LrgpV1, Hal, Corpus, bibRecord, 000A77

Study of interaction between organic compounds and mono or dicationic oxygenated ionic liquids using gas chromatography

Identifieur interne : 000A77 ( Hal/Corpus ); précédent : 000A76; suivant : 000A78

Study of interaction between organic compounds and mono or dicationic oxygenated ionic liquids using gas chromatography

Auteurs : Fabrice Mutelet ; Patrick Carre ; Andrzej Skrzypczak

Source :

Fluid Phase Equilibria [ 0378-3812 ] ; 2015-02.

RBID : Hal:hal-01267383

Abstract

Interactions of selected organic compounds with 16 functionalized based mono or dicationic ionic liquids were studied using inverse gas chromatography. Retention data were used to determine the selectivity and capacity values with these ionic liquids for four separation problems: hexane/benzene, hexane/methanol, hexane/thiophene, and cyclohexane/thiophene. It was found that the choice of the anion, the cation and the functionalized chain play an important role in the efficiency of the separation process. The solvation characteristics of this class of ionic liquids were also evaluated using linear solvation energy relationships (LSERs). Results indicate that mono and dicationic ionic liquids have similar solvation properties.

Url:

https://hal.univ-lorraine.fr/hal-01267383

DOI: 10.1016/j.fluid.2014.11.020

Links to Exploration step

Hal:hal-01267383

Le document en format XML

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<front><div type="abstract" xml:lang="en">Interactions of selected organic compounds with 16 functionalized based mono or dicationic ionic liquids were studied using inverse gas chromatography. Retention data were used to determine the selectivity and capacity values with these ionic liquids for four separation problems: hexane/benzene, hexane/methanol, hexane/thiophene, and cyclohexane/thiophene. It was found that the choice of the anion, the cation and the functionalized chain play an important role in the efficiency of the separation process. The solvation characteristics of this class of ionic liquids were also evaluated using linear solvation energy relationships (LSERs). Results indicate that mono and dicationic ionic liquids have similar solvation properties.</div>
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<abstract xml:lang="en">Interactions of selected organic compounds with 16 functionalized based mono or dicationic ionic liquids were studied using inverse gas chromatography. Retention data were used to determine the selectivity and capacity values with these ionic liquids for four separation problems: hexane/benzene, hexane/methanol, hexane/thiophene, and cyclohexane/thiophene. It was found that the choice of the anion, the cation and the functionalized chain play an important role in the efficiency of the separation process. The solvation characteristics of this class of ionic liquids were also evaluated using linear solvation energy relationships (LSERs). Results indicate that mono and dicationic ionic liquids have similar solvation properties.</abstract>
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Study of interaction between organic compounds and mono or dicationic oxygenated ionic liquids using gas chromatography

Study of interaction between organic compounds and mono or dicationic oxygenated ionic liquids using gas chromatography

Source :

Abstract

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri