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A novel quasicrystal-resin composite for stereolithography

Identifieur interne : 000370 ( Main/Exploration ); précédent : 000369; suivant : 000371

A novel quasicrystal-resin composite for stereolithography

Auteurs : Adnène Sakly [France] ; Samuel Kenzari [France] ; David Bonina [France] ; Serge Corbel [France] ; Vincent Fournée [France]

Source :

RBID : Hal:hal-01275729

Abstract

Laser stereolithography (SL) is an additive manufacturing technology which is increasingly being used to produce customized end-user parts of any complex shape. It requires the use of a photo-curable resin which can be loaded with ceramic powders or carbon fibers to produce composite parts. However, the range of available materials compatible with the SL process is rather limited. In particular, photo-curable resins reinforced by metal particles are difficult to process, because of fundamental limitations related to the high reflectivity of intermetallics in the UV-visible range. In this work, the unique properties of Al-based quasicrystalline alloys are being used to develop a new UV-curable resin reinforced by such metal particles. The optical properties of the quasicrystalline particles and of the filled resin are studied and they are found to be compatible with the SL process. The volume fraction of the filler particles in the liquid resin is optimized to increase the polymerization depth while preserving suitable rheological behaviour. Finally, 3D composite parts are being built by SL. The composite parts have improved mechanical properties compared to the unfilled resin (higher hardness, reduced wear losses and lower friction coefficient) and compete favourably with the other commercial photo-curable resins.

Url:
DOI: 10.1016/j.matdes.2013.11.025


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<country>France</country>
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<settlement type="city">Nancy</settlement>
<settlement type="city">Metz</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
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<orgName type="university">Université de Lorraine</orgName>
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<author>
<name sortKey="Corbel, Serge" sort="Corbel, Serge" uniqKey="Corbel S" first="Serge" last="Corbel">Serge Corbel</name>
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<idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
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<address>
<addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
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<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
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<address>
<addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
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</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
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<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
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<address>
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</hal:affiliation>
<country>France</country>
<placeName>
<settlement type="city">Nancy</settlement>
<settlement type="city">Metz</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="university">Université de Lorraine</orgName>
<placeName>
<settlement type="city">Nancy</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="laboratoire" n="5">Laboratoire réactions et génie des procédés</orgName>
<orgName type="university">Université de Lorraine</orgName>
<orgName type="institution">Centre national de la recherche scientifique</orgName>
</affiliation>
</author>
<author>
<name sortKey="Fournee, Vincent" sort="Fournee, Vincent" uniqKey="Fournee V" first="Vincent" last="Fournée">Vincent Fournée</name>
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<idno type="RNSR">200918462H</idno>
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<orgName>Institut Jean Lamour</orgName>
<orgName type="acronym">IJL</orgName>
<date type="start">2012-01-01</date>
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<address>
<addrLine>Institut Jean Lamour, Parc de Saurupt, Rond-point Marguerite de Lorraine, CS 50840, 54011 NANCY cedex</addrLine>
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</address>
<ref type="url">http://ijl.univ-lorraine.fr</ref>
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<orgName>Université de Lorraine</orgName>
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<date type="start">2012-01-01</date>
<desc>
<address>
<addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
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</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
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<orgName type="acronym">CNRS</orgName>
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</hal:affiliation>
<country>France</country>
<placeName>
<settlement type="city">Nancy</settlement>
<settlement type="city">Metz</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Lorraine (région)</region>
</placeName>
<orgName type="university">Université de Lorraine</orgName>
</affiliation>
</author>
</analytic>
<idno type="DOI">10.1016/j.matdes.2013.11.025</idno>
<series>
<title level="j">Materials and Design</title>
<idno type="ISSN">0264-1275</idno>
<imprint>
<date type="datePub">2014-04</date>
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<front>
<div type="abstract" xml:lang="en">Laser stereolithography (SL) is an additive manufacturing technology which is increasingly being used to produce customized end-user parts of any complex shape. It requires the use of a photo-curable resin which can be loaded with ceramic powders or carbon fibers to produce composite parts. However, the range of available materials compatible with the SL process is rather limited. In particular, photo-curable resins reinforced by metal particles are difficult to process, because of fundamental limitations related to the high reflectivity of intermetallics in the UV-visible range. In this work, the unique properties of Al-based quasicrystalline alloys are being used to develop a new UV-curable resin reinforced by such metal particles. The optical properties of the quasicrystalline particles and of the filled resin are studied and they are found to be compatible with the SL process. The volume fraction of the filler particles in the liquid resin is optimized to increase the polymerization depth while preserving suitable rheological behaviour. Finally, 3D composite parts are being built by SL. The composite parts have improved mechanical properties compared to the unfilled resin (higher hardness, reduced wear losses and lower friction coefficient) and compete favourably with the other commercial photo-curable resins.</div>
</front>
</TEI>
<affiliations>
<list>
<country>
<li>France</li>
</country>
<region>
<li>Grand Est</li>
<li>Lorraine (région)</li>
</region>
<settlement>
<li>Metz</li>
<li>Nancy</li>
</settlement>
<orgName>
<li>Centre national de la recherche scientifique</li>
<li>Laboratoire réactions et génie des procédés</li>
<li>Université de Lorraine</li>
</orgName>
</list>
<tree>
<country name="France">
<region name="Grand Est">
<name sortKey="Sakly, Adnene" sort="Sakly, Adnene" uniqKey="Sakly A" first="Adnène" last="Sakly">Adnène Sakly</name>
</region>
<name sortKey="Bonina, David" sort="Bonina, David" uniqKey="Bonina D" first="David" last="Bonina">David Bonina</name>
<name sortKey="Corbel, Serge" sort="Corbel, Serge" uniqKey="Corbel S" first="Serge" last="Corbel">Serge Corbel</name>
<name sortKey="Fournee, Vincent" sort="Fournee, Vincent" uniqKey="Fournee V" first="Vincent" last="Fournée">Vincent Fournée</name>
<name sortKey="Kenzari, Samuel" sort="Kenzari, Samuel" uniqKey="Kenzari S" first="Samuel" last="Kenzari">Samuel Kenzari</name>
</country>
</tree>
</affiliations>
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