Improved Energy Efficiency of a Hybrid Pervaporation/Distillation Process for Acetic Acid Production: Identification of Target Membrane Performances by Simulation
Identifieur interne : 000597 ( Hal/Corpus ); précédent : 000596; suivant : 000598Improved Energy Efficiency of a Hybrid Pervaporation/Distillation Process for Acetic Acid Production: Identification of Target Membrane Performances by Simulation
Auteurs : Clement Servel ; Denis Roizard ; Eric Favre ; Dominique HorbezSource :
- Industrial and engineering chemistry research [ 0888-5885 ] ; 2014-05.
Abstract
The continuously rising cost of world energy is pushing the chemical process industry to find alternative processes to conventional separation processes. Previous studies on hybrid processes coupling pervaporation or vapor permeation with distillation have claimed interesting decreases in energy consumption compared to conventional processes. However, most of the time, it remains difficult to really evaluate the actual potential and the energy gain achievable for a membrane process for a particular separation. This paper reports an innovative simulation methodology that can be applied to determine the membrane performances that have to be achieved to replace conventional processes with a hybrid process while respecting constraints that are fixed by industrial specifications. This method is applied to the case of acetic acid dehydration. A hybrid process consisting of a pervaporation module equipped with a hydrophilic membrane coupled with a distillation column is proposed and studied. The minimum membrane performances for industrial use of pervaporation are determined and compared to membrane performances that have already been reported in the literature. As a result, this work shows that commercially available membranes have a selectivity that is too low to induce significant economic savings for this application, although some materials that are not yet commercialized show very interesting separation results.
Url:
DOI: 10.1021/ie500467k
Links to Exploration step
Hal:hal-01275613Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Improved Energy Efficiency of a Hybrid Pervaporation/Distillation Process for Acetic Acid Production: Identification of Target Membrane Performances by Simulation</title>
<author><name sortKey="Servel, Clement" sort="Servel, Clement" uniqKey="Servel C" first="Clement" last="Servel">Clement Servel</name>
<affiliation><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
</affiliation>
</author>
<author><name sortKey="Roizard, Denis" sort="Roizard, Denis" uniqKey="Roizard D" first="Denis" last="Roizard">Denis Roizard</name>
<affiliation><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
</affiliation>
</author>
<author><name sortKey="Favre, Eric" sort="Favre, Eric" uniqKey="Favre E" first="Eric" last="Favre">Eric Favre</name>
<affiliation><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
</affiliation>
</author>
<author><name sortKey="Horbez, Dominique" sort="Horbez, Dominique" uniqKey="Horbez D" first="Dominique" last="Horbez">Dominique Horbez</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">HAL</idno>
<idno type="RBID">Hal:hal-01275613</idno>
<idno type="halId">hal-01275613</idno>
<idno type="halUri">https://hal.univ-lorraine.fr/hal-01275613</idno>
<idno type="url">https://hal.univ-lorraine.fr/hal-01275613</idno>
<idno type="doi">10.1021/ie500467k</idno>
<date when="2014-05">2014-05</date>
<idno type="wicri:Area/Hal/Corpus">000597</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">Improved Energy Efficiency of a Hybrid Pervaporation/Distillation Process for Acetic Acid Production: Identification of Target Membrane Performances by Simulation</title>
<author><name sortKey="Servel, Clement" sort="Servel, Clement" uniqKey="Servel C" first="Clement" last="Servel">Clement Servel</name>
<affiliation><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
</affiliation>
</author>
<author><name sortKey="Roizard, Denis" sort="Roizard, Denis" uniqKey="Roizard D" first="Denis" last="Roizard">Denis Roizard</name>
<affiliation><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
</affiliation>
</author>
<author><name sortKey="Favre, Eric" sort="Favre, Eric" uniqKey="Favre E" first="Eric" last="Favre">Eric Favre</name>
<affiliation><hal:affiliation type="laboratory" xml:id="struct-211875" status="VALID"><idno type="IdRef">153068876</idno>
<idno type="RNSR">201320573K</idno>
<idno type="IdUnivLorraine">[UL]RQC--</idno>
<orgName>Laboratoire Réactions et Génie des Procédés</orgName>
<orgName type="acronym">LRGP</orgName>
<date type="start">2013-01-01</date>
<desc><address><addrLine>Université de Lorraine - ENSIC, 1 rue de Grandville BP 20451, 54001 Nancy Cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://lrgp.univ-lorraine.fr/</ref>
</desc>
<listRelation><relation active="#struct-413289" type="direct"></relation>
<relation name="UMR7274" active="#struct-441569" type="direct"></relation>
</listRelation>
<tutelles><tutelle active="#struct-413289" type="direct"><org type="institution" xml:id="struct-413289" status="VALID"><idno type="IdRef">157040569</idno>
<idno type="IdUnivLorraine">[UL]100--</idno>
<orgName>Université de Lorraine</orgName>
<orgName type="acronym">UL</orgName>
<date type="start">2012-01-01</date>
<desc><address><addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
<country key="FR"></country>
</address>
<ref type="url">http://www.univ-lorraine.fr/</ref>
</desc>
</org>
</tutelle>
<tutelle name="UMR7274" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"><idno type="ISNI">0000000122597504</idno>
<idno type="IdRef">02636817X</idno>
<orgName>Centre National de la Recherche Scientifique</orgName>
<orgName type="acronym">CNRS</orgName>
<date type="start">1939-10-19</date>
<desc><address><country key="FR"></country>
</address>
<ref type="url">http://www.cnrs.fr/</ref>
</desc>
</org>
</tutelle>
</tutelles>
</hal:affiliation>
</affiliation>
</author>
<author><name sortKey="Horbez, Dominique" sort="Horbez, Dominique" uniqKey="Horbez D" first="Dominique" last="Horbez">Dominique Horbez</name>
</author>
</analytic>
<idno type="DOI">10.1021/ie500467k</idno>
<series><title level="j">Industrial and engineering chemistry research</title>
<idno type="ISSN">0888-5885</idno>
<imprint><date type="datePub">2014-05</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The continuously rising cost of world energy is pushing the chemical process industry to find alternative processes to conventional separation processes. Previous studies on hybrid processes coupling pervaporation or vapor permeation with distillation have claimed interesting decreases in energy consumption compared to conventional processes. However, most of the time, it remains difficult to really evaluate the actual potential and the energy gain achievable for a membrane process for a particular separation. This paper reports an innovative simulation methodology that can be applied to determine the membrane performances that have to be achieved to replace conventional processes with a hybrid process while respecting constraints that are fixed by industrial specifications. This method is applied to the case of acetic acid dehydration. A hybrid process consisting of a pervaporation module equipped with a hydrophilic membrane coupled with a distillation column is proposed and studied. The minimum membrane performances for industrial use of pervaporation are determined and compared to membrane performances that have already been reported in the literature. As a result, this work shows that commercially available membranes have a selectivity that is too low to induce significant economic savings for this application, although some materials that are not yet commercialized show very interesting separation results.</div>
</front>
</TEI>
<hal api="V3"><titleStmt><title xml:lang="en">Improved Energy Efficiency of a Hybrid Pervaporation/Distillation Process for Acetic Acid Production: Identification of Target Membrane Performances by Simulation</title>
<author role="aut"><persName><forename type="first">Clement</forename>
<surname>Servel</surname>
</persName>
<email></email>
<idno type="halauthor">1296029</idno>
<affiliation ref="#struct-211875"></affiliation>
</author>
<author role="rsp"><persName><forename type="first">Denis</forename>
<surname>Roizard</surname>
</persName>
<email>denis.roizard@univ-lorraine.fr</email>
<idno type="halauthor">805887</idno>
<affiliation ref="#struct-211875"></affiliation>
</author>
<author role="aut"><persName><forename type="first">Eric</forename>
<surname>Favre</surname>
</persName>
<email></email>
<idno type="halauthor">193762</idno>
<affiliation ref="#struct-211875"></affiliation>
</author>
<author role="aut"><persName><forename type="first">Dominique</forename>
<surname>Horbez</surname>
</persName>
<email></email>
<idno type="halauthor">1296030</idno>
</author>
<editor role="depositor"><persName><forename>LRGP</forename>
<surname>UL</surname>
</persName>
<email>ddoc-appuirecherche-lrgp@univ-lorraine.fr</email>
</editor>
</titleStmt>
<editionStmt><edition n="v1" type="current"><date type="whenSubmitted">2016-02-17 17:50:35</date>
<date type="whenModified">2016-05-10 16:53:26</date>
<date type="whenReleased">2016-02-17 17:50:35</date>
<date type="whenProduced">2014-05</date>
</edition>
<respStmt><resp>contributor</resp>
<name key="329568"><persName><forename>LRGP</forename>
<surname>UL</surname>
</persName>
<email>ddoc-appuirecherche-lrgp@univ-lorraine.fr</email>
</name>
</respStmt>
</editionStmt>
<publicationStmt><distributor>CCSD</distributor>
<idno type="halId">hal-01275613</idno>
<idno type="halUri">https://hal.univ-lorraine.fr/hal-01275613</idno>
<idno type="halBibtex">servel:hal-01275613</idno>
<idno type="halRefHtml">Industrial and engineering chemistry research, American Chemical Society, 2014, 53 (18), pp.7768-7779. <10.1021/ie500467k></idno>
<idno type="halRef">Industrial and engineering chemistry research, American Chemical Society, 2014, 53 (18), pp.7768-7779. <10.1021/ie500467k></idno>
</publicationStmt>
<seriesStmt><idno type="stamp" n="UNIV-LORRAINE">Université de Lorraine</idno>
<idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
<idno type="stamp" n="LRGP-UL">LRGP</idno>
</seriesStmt>
<notesStmt><note type="audience" n="2">International</note>
<note type="popular" n="0">No</note>
<note type="peer" n="1">Yes</note>
</notesStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">Improved Energy Efficiency of a Hybrid Pervaporation/Distillation Process for Acetic Acid Production: Identification of Target Membrane Performances by Simulation</title>
<author role="aut"><persName><forename type="first">Clement</forename>
<surname>Servel</surname>
</persName>
<idno type="halAuthorId">1296029</idno>
<affiliation ref="#struct-211875"></affiliation>
</author>
<author role="rsp"><persName><forename type="first">Denis</forename>
<surname>Roizard</surname>
</persName>
<email>denis.roizard@univ-lorraine.fr</email>
<idno type="halAuthorId">805887</idno>
<affiliation ref="#struct-211875"></affiliation>
</author>
<author role="aut"><persName><forename type="first">Eric</forename>
<surname>Favre</surname>
</persName>
<idno type="halAuthorId">193762</idno>
<affiliation ref="#struct-211875"></affiliation>
</author>
<author role="aut"><persName><forename type="first">Dominique</forename>
<surname>Horbez</surname>
</persName>
<idno type="halAuthorId">1296030</idno>
</author>
</analytic>
<monogr><idno type="halJournalId" status="VALID">5453</idno>
<idno type="issn">0888-5885</idno>
<idno type="eissn">1520-5045</idno>
<title level="j">Industrial and engineering chemistry research</title>
<imprint><publisher>American Chemical Society</publisher>
<biblScope unit="volume">53</biblScope>
<biblScope unit="issue">18</biblScope>
<biblScope unit="pp">7768-7779</biblScope>
<date type="datePub">2014-05</date>
</imprint>
</monogr>
<idno type="doi">10.1021/ie500467k</idno>
</biblStruct>
</sourceDesc>
<profileDesc><langUsage><language ident="en">English</language>
</langUsage>
<textClass><classCode scheme="halDomain" n="chim">Chemical Sciences</classCode>
<classCode scheme="halTypology" n="ART">Journal articles</classCode>
</textClass>
<abstract xml:lang="en">The continuously rising cost of world energy is pushing the chemical process industry to find alternative processes to conventional separation processes. Previous studies on hybrid processes coupling pervaporation or vapor permeation with distillation have claimed interesting decreases in energy consumption compared to conventional processes. However, most of the time, it remains difficult to really evaluate the actual potential and the energy gain achievable for a membrane process for a particular separation. This paper reports an innovative simulation methodology that can be applied to determine the membrane performances that have to be achieved to replace conventional processes with a hybrid process while respecting constraints that are fixed by industrial specifications. This method is applied to the case of acetic acid dehydration. A hybrid process consisting of a pervaporation module equipped with a hydrophilic membrane coupled with a distillation column is proposed and studied. The minimum membrane performances for industrial use of pervaporation are determined and compared to membrane performances that have already been reported in the literature. As a result, this work shows that commercially available membranes have a selectivity that is too low to induce significant economic savings for this application, although some materials that are not yet commercialized show very interesting separation results.</abstract>
</profileDesc>
</hal>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Lorraine/explor/LrgpV1/Data/Hal/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000597 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Hal/Corpus/biblio.hfd -nk 000597 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/Lorraine |area= LrgpV1 |flux= Hal |étape= Corpus |type= RBID |clé= Hal:hal-01275613 |texte= Improved Energy Efficiency of a Hybrid Pervaporation/Distillation Process for Acetic Acid Production: Identification of Target Membrane Performances by Simulation }}
![]() | This area was generated with Dilib version V0.6.32. | ![]() |