LrgpV1, Ncbi, Checkpoint, bibRecord, 000268

Experimental study of the oxidation of methyl oleate in a jet-stirred reactor

Identifieur interne : 000268 ( Ncbi/Checkpoint ); précédent : 000267; suivant : 000269

Experimental study of the oxidation of methyl oleate in a jet-stirred reactor

Auteurs : Sarah Bax [France] ; Mohammed Hichem Hakka [France] ; Pierre-Alexandre Glaude [France] ; Olivier Herbinet [France] ; Frédérique Battin-Leclerc [France]

Source :

Combustion and flame [ 0010-2180 ] ; 2010.

RBID : PMC:3662212

Abstract

The experimental study of the oxidation of a blend containing n-decane and a large unsaturated ester, methyl oleate, was performed in a jet-stirred reactor over a wide range of temperature covering both low and high temperature regions (550–1100 K), at a residence time of 1.5 s, at quasi atmospheric pressure with high dilution in helium (n-decane and methyl oleate inlet mole fractions of 1.48 × 10⁻³ and 5.2 × 10⁻⁴) and under stoichiometric conditions.

The formation of numerous reaction products was observed. At low and intermediate temperatures, the oxidation of the blend led to the formation of species containing oxygen atoms like cyclic ethers, aldehydes and ketones deriving from n-decane and methyl oleate. At higher temperature, these species were not formed anymore and the presence of unsaturated species was observed. Because of the presence of the double bond in the middle of the alkyl chain of methyl oleate, the formation of some specific products was observed. These species are dienes and esters with two double bonds produced from the decomposition paths of methyl oleate and some species obtained from the addition of H-atoms, OH and HO₂ radicals to the double bond.

Experimental results were compared with former results of the oxidation of a blend of n-decane and methyl palmitate performed under similar conditions. This comparison allowed highlighting the similarities and the differences in the reactivity and in the distribution of the reaction products for the oxidation of large saturated and unsaturated esters.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3662212

DOI: 10.1016/j.combustflame.2009.12.008
PubMed: 23710077
PubMed Central: 3662212

Affiliations:

Links to Exploration step

PMC:3662212

Le document en format XML

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<front><div type="abstract" xml:lang="en"><p id="P1">The experimental study of the oxidation of a blend containing n-decane and a large unsaturated ester, methyl oleate, was performed in a jet-stirred reactor over a wide range of temperature covering both low and high temperature regions (550–1100 K), at a residence time of 1.5 s, at quasi atmospheric pressure with high dilution in helium (n-decane and methyl oleate inlet mole fractions of 1.48 × 10<sup>−3</sup>
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<p id="P2">The formation of numerous reaction products was observed. At low and intermediate temperatures, the oxidation of the blend led to the formation of species containing oxygen atoms like cyclic ethers, aldehydes and ketones deriving from n-decane and methyl oleate. At higher temperature, these species were not formed anymore and the presence of unsaturated species was observed. Because of the presence of the double bond in the middle of the alkyl chain of methyl oleate, the formation of some specific products was observed. These species are dienes and esters with two double bonds produced from the decomposition paths of methyl oleate and some species obtained from the addition of H-atoms, OH and HO<sub>2</sub>
 radicals to the double bond.</p>
<p id="P3">Experimental results were compared with former results of the oxidation of a blend of n-decane and methyl palmitate performed under similar conditions. This comparison allowed highlighting the similarities and the differences in the reactivity and in the distribution of the reaction products for the oxidation of large saturated and unsaturated esters.</p>
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Experimental study of the oxidation of methyl oleate in a jet-stirred reactor

Experimental study of the oxidation of methyl oleate in a jet-stirred reactor

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