Influence of incorporating CaCO3 into room temperature vulcanized silicone sealant on its mechanical and dynamic rheological properties
Identifieur interne : 001051 ( Istex/Corpus ); précédent : 001050; suivant : 001052Influence of incorporating CaCO3 into room temperature vulcanized silicone sealant on its mechanical and dynamic rheological properties
Auteurs : Xiaoming Xu ; Yihu Song ; Qiang Zheng ; Guohua HuSource :
- Journal of Applied Polymer Science [ 0021-8995 ] ; 2007-02-05.
English descriptors
- KwdEn :
- Adhesion, Average diameter, Caco3, Chain extender agent, Continuous network, Crosslinking, Different caco3 contents, Dynamic loss modulus, Dynamic storage modulus, Elongation, Extender, Glass transition temperature, High elongation, Ketoxime silane, Lled, Ller, Ller amount, Ller content, Ller contents, Ller network, Mechanical properties, Modulus, Novel silane, Other hand, Particle diameter distribution, Pdms, Polym, Polymer, Polymer chains, Polymer science, Rheol, Room temperature, Sealant, Sealant samples, Silane, Silicone, Silicone sealant, Silicone sealants, Strain amplitude, Tensile strength, Virgin pdms.
- Teeft :
- Adhesion, Average diameter, Caco3, Chain extender agent, Continuous network, Crosslinking, Different caco3 contents, Dynamic loss modulus, Dynamic storage modulus, Elongation, Extender, Glass transition temperature, High elongation, Ketoxime silane, Lled, Ller, Ller amount, Ller content, Ller contents, Ller network, Mechanical properties, Modulus, Novel silane, Other hand, Particle diameter distribution, Pdms, Polym, Polymer, Polymer chains, Polymer science, Rheol, Room temperature, Sealant, Sealant samples, Silane, Silicone, Silicone sealant, Silicone sealants, Strain amplitude, Tensile strength, Virgin pdms.
Abstract
Silicone sealants with low modulus and high elongation were prepared by using ketoxime silane as chain extender agent, and a novel silane coupling agent acting as adhesion promoting agent was synthesized. Mechanical properties of vulcanized polydimethylsiloxane (PDMS) filled with large amounts of carbonate calcium (CaCO3) and dynamic viscoelastic properties of unvulcanized samples were investigated through electronic multifunctional tensile tests, dynamic mechanical analyzers, and dynamic rheological measurements. The results of mechanical tests indicate that diminishing the particle diameter size, narrowing the particle diameter distribution, and increasing the filler amount lead to a relative high tensile strength and modulus at 100% elongation, but a relative low elongation at break. The reasons for these are believed to be the evolution of molecular interactions and the formation of additional physical crosslinking induced by the filler network. Compared to virgin PDMS, there is a significant elevation of glass transition temperature with filler addition. On the other hand, the results of dynamic rheological measurements reveal that as filler amount increases, the span of the linear viscoelastic region in which dynamic storage modulus (G′) is constant in low strain amplitude narrows. However, a characteristic plateau phenomenon appears in low frequency regions together with increasing the width and height of the modulus plateau. This phenomenon is also ascribed to the formation of a filler network due to filler–polymer and filler–filler interaction. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2027–2035, 2007
Url:
DOI: 10.1002/app.25324
Links to Exploration step
ISTEX:BDAD0CC85EEEC87B172D7A8A31D1F12BFAB06CFCLe document en format XML
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with low modulus and high elongation were prepared by using ketoxime silane as chain extender agent, and a novel silane coupling agent acting as adhesion promoting agent was synthesized. Mechanical properties of vulcanized polydimethylsiloxane (PDMS) filled with large amounts of carbonate calcium (CaCO3) and dynamic viscoelastic properties of unvulcanized samples were investigated through electronic multifunctional tensile tests, dynamic mechanical analyzers, and dynamic rheological measurements. The results of mechanical tests indicate that diminishing the particle diameter size, narrowing the particle diameter distribution, and increasing the filler amount lead to a relative high tensile strength and modulus at 100% elongation, but a relative low elongation at break. The reasons for these are believed to be the evolution of molecular interactions and the formation of additional physical crosslinking induced by the filler network. Compared to virgin PDMS, there is a significant elevation of glass transition temperature with filler addition. On the other hand, the results of dynamic rheological measurements reveal that as filler amount increases, the span of the linear viscoelastic region in which dynamic storage modulus (G′) is constant in low strain amplitude narrows. However, a characteristic plateau phenomenon appears in low frequency regions together with increasing the width and height of the modulus plateau. This phenomenon is also ascribed to the formation of a filler network due to filler–polymer and filler–filler interaction. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2027–2035, 2007</div></front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>ller</json:string><json:string>sealant</json:string><json:string>modulus</json:string><json:string>caco3</json:string><json:string>silicone sealants</json:string><json:string>silicone</json:string><json:string>polymer</json:string><json:string>pdms</json:string><json:string>ller network</json:string><json:string>mechanical properties</json:string><json:string>ller amount</json:string><json:string>polymer science</json:string><json:string>silane</json:string><json:string>tensile strength</json:string><json:string>lled</json:string><json:string>rheol</json:string><json:string>crosslinking</json:string><json:string>strain amplitude</json:string><json:string>extender</json:string><json:string>polym</json:string><json:string>high elongation</json:string><json:string>ller content</json:string><json:string>silicone sealant</json:string><json:string>dynamic storage modulus</json:string><json:string>chain extender agent</json:string><json:string>ller contents</json:string><json:string>room temperature</json:string><json:string>average diameter</json:string><json:string>other hand</json:string><json:string>ketoxime silane</json:string><json:string>polymer chains</json:string><json:string>adhesion</json:string><json:string>elongation</json:string><json:string>novel silane</json:string><json:string>glass transition temperature</json:string><json:string>virgin pdms</json:string><json:string>continuous network</json:string><json:string>sealant samples</json:string><json:string>dynamic loss modulus</json:string><json:string>different caco3 contents</json:string><json:string>particle diameter distribution</json:string></teeft></keywords><author><json:item><name>Xiaoming Xu</name><affiliations><json:string>Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China</json:string><json:string>National Engineering Research Center for Compounding and Modification of Polymeric Materials, Guiyang 550025, People's Republic of China</json:string></affiliations></json:item><json:item><name>Yihu Song</name><affiliations><json:string>Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China</json:string></affiliations></json:item><json:item><name>Qiang Zheng</name><affiliations><json:string>Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China</json:string><json:string>National Engineering Research Center for Compounding and Modification of Polymeric Materials, Guiyang 550025, People's Republic of China</json:string><json:string>Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China===</json:string></affiliations></json:item><json:item><name>Guohua Hu</name><affiliations><json:string>Laboratory of Chemical Engineering Sciences, CNRS‐ENSIC‐INPL, 1 rue Grandville, BP 20451, 54001 Nancy, France</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>mechanical properties</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>dynamic rheological behavior</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>filler network</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>particle diameter</value></json:item><json:item><lang><json:string>eng</json:string></lang><value>polydimethylsiloxane</value></json:item></subject><articleId><json:string>APP25324</json:string></articleId><language><json:string>eng</json:string></language><originalGenre><json:string>article</json:string></originalGenre><abstract>Silicone sealants with low modulus and high elongation were prepared by using ketoxime silane as chain extender agent, and a novel silane coupling agent acting as adhesion promoting agent was synthesized. Mechanical properties of vulcanized polydimethylsiloxane (PDMS) filled with large amounts of carbonate calcium (CaCO3) and dynamic viscoelastic properties of unvulcanized samples were investigated through electronic multifunctional tensile tests, dynamic mechanical analyzers, and dynamic rheological measurements. The results of mechanical tests indicate that diminishing the particle diameter size, narrowing the particle diameter distribution, and increasing the filler amount lead to a relative high tensile strength and modulus at 100% elongation, but a relative low elongation at break. The reasons for these are believed to be the evolution of molecular interactions and the formation of additional physical crosslinking induced by the filler network. Compared to virgin PDMS, there is a significant elevation of glass transition temperature with filler addition. On the other hand, the results of dynamic rheological measurements reveal that as filler amount increases, the span of the linear viscoelastic region in which dynamic storage modulus (G′) is constant in low strain amplitude narrows. However, a characteristic plateau phenomenon appears in low frequency regions together with increasing the width and height of the modulus plateau. This phenomenon is also ascribed to the formation of a filler network due to filler–polymer and filler–filler interaction. © 2006 Wiley Periodicals, Inc. 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of Silicone Sealants</title><author xml:id="author-0000"><persName><forename type="first">Xiaoming</forename><surname>Xu</surname></persName><affiliation>Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China<address><country key="CN"></country></address></affiliation><affiliation>National Engineering Research Center for Compounding and Modification of Polymeric Materials, Guiyang 550025, People's Republic of China<address><country key="CN"></country></address></affiliation></author><author xml:id="author-0001"><persName><forename type="first">Yihu</forename><surname>Song</surname></persName><affiliation>Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China<address><country key="CN"></country></address></affiliation></author><author xml:id="author-0002" role="corresp"><persName><forename type="first">Qiang</forename><surname>Zheng</surname></persName><email>zhengqiang@zju.edu.cn</email><affiliation>Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China<address><country key="CN"></country></address></affiliation><affiliation>National Engineering Research Center for Compounding and Modification of Polymeric Materials, Guiyang 550025, People's Republic of China<address><country key="CN"></country></address></affiliation><affiliation>Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China===</affiliation></author><author xml:id="author-0003"><persName><forename type="first">Guohua</forename><surname>Hu</surname></persName><affiliation>Laboratory of Chemical Engineering Sciences, CNRS‐ENSIC‐INPL, 1 rue Grandville, BP 20451, 54001 Nancy, France<address><country key="FR"></country></address></affiliation></author><idno 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Mechanical properties of vulcanized polydimethylsiloxane (PDMS) filled with large amounts of carbonate calcium (CaCO<hi rend="subscript">3</hi>) and dynamic viscoelastic properties of unvulcanized samples were investigated through electronic multifunctional tensile tests, dynamic mechanical analyzers, and dynamic rheological measurements. The results of mechanical tests indicate that diminishing the particle diameter size, narrowing the particle diameter distribution, and increasing the filler amount lead to a relative high tensile strength and modulus at 100% elongation, but a relative low elongation at break. The reasons for these are believed to be the evolution of molecular interactions and the formation of additional physical crosslinking induced by the filler network. Compared to virgin PDMS, there is a significant elevation of glass transition temperature with filler addition. On the other hand, the results of dynamic rheological measurements reveal that as filler amount increases, the span of the linear viscoelastic region in which dynamic storage modulus (G′) is constant in low strain amplitude narrows. However, a characteristic plateau phenomenon appears in low frequency regions together with increasing the width and height of the modulus plateau. This phenomenon is also ascribed to the formation of a filler network due to filler–polymer and filler–filler interaction. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2027–2035, 2007</p></abstract><textClass><keywords xml:lang="en"><term xml:id="kwd1">mechanical properties</term><term xml:id="kwd2">dynamic rheological behavior</term><term xml:id="kwd3">filler network</term><term xml:id="kwd4">particle diameter</term><term xml:id="kwd5">polydimethylsiloxane</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/BDAD0CC85EEEC87B172D7A8A31D1F12BFAB06CFC/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>Wiley Subscription Services, Inc., A Wiley Company</publisherName><publisherLoc>Hoboken</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1097-4628</doi><issn type="print">0021-8995</issn><issn type="electronic">1097-4628</issn><idGroup><id type="product" value="APP"></id></idGroup><titleGroup><title type="main" xml:lang="en" sort="JOURNAL OF APPLIED POLYMER SCIENCE">Journal of Applied Polymer Science</title><title type="short">J. 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Sci.</title></titleGroup></publicationMeta><publicationMeta level="part" position="30"><doi origin="wiley" registered="yes">10.1002/app.v103:3</doi><numberingGroup><numbering type="journalVolume" number="103">103</numbering><numbering type="journalIssue">3</numbering></numberingGroup><coverDate startDate="2007-02-05">5 February 2007</coverDate></publicationMeta><publicationMeta level="unit" type="article" position="415" status="forIssue"><doi origin="wiley" registered="yes">10.1002/app.25324</doi><idGroup><id type="unit" value="APP25324"></id></idGroup><countGroup><count type="pageTotal" number="9"></count></countGroup><copyright ownership="publisher">Copyright © 2006 Wiley Periodicals, Inc.</copyright><eventGroup><event type="manuscriptReceived" date="2006-05-20"></event><event type="manuscriptAccepted" date="2006-08-08"></event><event type="firstOnline" date="2006-11-08"></event><event type="publishedOnlineFinalForm" date="2006-11-08"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.6 mode:FullText source:FullText result:FullText" date="2010-04-20"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:4.0.1" date="2014-03-24"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-23"></event></eventGroup><numberingGroup><numbering type="pageFirst">2027</numbering><numbering type="pageLast">2035</numbering></numberingGroup><correspondenceTo>Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China===</correspondenceTo><objectNameGroup><objectName elementName="figure">Scheme</objectName></objectNameGroup><linkGroup><link type="toTypesetVersion" href="file:APP.APP25324.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="10"></count><count type="tableTotal" number="3"></count><count type="referenceTotal" number="33"></count><count type="wordTotal" number="4837"></count></countGroup><titleGroup><title type="main" xml:lang="en">Influence of incorporating CaCO<sub>3</sub> into room temperature vulcanized silicone sealant on its mechanical and dynamic rheological properties</title><title type="short" xml:lang="en">Preparation and Properties of Silicone Sealants</title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#af1 #af2"><personName><givenNames>Xiaoming</givenNames><familyName>Xu</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Yihu</givenNames><familyName>Song</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#af1 #af2" corresponding="yes"><personName><givenNames>Qiang</givenNames><familyName>Zheng</familyName></personName><contactDetails><email>zhengqiang@zju.edu.cn</email></contactDetails></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#af3"><personName><givenNames>Guohua</givenNames><familyName>Hu</familyName></personName></creator></creators><affiliationGroup><affiliation xml:id="af1" countryCode="CN" type="organization"><unparsedAffiliation>Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China</unparsedAffiliation></affiliation><affiliation xml:id="af2" countryCode="CN" type="organization"><unparsedAffiliation>National Engineering Research Center for Compounding and Modification of Polymeric Materials, Guiyang 550025, People's Republic of China</unparsedAffiliation></affiliation><affiliation xml:id="af3" countryCode="FR" type="organization"><unparsedAffiliation>Laboratory of Chemical Engineering Sciences, CNRS‐ENSIC‐INPL, 1 rue Grandville, BP 20451, 54001 Nancy, France</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">mechanical properties</keyword><keyword xml:id="kwd2">dynamic rheological behavior</keyword><keyword xml:id="kwd3">filler network</keyword><keyword xml:id="kwd4">particle diameter</keyword><keyword xml:id="kwd5">polydimethylsiloxane</keyword></keywordGroup><fundingInfo><fundingAgency>National Basic Research Program of China</fundingAgency><fundingNumber>2005CB623800</fundingNumber></fundingInfo><fundingInfo><fundingAgency>National Natural Science Foundation of China</fundingAgency><fundingNumber>50373037</fundingNumber></fundingInfo><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>Silicone sealants with low modulus and high elongation were prepared by using ketoxime silane as chain extender agent, and a novel silane coupling agent acting as adhesion promoting agent was synthesized. Mechanical properties of vulcanized polydimethylsiloxane (PDMS) filled with large amounts of carbonate calcium (CaCO<sub>3</sub>) and dynamic viscoelastic properties of unvulcanized samples were investigated through electronic multifunctional tensile tests, dynamic mechanical analyzers, and dynamic rheological measurements. The results of mechanical tests indicate that diminishing the particle diameter size, narrowing the particle diameter distribution, and increasing the filler amount lead to a relative high tensile strength and modulus at 100% elongation, but a relative low elongation at break. The reasons for these are believed to be the evolution of molecular interactions and the formation of additional physical crosslinking induced by the filler network. Compared to virgin PDMS, there is a significant elevation of glass transition temperature with filler addition. On the other hand, the results of dynamic rheological measurements reveal that as filler amount increases, the span of the linear viscoelastic region in which dynamic storage modulus (G′) is constant in low strain amplitude narrows. However, a characteristic plateau phenomenon appears in low frequency regions together with increasing the width and height of the modulus plateau. This phenomenon is also ascribed to the formation of a filler network due to filler–polymer and filler–filler interaction. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2027–2035, 2007</p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Influence of incorporating CaCO3 into room temperature vulcanized silicone sealant on its mechanical and dynamic rheological properties</title></titleInfo><titleInfo type="abbreviated" lang="en"><title>Preparation and Properties of Silicone Sealants</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Influence of incorporating CaCO3 into room temperature vulcanized silicone sealant on its mechanical and dynamic rheological properties</title></titleInfo><name type="personal"><namePart type="given">Xiaoming</namePart><namePart type="family">Xu</namePart><affiliation>Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China</affiliation><affiliation>National Engineering Research Center for Compounding and Modification of Polymeric Materials, Guiyang 550025, People's Republic of China</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Yihu</namePart><namePart type="family">Song</namePart><affiliation>Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Qiang</namePart><namePart type="family">Zheng</namePart><affiliation>Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China</affiliation><affiliation>National Engineering Research Center for Compounding and Modification of Polymeric Materials, Guiyang 550025, People's Republic of China</affiliation><affiliation>E-mail: zhengqiang@zju.edu.cn</affiliation><affiliation>Correspondence address: Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China===</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Guohua</namePart><namePart type="family">Hu</namePart><affiliation>Laboratory of Chemical Engineering Sciences, CNRS‐ENSIC‐INPL, 1 rue Grandville, BP 20451, 54001 Nancy, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</genre><originInfo><publisher>Wiley Subscription Services, Inc., A Wiley Company</publisher><place><placeTerm type="text">Hoboken</placeTerm></place><dateIssued encoding="w3cdtf">2007-02-05</dateIssued><dateCaptured encoding="w3cdtf">2006-05-20</dateCaptured><dateValid encoding="w3cdtf">2006-08-08</dateValid><copyrightDate encoding="w3cdtf">2007</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">10</extent><extent unit="tables">3</extent><extent unit="references">33</extent><extent unit="words">4837</extent></physicalDescription><abstract lang="en">Silicone sealants with low modulus and high elongation were prepared by using ketoxime silane as chain extender agent, and a novel silane coupling agent acting as adhesion promoting agent was synthesized. Mechanical properties of vulcanized polydimethylsiloxane (PDMS) filled with large amounts of carbonate calcium (CaCO3) and dynamic viscoelastic properties of unvulcanized samples were investigated through electronic multifunctional tensile tests, dynamic mechanical analyzers, and dynamic rheological measurements. The results of mechanical tests indicate that diminishing the particle diameter size, narrowing the particle diameter distribution, and increasing the filler amount lead to a relative high tensile strength and modulus at 100% elongation, but a relative low elongation at break. The reasons for these are believed to be the evolution of molecular interactions and the formation of additional physical crosslinking induced by the filler network. Compared to virgin PDMS, there is a significant elevation of glass transition temperature with filler addition. On the other hand, the results of dynamic rheological measurements reveal that as filler amount increases, the span of the linear viscoelastic region in which dynamic storage modulus (G′) is constant in low strain amplitude narrows. However, a characteristic plateau phenomenon appears in low frequency regions together with increasing the width and height of the modulus plateau. This phenomenon is also ascribed to the formation of a filler network due to filler–polymer and filler–filler interaction. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2027–2035, 2007</abstract><note type="funding">National Basic Research Program of China - No. 2005CB623800; </note><note type="funding">National Natural Science Foundation of China - No. 50373037; </note><subject lang="en"><genre>keywords</genre><topic>mechanical properties</topic><topic>dynamic rheological behavior</topic><topic>filler network</topic><topic>particle diameter</topic><topic>polydimethylsiloxane</topic></subject><relatedItem type="host"><titleInfo><title>Journal of Applied Polymer Science</title></titleInfo><titleInfo type="abbreviated"><title>J. Appl. Polym. Sci.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><identifier type="ISSN">0021-8995</identifier><identifier type="eISSN">1097-4628</identifier><identifier type="DOI">10.1002/(ISSN)1097-4628</identifier><identifier type="PublisherID">APP</identifier><part><date>2007</date><detail type="volume"><caption>vol.</caption><number>103</number></detail><detail type="issue"><caption>no.</caption><number>3</number></detail><extent unit="pages"><start>2027</start><end>2035</end><total>9</total></extent></part></relatedItem><identifier type="istex">BDAD0CC85EEEC87B172D7A8A31D1F12BFAB06CFC</identifier><identifier type="ark">ark:/67375/WNG-WDT142LK-X</identifier><identifier type="DOI">10.1002/app.25324</identifier><identifier type="ArticleID">APP25324</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2006 Wiley Periodicals, Inc.</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-L0C46X92-X">wiley</recordContentSource><recordOrigin>Wiley Subscription Services, Inc., A Wiley Company</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/BDAD0CC85EEEC87B172D7A8A31D1F12BFAB06CFC/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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