LrgpV1, PascalFrancis, Corpus, bibRecord, 000066

Selectivity of Bio-oils Catalytic Hydrotreatment Assessed by Petroleomic and GC*GC/MS-FID Analysis

Identifieur interne : 000066 ( PascalFrancis/Corpus ); précédent : 000065; suivant : 000067

Selectivity of Bio-oils Catalytic Hydrotreatment Assessed by Petroleomic and GC*GC/MS-FID Analysis

Auteurs : Roberto Olcese ; Vincent Carre ; Frédéric Aubriet ; Anthony Dufour

Source :

Energy & fuels [ 0887-0624 ] ; 2013.

RBID : Pascal:13-0168162

Descripteurs français

Pascal (Inist)
- Hydrotraitement, Sélectivité catalyseur, Haute résolution, Spectrométrie masse, Transformation Fourier, Résonance cyclotronique, Détecteur ionisation flamme, Méthanol, Lignine, Pyrolyse, Fer, Catalyseur sur support, Norme, Désorption laser, Ionisation, Lit fixe, Silice, Charbon actif, Teneur oxygène, Oligomère.

English descriptors

KwdEn :
- Activated carbon, Catalyst selectivity, Cyclotron resonance, Fixed bed, Flame ionization detector, Fourier transformation, High resolution, Hydrotreating, Ionization, Iron, Laser desorption, Lignin, Mass spectrometry, Methanol, Oligomer, Oxygen content, Pyrolysis, Silica, Standards, Supported catalyst.

Abstract

We propose to assess the selectivity of hydrotreatment catalysts by two complementary analytical methods: (1) high-resolution mass spectrometry (MS), called "petroleomic" analysis, by Fourier transform ion cyclotron resonance (FT ICR, 9.4T) MS for species heavier than m/z of about 200 Da and (2) quantitative GC^*GC (heart-cutting)/MS-flame ionization detector (FID) analysis of lighter species. The methodology is illustrated on methanol-soluble bio-oils produced by lignin pyrolysis and hydrotreated by iron-based catalysts. GC^*GC analysis is calibrated by a combination of internal standard and prediction of response factors on the FID. Laser desorption ionization (LDI) and electro spray ionization (ESI) in negative-ion mode are combined for the petroleomic analysis. The selectivity of hydrotreatment (catalytic fixed bed, 1 atm, 400 °C) is assessed as a function of catalyst loads and iron support (silica and activated carbon). Hundreds of species are analyzed by GC^*GC and petroleomic and mapped in Van Krevelen diagrams. The high selectivity of reduced iron for the hydrodeoxygenation of lignin pyrolysis vapors is demonstrated. The effect of the catalytic treatment on oxygen content and unsaturation is studied for a broad range of species: from C₂ to C₁₄ by GC analysis and from C₈ to C₃₇ by petroleomic. Many heavy lignin oligomers produced by the pyrolysis are trapped by the catalytic bed, highlighting the need of new catalytic systems to convert them into valuable fuels or chemicals.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

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A11	`01`	`1`		`@1 OLCESE (Roberto)`
A11	`02`	`1`		`@1 CARRE (Vincent)`
A11	`03`	`1`		`@1 AUBRIET (Frédéric)`
A11	`04`	`1`		`@1 DUFOUR (Anthony)`
A14	`01`			`@1 Reactions and Processes Engineering Laboratory, CNRS, Lorraine University, ENSIC, 1 rue Grandville @2 54000 Nancy @3 FRA @Z 1 aut. @Z 4 aut.`
A14	`02`			`@1 Laboratoire Chimie et de Physique des Milieux Complexes, Lorraine University, ICPM, 1 Boulevard Arago @2 57078 Metz @3 FRA @Z 2 aut. @Z 3 aut.`
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A44				`@0 0000 @1 © 2013 INIST-CNRS. All rights reserved.`
A45				`@0 59 ref.`
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C01	`01`		`ENG`	@0 We propose to assess the selectivity of hydrotreatment catalysts by two complementary analytical methods: (1) high-resolution mass spectrometry (MS), called "petroleomic" analysis, by Fourier transform ion cyclotron resonance (FT ICR, 9.4T) MS for species heavier than m/z of about 200 Da and (2) quantitative GC^GC (heart-cutting)/MS-flame ionization detector (FID) analysis of lighter species. The methodology is illustrated on methanol-soluble bio-oils produced by lignin pyrolysis and hydrotreated by iron-based catalysts. GC^GC analysis is calibrated by a combination of internal standard and prediction of response factors on the FID. Laser desorption ionization (LDI) and electro spray ionization (ESI) in negative-ion mode are combined for the petroleomic analysis. The selectivity of hydrotreatment (catalytic fixed bed, 1 atm, 400 °C) is assessed as a function of catalyst loads and iron support (silica and activated carbon). Hundreds of species are analyzed by GC^*GC and petroleomic and mapped in Van Krevelen diagrams. The high selectivity of reduced iron for the hydrodeoxygenation of lignin pyrolysis vapors is demonstrated. The effect of the catalytic treatment on oxygen content and unsaturation is studied for a broad range of species: from C₂ to C₁₄ by GC analysis and from C₈ to C₃₇ by petroleomic. Many heavy lignin oligomers produced by the pyrolysis are trapped by the catalytic bed, highlighting the need of new catalytic systems to convert them into valuable fuels or chemicals.
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C03	`01`	`X`	`ENG`	`@0 Hydrotreating @5 05`
C03	`01`	`X`	`SPA`	`@0 Hidrotratamiento @5 05`
C03	`02`	`X`	`FRE`	`@0 Sélectivité catalyseur @5 06`
C03	`02`	`X`	`ENG`	`@0 Catalyst selectivity @5 06`
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C03	`06`	`X`	`FRE`	`@0 Résonance cyclotronique @5 10`
C03	`06`	`X`	`ENG`	`@0 Cyclotron resonance @5 10`
C03	`06`	`X`	`SPA`	`@0 Resonancia ciclotrónica @5 10`
C03	`07`	`X`	`FRE`	`@0 Détecteur ionisation flamme @5 11`
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C03	`07`	`X`	`SPA`	`@0 Detector ionización por llama @5 11`
C03	`08`	`X`	`FRE`	`@0 Méthanol @2 NK @2 FX @5 12`
C03	`08`	`X`	`ENG`	`@0 Methanol @2 NK @2 FX @5 12`
C03	`08`	`X`	`SPA`	`@0 Metanol @2 NK @2 FX @5 12`
C03	`09`	`X`	`FRE`	`@0 Lignine @5 13`
C03	`09`	`X`	`ENG`	`@0 Lignin @5 13`
C03	`09`	`X`	`SPA`	`@0 Lignina @5 13`
C03	`10`	`X`	`FRE`	`@0 Pyrolyse @5 14`
C03	`10`	`X`	`ENG`	`@0 Pyrolysis @5 14`
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C03	`13`	`X`	`SPA`	`@0 Norma @5 17`
C03	`14`	`X`	`FRE`	`@0 Désorption laser @5 18`
C03	`14`	`X`	`ENG`	`@0 Laser desorption @5 18`
C03	`14`	`X`	`SPA`	`@0 Desorción láser @5 18`
C03	`15`	`X`	`FRE`	`@0 Ionisation @5 19`
C03	`15`	`X`	`ENG`	`@0 Ionization @5 19`
C03	`15`	`X`	`SPA`	`@0 Ionización @5 19`
C03	`16`	`X`	`FRE`	`@0 Lit fixe @5 20`
C03	`16`	`X`	`ENG`	`@0 Fixed bed @5 20`
C03	`16`	`X`	`SPA`	`@0 Lecho fijo @5 20`
C03	`17`	`X`	`FRE`	`@0 Silice @2 NK @2 FX @5 21`
C03	`17`	`X`	`ENG`	`@0 Silica @2 NK @2 FX @5 21`
C03	`17`	`X`	`SPA`	`@0 Sílice @2 NK @2 FX @5 21`
C03	`18`	`X`	`FRE`	`@0 Charbon actif @5 22`
C03	`18`	`X`	`ENG`	`@0 Activated carbon @5 22`
C03	`18`	`X`	`SPA`	`@0 Carbón activado @5 22`
C03	`19`	`X`	`FRE`	`@0 Teneur oxygène @5 23`
C03	`19`	`X`	`ENG`	`@0 Oxygen content @5 23`
C03	`19`	`X`	`SPA`	`@0 Contenido oxígeno @5 23`
C03	`20`	`X`	`FRE`	`@0 Oligomère @5 24`
C03	`20`	`X`	`ENG`	`@0 Oligomer @5 24`
C03	`20`	`X`	`SPA`	`@0 Oligómero @5 24`
N21				`@1 147`
N44	`01`			`@1 OTO`
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Format Inist (serveur)

NO :	PASCAL 13-0168162 INIST
ET :	Selectivity of Bio-oils Catalytic Hydrotreatment Assessed by Petroleomic and GC^*GC/MS-FID Analysis
AU :	OLCESE (Roberto); CARRE (Vincent); AUBRIET (Frédéric); DUFOUR (Anthony)
AF :	Reactions and Processes Engineering Laboratory, CNRS, Lorraine University, ENSIC, 1 rue Grandville/54000 Nancy/France (1 aut., 4 aut.); Laboratoire Chimie et de Physique des Milieux Complexes, Lorraine University, ICPM, 1 Boulevard Arago/57078 Metz/France (2 aut., 3 aut.)
DT :	Publication en série; Niveau analytique
SO :	Energy & fuels; ISSN 0887-0624; Coden ENFUEM; Etats-Unis; Da. 2013; Vol. 27; No. MARAVR; Pp. 2135-2145; Bibl. 59 ref.
LA :	Anglais
EA :	We propose to assess the selectivity of hydrotreatment catalysts by two complementary analytical methods: (1) high-resolution mass spectrometry (MS), called "petroleomic" analysis, by Fourier transform ion cyclotron resonance (FT ICR, 9.4T) MS for species heavier than m/z of about 200 Da and (2) quantitative GC^GC (heart-cutting)/MS-flame ionization detector (FID) analysis of lighter species. The methodology is illustrated on methanol-soluble bio-oils produced by lignin pyrolysis and hydrotreated by iron-based catalysts. GC^GC analysis is calibrated by a combination of internal standard and prediction of response factors on the FID. Laser desorption ionization (LDI) and electro spray ionization (ESI) in negative-ion mode are combined for the petroleomic analysis. The selectivity of hydrotreatment (catalytic fixed bed, 1 atm, 400 °C) is assessed as a function of catalyst loads and iron support (silica and activated carbon). Hundreds of species are analyzed by GC^*GC and petroleomic and mapped in Van Krevelen diagrams. The high selectivity of reduced iron for the hydrodeoxygenation of lignin pyrolysis vapors is demonstrated. The effect of the catalytic treatment on oxygen content and unsaturation is studied for a broad range of species: from C₂ to C₁₄ by GC analysis and from C₈ to C₃₇ by petroleomic. Many heavy lignin oligomers produced by the pyrolysis are trapped by the catalytic bed, highlighting the need of new catalytic systems to convert them into valuable fuels or chemicals.
CC :	001D06B02D; 001D06D; 230
FD :	Hydrotraitement; Sélectivité catalyseur; Haute résolution; Spectrométrie masse; Transformation Fourier; Résonance cyclotronique; Détecteur ionisation flamme; Méthanol; Lignine; Pyrolyse; Fer; Catalyseur sur support; Norme; Désorption laser; Ionisation; Lit fixe; Silice; Charbon actif; Teneur oxygène; Oligomère
ED :	Hydrotreating; Catalyst selectivity; High resolution; Mass spectrometry; Fourier transformation; Cyclotron resonance; Flame ionization detector; Methanol; Lignin; Pyrolysis; Iron; Supported catalyst; Standards; Laser desorption; Ionization; Fixed bed; Silica; Activated carbon; Oxygen content; Oligomer
SD :	Hidrotratamiento; Selectividad catalizador; Alta resolucion; Espectrometría masa; Transformación Fourier; Resonancia ciclotrónica; Detector ionización por llama; Metanol; Lignina; Pirólisis; Hierro; Catalizador sobre soporte; Norma; Desorción láser; Ionización; Lecho fijo; Sílice; Carbón activado; Contenido oxígeno; Oligómero
LO :	INIST-21106.354000503775721020
ID :	13-0168162

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Pascal:13-0168162

Le document en format XML

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<front><div type="abstract" xml:lang="en">We propose to assess the selectivity of hydrotreatment catalysts by two complementary analytical methods: (1) high-resolution mass spectrometry (MS), called "petroleomic" analysis, by Fourier transform ion cyclotron resonance (FT ICR, 9.4T) MS for species heavier than m/z of about 200 Da and (2) quantitative GC<sup>*</sup>
GC (heart-cutting)/MS-flame ionization detector (FID) analysis of lighter species. The methodology is illustrated on methanol-soluble bio-oils produced by lignin pyrolysis and hydrotreated by iron-based catalysts. GC<sup>*</sup>
GC analysis is calibrated by a combination of internal standard and prediction of response factors on the FID. Laser desorption ionization (LDI) and electro spray ionization (ESI) in negative-ion mode are combined for the petroleomic analysis. The selectivity of hydrotreatment (catalytic fixed bed, 1 atm, 400 °C) is assessed as a function of catalyst loads and iron support (silica and activated carbon). Hundreds of species are analyzed by GC<sup>*</sup>
GC and petroleomic and mapped in Van Krevelen diagrams. The high selectivity of reduced iron for the hydrodeoxygenation of lignin pyrolysis vapors is demonstrated. The effect of the catalytic treatment on oxygen content and unsaturation is studied for a broad range of species: from C<sub>2</sub>
 to C<sub>14</sub>
 by GC analysis and from C<sub>8</sub>
 to C<sub>37</sub>
 by petroleomic. Many heavy lignin oligomers produced by the pyrolysis are trapped by the catalytic bed, highlighting the need of new catalytic systems to convert them into valuable fuels or chemicals.</div>
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<fC01 i1="01" l="ENG"><s0>We propose to assess the selectivity of hydrotreatment catalysts by two complementary analytical methods: (1) high-resolution mass spectrometry (MS), called "petroleomic" analysis, by Fourier transform ion cyclotron resonance (FT ICR, 9.4T) MS for species heavier than m/z of about 200 Da and (2) quantitative GC<sup>*</sup>
GC (heart-cutting)/MS-flame ionization detector (FID) analysis of lighter species. The methodology is illustrated on methanol-soluble bio-oils produced by lignin pyrolysis and hydrotreated by iron-based catalysts. GC<sup>*</sup>
GC analysis is calibrated by a combination of internal standard and prediction of response factors on the FID. Laser desorption ionization (LDI) and electro spray ionization (ESI) in negative-ion mode are combined for the petroleomic analysis. The selectivity of hydrotreatment (catalytic fixed bed, 1 atm, 400 °C) is assessed as a function of catalyst loads and iron support (silica and activated carbon). Hundreds of species are analyzed by GC<sup>*</sup>
GC and petroleomic and mapped in Van Krevelen diagrams. The high selectivity of reduced iron for the hydrodeoxygenation of lignin pyrolysis vapors is demonstrated. The effect of the catalytic treatment on oxygen content and unsaturation is studied for a broad range of species: from C<sub>2</sub>
 to C<sub>14</sub>
 by GC analysis and from C<sub>8</sub>
 to C<sub>37</sub>
 by petroleomic. Many heavy lignin oligomers produced by the pyrolysis are trapped by the catalytic bed, highlighting the need of new catalytic systems to convert them into valuable fuels or chemicals.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001D06B02D</s0>
</fC02>
<fC02 i1="02" i2="X"><s0>001D06D</s0>
</fC02>
<fC02 i1="03" i2="X"><s0>230</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Hydrotraitement</s0>
<s5>05</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Hydrotreating</s0>
<s5>05</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Hidrotratamiento</s0>
<s5>05</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Sélectivité catalyseur</s0>
<s5>06</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Catalyst selectivity</s0>
<s5>06</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Selectividad catalizador</s0>
<s5>06</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Haute résolution</s0>
<s5>07</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>High resolution</s0>
<s5>07</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Alta resolucion</s0>
<s5>07</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Spectrométrie masse</s0>
<s5>08</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Mass spectrometry</s0>
<s5>08</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Espectrometría masa</s0>
<s5>08</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Transformation Fourier</s0>
<s5>09</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Fourier transformation</s0>
<s5>09</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Transformación Fourier</s0>
<s5>09</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Résonance cyclotronique</s0>
<s5>10</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Cyclotron resonance</s0>
<s5>10</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Resonancia ciclotrónica</s0>
<s5>10</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Détecteur ionisation flamme</s0>
<s5>11</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Flame ionization detector</s0>
<s5>11</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Detector ionización por llama</s0>
<s5>11</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Méthanol</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>12</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Methanol</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>12</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Metanol</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>12</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Lignine</s0>
<s5>13</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Lignin</s0>
<s5>13</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Lignina</s0>
<s5>13</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Pyrolyse</s0>
<s5>14</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Pyrolysis</s0>
<s5>14</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Pirólisis</s0>
<s5>14</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Fer</s0>
<s2>NC</s2>
<s5>15</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Iron</s0>
<s2>NC</s2>
<s5>15</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Hierro</s0>
<s2>NC</s2>
<s5>15</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Catalyseur sur support</s0>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Supported catalyst</s0>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Catalizador sobre soporte</s0>
<s5>16</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Norme</s0>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Standards</s0>
<s5>17</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Norma</s0>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Désorption laser</s0>
<s5>18</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Laser desorption</s0>
<s5>18</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Desorción láser</s0>
<s5>18</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Ionisation</s0>
<s5>19</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>Ionization</s0>
<s5>19</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Ionización</s0>
<s5>19</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>Lit fixe</s0>
<s5>20</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG"><s0>Fixed bed</s0>
<s5>20</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA"><s0>Lecho fijo</s0>
<s5>20</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Silice</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>21</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG"><s0>Silica</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>21</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA"><s0>Sílice</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>21</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE"><s0>Charbon actif</s0>
<s5>22</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG"><s0>Activated carbon</s0>
<s5>22</s5>
</fC03>
<fC03 i1="18" i2="X" l="SPA"><s0>Carbón activado</s0>
<s5>22</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE"><s0>Teneur oxygène</s0>
<s5>23</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG"><s0>Oxygen content</s0>
<s5>23</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA"><s0>Contenido oxígeno</s0>
<s5>23</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE"><s0>Oligomère</s0>
<s5>24</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG"><s0>Oligomer</s0>
<s5>24</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA"><s0>Oligómero</s0>
<s5>24</s5>
</fC03>
<fN21><s1>147</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
</standard>
<server><NO>PASCAL 13-0168162 INIST</NO>
<ET>Selectivity of Bio-oils Catalytic Hydrotreatment Assessed by Petroleomic and GC<sup>*</sup>
GC/MS-FID Analysis</ET>
<AU>OLCESE (Roberto); CARRE (Vincent); AUBRIET (Frédéric); DUFOUR (Anthony)</AU>
<AF>Reactions and Processes Engineering Laboratory, CNRS, Lorraine University, ENSIC, 1 rue Grandville/54000 Nancy/France (1 aut., 4 aut.); Laboratoire Chimie et de Physique des Milieux Complexes, Lorraine University, ICPM, 1 Boulevard Arago/57078 Metz/France (2 aut., 3 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Energy & fuels; ISSN 0887-0624; Coden ENFUEM; Etats-Unis; Da. 2013; Vol. 27; No. MARAVR; Pp. 2135-2145; Bibl. 59 ref.</SO>
<LA>Anglais</LA>
<EA>We propose to assess the selectivity of hydrotreatment catalysts by two complementary analytical methods: (1) high-resolution mass spectrometry (MS), called "petroleomic" analysis, by Fourier transform ion cyclotron resonance (FT ICR, 9.4T) MS for species heavier than m/z of about 200 Da and (2) quantitative GC<sup>*</sup>
GC (heart-cutting)/MS-flame ionization detector (FID) analysis of lighter species. The methodology is illustrated on methanol-soluble bio-oils produced by lignin pyrolysis and hydrotreated by iron-based catalysts. GC<sup>*</sup>
GC analysis is calibrated by a combination of internal standard and prediction of response factors on the FID. Laser desorption ionization (LDI) and electro spray ionization (ESI) in negative-ion mode are combined for the petroleomic analysis. The selectivity of hydrotreatment (catalytic fixed bed, 1 atm, 400 °C) is assessed as a function of catalyst loads and iron support (silica and activated carbon). Hundreds of species are analyzed by GC<sup>*</sup>
GC and petroleomic and mapped in Van Krevelen diagrams. The high selectivity of reduced iron for the hydrodeoxygenation of lignin pyrolysis vapors is demonstrated. The effect of the catalytic treatment on oxygen content and unsaturation is studied for a broad range of species: from C<sub>2</sub>
 to C<sub>14</sub>
 by GC analysis and from C<sub>8</sub>
 to C<sub>37</sub>
 by petroleomic. Many heavy lignin oligomers produced by the pyrolysis are trapped by the catalytic bed, highlighting the need of new catalytic systems to convert them into valuable fuels or chemicals.</EA>
<CC>001D06B02D; 001D06D; 230</CC>
<FD>Hydrotraitement; Sélectivité catalyseur; Haute résolution; Spectrométrie masse; Transformation Fourier; Résonance cyclotronique; Détecteur ionisation flamme; Méthanol; Lignine; Pyrolyse; Fer; Catalyseur sur support; Norme; Désorption laser; Ionisation; Lit fixe; Silice; Charbon actif; Teneur oxygène; Oligomère</FD>
<ED>Hydrotreating; Catalyst selectivity; High resolution; Mass spectrometry; Fourier transformation; Cyclotron resonance; Flame ionization detector; Methanol; Lignin; Pyrolysis; Iron; Supported catalyst; Standards; Laser desorption; Ionization; Fixed bed; Silica; Activated carbon; Oxygen content; Oligomer</ED>
<SD>Hidrotratamiento; Selectividad catalizador; Alta resolucion; Espectrometría masa; Transformación Fourier; Resonancia ciclotrónica; Detector ionización por llama; Metanol; Lignina; Pirólisis; Hierro; Catalizador sobre soporte; Norma; Desorción láser; Ionización; Lecho fijo; Sílice; Carbón activado; Contenido oxígeno; Oligómero</SD>
<LO>INIST-21106.354000503775721020</LO>
<ID>13-0168162</ID>
</server>
</inist>
</record>

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Selectivity of Bio-oils Catalytic Hydrotreatment Assessed by Petroleomic and GC*GC/MS-FID Analysis

Selectivity of Bio-oils Catalytic Hydrotreatment Assessed by Petroleomic and GC*GC/MS-FID Analysis

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