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Preparation process and properties of exfoliated graphite nanoplatelets filled Bisphthalonitrile nanocomposites

Identifieur interne : 000932 ( Hal/Corpus ); précédent : 000931; suivant : 000933

Preparation process and properties of exfoliated graphite nanoplatelets filled Bisphthalonitrile nanocomposites

Auteurs : Yajie Lei ; Guo-Hua Hu ; Rui Zhao ; Heng Guo ; Xin Zhao ; Xiaobo Liu

Source :

RBID : Hal:hal-00778387

English descriptors

Abstract

Exfoliated graphite nanoplatelets (xGnP) filled 4,4'-Bis (3,4-dicyanophenoxy) biphenyl (BPh) nanocomposites were prepared by a resin transfer molding process. The theological behavior of the BPh pre-polymer, and the morphology and electrical, mechanical and thermal properties of the xGnP/BPh nanocomposites were systematically investigated. The results showed that the xGnP/BPh pre-polymer possessed a higher complex viscosity and storage modulus than the pure BPh and that the xGnP could significantly enhance the mechanical and electrical properties of the resulted nanocomposites. The electrical percolation threshold of the xGnP/BPh nanocomposites was between 5 and 10 wt% xGnP. The flexural strength and modulus of the xGnP/BPh nanocomposites with 10 wt% xGnP exhibited maximum values and their thermal stabilities were greatly improved. Those novel xGnP/BPh nanocomposites could have advanced applications in areas like aerospace and military industry.

Url:
DOI: 10.1016/j.jpcs.2012.07.003

Links to Exploration step

Hal:hal-00778387

Le document en format XML

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<div type="abstract" xml:lang="en">Exfoliated graphite nanoplatelets (xGnP) filled 4,4'-Bis (3,4-dicyanophenoxy) biphenyl (BPh) nanocomposites were prepared by a resin transfer molding process. The theological behavior of the BPh pre-polymer, and the morphology and electrical, mechanical and thermal properties of the xGnP/BPh nanocomposites were systematically investigated. The results showed that the xGnP/BPh pre-polymer possessed a higher complex viscosity and storage modulus than the pure BPh and that the xGnP could significantly enhance the mechanical and electrical properties of the resulted nanocomposites. The electrical percolation threshold of the xGnP/BPh nanocomposites was between 5 and 10 wt% xGnP. The flexural strength and modulus of the xGnP/BPh nanocomposites with 10 wt% xGnP exhibited maximum values and their thermal stabilities were greatly improved. Those novel xGnP/BPh nanocomposites could have advanced applications in areas like aerospace and military industry.</div>
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<forename>Gabriel</forename>
<surname>Wild</surname>
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<funder>National Natural Science Foundation 51173021 "863" National Major Program of High Technology 2012AA03A212 Fundamental Research Funds for the Central Universities 103.1.2.E022050205 University of Electronic Science and Technology of China China scholarship Council</funder>
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<date type="whenSubmitted">2013-01-19 22:03:10</date>
<date type="whenWritten">2012</date>
<date type="whenModified">2016-05-10 16:53:05</date>
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<title xml:lang="en">Preparation process and properties of exfoliated graphite nanoplatelets filled Bisphthalonitrile nanocomposites</title>
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<persName>
<forename type="first">Yajie</forename>
<surname>Lei</surname>
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<forename type="first">Guo-Hua</forename>
<surname>Hu</surname>
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<idno type="halAuthorId">805871</idno>
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<author role="aut">
<persName>
<forename type="first">Rui</forename>
<surname>Zhao</surname>
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<idno type="halAuthorId">370132</idno>
<affiliation ref="#struct-212118"></affiliation>
</author>
<author role="aut">
<persName>
<forename type="first">Heng</forename>
<surname>Guo</surname>
</persName>
<idno type="halAuthorId">588874</idno>
<affiliation ref="#struct-212118"></affiliation>
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<author role="aut">
<persName>
<forename type="first">Xin</forename>
<surname>Zhao</surname>
</persName>
<idno type="halAuthorId">218325</idno>
<affiliation ref="#struct-212118"></affiliation>
</author>
<author role="aut">
<persName>
<forename type="first">Xiaobo</forename>
<surname>Liu</surname>
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<idno type="halAuthorId">807577</idno>
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<title level="j">Journal of Physics and Chemistry of Solids</title>
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<biblScope unit="volume">73</biblScope>
<biblScope unit="issue">11</biblScope>
<biblScope unit="pp">1335-1341</biblScope>
<date type="datePub">2012-11</date>
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<idno type="doi">10.1016/j.jpcs.2012.07.003</idno>
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<term xml:lang="en">Mechanical properties</term>
<term xml:lang="en">KeyWords Plus: ACID MODIFIED POLYPROPYLENE</term>
<term xml:lang="en">INTERCALATION POLYMERIZATION</term>
<term xml:lang="en">MECHANICAL-PROPERTIES</term>
<term xml:lang="en">CARBON NANOTUBES</term>
<term xml:lang="en">COMPOSITES</term>
<term xml:lang="en">MONTMORILLONITE</term>
<term xml:lang="en">MORPHOLOGY</term>
<term xml:lang="en">RESIN</term>
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<abstract xml:lang="en">Exfoliated graphite nanoplatelets (xGnP) filled 4,4'-Bis (3,4-dicyanophenoxy) biphenyl (BPh) nanocomposites were prepared by a resin transfer molding process. The theological behavior of the BPh pre-polymer, and the morphology and electrical, mechanical and thermal properties of the xGnP/BPh nanocomposites were systematically investigated. The results showed that the xGnP/BPh pre-polymer possessed a higher complex viscosity and storage modulus than the pure BPh and that the xGnP could significantly enhance the mechanical and electrical properties of the resulted nanocomposites. The electrical percolation threshold of the xGnP/BPh nanocomposites was between 5 and 10 wt% xGnP. The flexural strength and modulus of the xGnP/BPh nanocomposites with 10 wt% xGnP exhibited maximum values and their thermal stabilities were greatly improved. Those novel xGnP/BPh nanocomposites could have advanced applications in areas like aerospace and military industry.</abstract>
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