Quantification of hydrogen peroxide during the low-temperature oxidation of alkanes
Identifieur interne : 000155 ( Pmc/Corpus ); précédent : 000154; suivant : 000156Quantification of hydrogen peroxide during the low-temperature oxidation of alkanes
Auteurs : Chiheb Bahrini ; Olivier Herbinet ; Pierre-Alexandre Glaude ; Coralie Schoemaecker ; Christa Fittschen ; Frédérique Battin-LeclercSource :
- Journal of the American Chemical Society [ 0002-7863 ] ; 2012.
Abstract
The first reliable quantification of hydrogen peroxide (H2O2) formed during the low temperature oxidation of an organic compound has been achieved thanks to a new system that couples a jet stirred reactor to a detection by continuous wave cavity ring-down spectroscopy (cw-CRDS) in the near infrared. The quantification of this key compound for hydrocarbon low-temperature oxidation regime has been obtained under conditions close to those actually observed before the autoignition. The studied hydrocarbon was
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DOI: 10.1021/ja305200h
PubMed: 22746212
PubMed Central: 3586669
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PMC:3586669Le document en format XML
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<author><name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name>
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<author><name sortKey="Battin Leclerc, Frederique" sort="Battin Leclerc, Frederique" uniqKey="Battin Leclerc F" first="Frédérique" last="Battin-Leclerc">Frédérique Battin-Leclerc</name>
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<series><title level="j">Journal of the American Chemical Society</title>
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<front><div type="abstract" xml:lang="en"><p id="P1">The first reliable quantification of hydrogen peroxide (H<sub>2</sub>
O<sub>2</sub>
) formed during the low temperature oxidation of an organic compound has been achieved thanks to a new system that couples a jet stirred reactor to a detection by continuous wave cavity ring-down spectroscopy (cw-CRDS) in the near infrared. The quantification of this key compound for hydrocarbon low-temperature oxidation regime has been obtained under conditions close to those actually observed before the autoignition. The studied hydrocarbon was <italic>n</italic>
-butane, the smallest alkane which has an oxidation behaviour close to that of the species present in gasoline and diesel fuels.</p>
</div>
</front>
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<pmc article-type="research-article"><pmc-comment>The publisher of this article does not allow downloading of the full text in XML form.</pmc-comment>
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<front><journal-meta><journal-id journal-id-type="nlm-journal-id">7503056</journal-id>
<journal-id journal-id-type="pubmed-jr-id">4435</journal-id>
<journal-id journal-id-type="nlm-ta">J Am Chem Soc</journal-id>
<journal-id journal-id-type="iso-abbrev">J. Am. Chem. Soc.</journal-id>
<journal-title-group><journal-title>Journal of the American Chemical Society</journal-title>
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<article-categories><subj-group subj-group-type="heading"><subject>Article</subject>
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<title-group><article-title>Quantification of hydrogen peroxide during the low-temperature oxidation of alkanes</article-title>
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<contrib-group><contrib contrib-type="author"><name><surname>Bahrini</surname>
<given-names>Chiheb</given-names>
</name>
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<contrib contrib-type="author"><name><surname>Herbinet</surname>
<given-names>Olivier</given-names>
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<xref ref-type="aff" rid="A1">#</xref>
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<contrib contrib-type="author"><name><surname>Glaude</surname>
<given-names>Pierre-Alexandre</given-names>
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<contrib contrib-type="author"><name><surname>Schoemaecker</surname>
<given-names>Coralie</given-names>
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<xref ref-type="aff" rid="A2">$</xref>
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<contrib contrib-type="author"><name><surname>Fittschen</surname>
<given-names>Christa</given-names>
</name>
<xref ref-type="aff" rid="A2">$</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Battin-Leclerc</surname>
<given-names>Frédérique</given-names>
</name>
<xref ref-type="aff" rid="A1">#</xref>
<xref ref-type="corresp" rid="CR1">*</xref>
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<aff id="A1"><label>#</label>
LRGP, Université de Lorraine, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France</aff>
<aff id="A2"><label>$</label>
PC2A, University Lille 1, CNRS, Cité Scientifique, Bât. C11, 59655 Villeneuve d’Ascq, France</aff>
<author-notes><corresp id="CR1"><label>*</label>
<bold>Corresponding Author</bold>
: <email>Frederique.Battin-Leclerc@ensic.inpl-nancy.fr</email>
</corresp>
</author-notes>
<pub-date pub-type="nihms-submitted"><day>22</day>
<month>2</month>
<year>2013</year>
</pub-date>
<pub-date pub-type="epub"><day>12</day>
<month>7</month>
<year>2012</year>
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<pub-date pub-type="ppub"><day>25</day>
<month>7</month>
<year>2012</year>
</pub-date>
<pub-date pub-type="pmc-release"><day>04</day>
<month>3</month>
<year>2013</year>
</pub-date>
<volume>134</volume>
<issue>29</issue>
<fpage>11944</fpage>
<lpage>11947</lpage>
<abstract><p id="P1">The first reliable quantification of hydrogen peroxide (H<sub>2</sub>
O<sub>2</sub>
) formed during the low temperature oxidation of an organic compound has been achieved thanks to a new system that couples a jet stirred reactor to a detection by continuous wave cavity ring-down spectroscopy (cw-CRDS) in the near infrared. The quantification of this key compound for hydrocarbon low-temperature oxidation regime has been obtained under conditions close to those actually observed before the autoignition. The studied hydrocarbon was <italic>n</italic>
-butane, the smallest alkane which has an oxidation behaviour close to that of the species present in gasoline and diesel fuels.</p>
</abstract>
<kwd-group><kwd>Hydrogen peroxide</kwd>
<kwd>alkane oxidation</kwd>
<kwd>jet stirred reactor</kwd>
<kwd>cavity ring down spectroscopy</kwd>
</kwd-group>
<funding-group><award-group><funding-source country="International">European Research Council : </funding-source>
<award-id>227669 || ERC_</award-id>
</award-group>
</funding-group>
</article-meta>
</front>
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