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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Experimental study of the oxidation of methyl oleate in a jet-stirred reactor</title><author><name sortKey="Bax, Sarah" sort="Bax, Sarah" uniqKey="Bax S" first="Sarah" last="Bax">Sarah Bax</name><affiliation><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff></affiliation></author><author><name sortKey="Hakka, Mohammed Hichem" sort="Hakka, Mohammed Hichem" uniqKey="Hakka M" first="Mohammed Hichem" last="Hakka">Mohammed Hichem Hakka</name><affiliation><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff></affiliation></author><author><name sortKey="Glaude, Pierre Alexandre" sort="Glaude, Pierre Alexandre" uniqKey="Glaude P" first="Pierre-Alexandre" last="Glaude">Pierre-Alexandre Glaude</name><affiliation><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff></affiliation></author><author><name sortKey="Herbinet, Olivier" sort="Herbinet, Olivier" uniqKey="Herbinet O" first="Olivier" last="Herbinet">Olivier Herbinet</name><affiliation><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff></affiliation></author><author><name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name><affiliation><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">23710077</idno><idno type="pmc">3662212</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3662212</idno><idno type="RBID">PMC:3662212</idno><idno type="doi">10.1016/j.combustflame.2009.12.008</idno><date when="2010">2010</date><idno type="wicri:Area/Pmc/Corpus">000167</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000167</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Experimental study of the oxidation of methyl oleate in a jet-stirred reactor</title><author><name sortKey="Bax, Sarah" sort="Bax, Sarah" uniqKey="Bax S" first="Sarah" last="Bax">Sarah Bax</name><affiliation><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff></affiliation></author><author><name sortKey="Hakka, Mohammed Hichem" sort="Hakka, Mohammed Hichem" uniqKey="Hakka M" first="Mohammed Hichem" last="Hakka">Mohammed Hichem Hakka</name><affiliation><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff></affiliation></author><author><name sortKey="Glaude, Pierre Alexandre" sort="Glaude, Pierre Alexandre" uniqKey="Glaude P" first="Pierre-Alexandre" last="Glaude">Pierre-Alexandre Glaude</name><affiliation><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff></affiliation></author><author><name sortKey="Herbinet, Olivier" sort="Herbinet, Olivier" uniqKey="Herbinet O" first="Olivier" last="Herbinet">Olivier Herbinet</name><affiliation><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff></affiliation></author><author><name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name><affiliation><nlm:aff id="A1">Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</nlm:aff></affiliation></author></analytic><series><title level="j">Combustion and flame</title><idno type="ISSN">0010-2180</idno><idno type="eISSN">1556-2921</idno><imprint><date when="2010">2010</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p id="P1">The experimental study of the oxidation of a blend containing n-decane and a large unsaturated ester, methyl oleate, was performed in a jet-stirred reactor over a wide range of temperature covering both low and high temperature regions (550–1100 K), at a residence time of 1.5 s, at quasi atmospheric pressure with high dilution in helium (n-decane and methyl oleate inlet mole fractions of 1.48 × 10<sup>−3</sup> and 5.2 × 10<sup>−4</sup>) and under stoichiometric conditions.</p><p id="P2">The formation of numerous reaction products was observed. At low and intermediate temperatures, the oxidation of the blend led to the formation of species containing oxygen atoms like cyclic ethers, aldehydes and ketones deriving from n-decane and methyl oleate. At higher temperature, these species were not formed anymore and the presence of unsaturated species was observed. Because of the presence of the double bond in the middle of the alkyl chain of methyl oleate, the formation of some specific products was observed. These species are dienes and esters with two double bonds produced from the decomposition paths of methyl oleate and some species obtained from the addition of H-atoms, OH and HO<sub>2</sub> radicals to the double bond.</p><p id="P3">Experimental results were compared with former results of the oxidation of a blend of n-decane and methyl palmitate performed under similar conditions. This comparison allowed highlighting the similarities and the differences in the reactivity and in the distribution of the reaction products for the oxidation of large saturated and unsaturated esters.</p></div></front></TEI><pmc article-type="research-article"><pmc-comment>The publisher of this article does not allow downloading of the full text in XML form.</pmc-comment>
<pmc-dir>properties manuscript</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-journal-id">9891739</journal-id><journal-id journal-id-type="pubmed-jr-id">41274</journal-id><journal-id journal-id-type="nlm-ta">Combust Flame</journal-id><journal-id journal-id-type="iso-abbrev">Combust Flame</journal-id><journal-title-group><journal-title>Combustion and flame</journal-title></journal-title-group><issn pub-type="ppub">0010-2180</issn><issn pub-type="epub">1556-2921</issn></journal-meta><article-meta><article-id pub-id-type="pmid">23710077</article-id><article-id pub-id-type="pmc">3662212</article-id><article-id pub-id-type="doi">10.1016/j.combustflame.2009.12.008</article-id><article-id pub-id-type="manuscript">EMS52084</article-id><article-categories><subj-group subj-group-type="heading"><subject>Article</subject></subj-group></article-categories><title-group><article-title>Experimental study of the oxidation of methyl oleate in a jet-stirred reactor</article-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Bax</surname><given-names>Sarah</given-names></name><xref ref-type="aff" rid="A1">a</xref></contrib><contrib contrib-type="author"><name><surname>Hakka</surname><given-names>Mohammed Hichem</given-names></name><xref ref-type="aff" rid="A1">a</xref></contrib><contrib contrib-type="author"><name><surname>Glaude</surname><given-names>Pierre-Alexandre</given-names></name><xref ref-type="aff" rid="A1">a</xref></contrib><contrib contrib-type="author"><name><surname>Herbinet</surname><given-names>Olivier</given-names></name><xref ref-type="aff" rid="A1">a</xref><xref ref-type="corresp" rid="CR1">*</xref></contrib><contrib contrib-type="author"><name><surname>Battin-Leclerc</surname><given-names>Frédérique</given-names></name><xref ref-type="aff" rid="A1">a</xref></contrib></contrib-group><aff id="A1"><label>a</label>Laboratoire Réactions et Génie des Procédés, Nancy Université, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</aff><author-notes><corresp id="CR1"><label>*</label>Corresponding author: Olivier Herbinet, Laboratoire Réactions et Génie des Procédés, CNRS UPR 3349, Nancy-Université, ENSIC, 1 rue Grandville, BP 20451, 54001 Nancy Cedex, France. Tel : +33 3 83 17 53 60 ; Fax : +33 3 83 37 81 20 <email>olivier.herbinet@ensic.inpl-nancy.fr</email></corresp></author-notes><pub-date pub-type="nihms-submitted"><day>9</day><month>5</month><year>2013</year></pub-date><pub-date pub-type="ppub"><month>6</month><year>2010</year></pub-date><pub-date pub-type="pmc-release"><day>23</day><month>5</month><year>2013</year></pub-date><volume>157</volume><issue>6</issue><fpage>1220</fpage><lpage>1229</lpage><self-uri xlink:href="http://www.sciencedirect.com/science/article/pii/S0010218009003538"></self-uri><abstract><p id="P1">The experimental study of the oxidation of a blend containing n-decane and a large unsaturated ester, methyl oleate, was performed in a jet-stirred reactor over a wide range of temperature covering both low and high temperature regions (550–1100 K), at a residence time of 1.5 s, at quasi atmospheric pressure with high dilution in helium (n-decane and methyl oleate inlet mole fractions of 1.48 × 10<sup>−3</sup> and 5.2 × 10<sup>−4</sup>) and under stoichiometric conditions.</p><p id="P2">The formation of numerous reaction products was observed. At low and intermediate temperatures, the oxidation of the blend led to the formation of species containing oxygen atoms like cyclic ethers, aldehydes and ketones deriving from n-decane and methyl oleate. At higher temperature, these species were not formed anymore and the presence of unsaturated species was observed. Because of the presence of the double bond in the middle of the alkyl chain of methyl oleate, the formation of some specific products was observed. These species are dienes and esters with two double bonds produced from the decomposition paths of methyl oleate and some species obtained from the addition of H-atoms, OH and HO<sub>2</sub> radicals to the double bond.</p><p id="P3">Experimental results were compared with former results of the oxidation of a blend of n-decane and methyl palmitate performed under similar conditions. This comparison allowed highlighting the similarities and the differences in the reactivity and in the distribution of the reaction products for the oxidation of large saturated and unsaturated esters.</p></abstract><kwd-group><kwd>Oxidation</kwd><kwd>Combustion</kwd><kwd>Biodiesel</kwd><kwd>Methyl esters</kwd><kwd>Methyl oleate</kwd><kwd>Methyl palmitate</kwd><kwd>Jet-stirred reactor</kwd><kwd>Engine</kwd><kwd>Kinetics</kwd></kwd-group><funding-group><award-group><funding-source country="International">European Research Council : </funding-source><award-id>227669 || ERC_</award-id></award-group></funding-group></article-meta></front></pmc></record>Pour manipuler ce document sous Unix (Dilib)
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