (i) <inline-formula><inline-graphic xlink:href="e-69-o1810-efi2.jpg" mimetype="image" mime-subtype="gif"></inline-graphic></inline-formula>.</p></table-wrap-foot></table-wrap></floats-group></pmc></record>Pour manipuler ce document sous Unix (Dilib)
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