Comparative study of biomass fast pyrolysis and direct liquefaction for bio-oils production: Products yield andcharacterizations
Identifieur interne : 000439 ( Hal/Checkpoint ); précédent : 000438; suivant : 000440Comparative study of biomass fast pyrolysis and direct liquefaction for bio-oils production: Products yield andcharacterizations
Auteurs : Doassans-Carrère Nicolas [France] ; Jean-Henry Ferrasse [France] ; Olivier Boutin [France] ; Guillain Mauviel [France] ; Jacques Lédé [France]Source :
- Energy and Fuels [ 0887-0624 ] ; 2014.
Abstract
The objective of this work is to compare two biomass-to-oil processes: fast pyrolysis and direct liquefaction, using the same biomass (beech sawdust). Fast pyrolysis is conducted in a cyclone reactor (wall temperature between 870 and 1040 K) and direct liquefaction in a 150-mL-autoclave reactor (bulk temperature between 420 and 600 K). Three fractions of pyro-oil areobtained from fast pyrolysis (heavy oil, light oil, and aerosol), whereas two fractions of liq-oil (heavy oil and water-soluble organics) are obtained from direct liquefaction. The comparison of both processes is based on the product yields and theircharacterization (ultimate analysis for solid and oils, oil−water content, gas and oil molecular composition, 1 H NMR for oils).For both processes, there is an optimal temperature at which the oil yield is maximum. Up to 62.6 wt % of pyro-oil are obtainedat 970 K with the cyclone reactor (with 25.7 wt % of gas and 11.7 wt % of solid), whereas 47.0 wt % of liq-oil was obtained at 573K with the batch-reactor (completed by 5.5 wt % of gas and 17.8 wt % of solid). Water content mainly explains the differences(mass yield and oxygen content) between oils from fast pyrolysis and direct liquefaction. Nevertheless, there are also somedifferences in organic composition: levoglucosane is a main component in pyro-oil, whereas levulinic acid is a main component in liq-oil. Finally, gas formed during direct liquefaction is mainly composed of CO2 (more than 99 wt %), whereas gas from fastpyrolysis is a mixture of CO, CO2, H2, CH4, and light hydrocarbons.
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DOI: 10.1021/ef500641c
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<front><div type="abstract" xml:lang="en">The objective of this work is to compare two biomass-to-oil processes: fast pyrolysis and direct liquefaction, using the same biomass (beech sawdust). Fast pyrolysis is conducted in a cyclone reactor (wall temperature between 870 and 1040 K) and direct liquefaction in a 150-mL-autoclave reactor (bulk temperature between 420 and 600 K). Three fractions of pyro-oil areobtained from fast pyrolysis (heavy oil, light oil, and aerosol), whereas two fractions of liq-oil (heavy oil and water-soluble organics) are obtained from direct liquefaction. The comparison of both processes is based on the product yields and theircharacterization (ultimate analysis for solid and oils, oil−water content, gas and oil molecular composition, 1 H NMR for oils).For both processes, there is an optimal temperature at which the oil yield is maximum. Up to 62.6 wt % of pyro-oil are obtainedat 970 K with the cyclone reactor (with 25.7 wt % of gas and 11.7 wt % of solid), whereas 47.0 wt % of liq-oil was obtained at 573K with the batch-reactor (completed by 5.5 wt % of gas and 17.8 wt % of solid). Water content mainly explains the differences(mass yield and oxygen content) between oils from fast pyrolysis and direct liquefaction. Nevertheless, there are also somedifferences in organic composition: levoglucosane is a main component in pyro-oil, whereas levulinic acid is a main component in liq-oil. Finally, gas formed during direct liquefaction is mainly composed of CO2 (more than 99 wt %), whereas gas from fastpyrolysis is a mixture of CO, CO2, H2, CH4, and light hydrocarbons.</div>
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<abstract xml:lang="en">The objective of this work is to compare two biomass-to-oil processes: fast pyrolysis and direct liquefaction, using the same biomass (beech sawdust). Fast pyrolysis is conducted in a cyclone reactor (wall temperature between 870 and 1040 K) and direct liquefaction in a 150-mL-autoclave reactor (bulk temperature between 420 and 600 K). Three fractions of pyro-oil areobtained from fast pyrolysis (heavy oil, light oil, and aerosol), whereas two fractions of liq-oil (heavy oil and water-soluble organics) are obtained from direct liquefaction. The comparison of both processes is based on the product yields and theircharacterization (ultimate analysis for solid and oils, oil−water content, gas and oil molecular composition, 1 H NMR for oils).For both processes, there is an optimal temperature at which the oil yield is maximum. Up to 62.6 wt % of pyro-oil are obtainedat 970 K with the cyclone reactor (with 25.7 wt % of gas and 11.7 wt % of solid), whereas 47.0 wt % of liq-oil was obtained at 573K with the batch-reactor (completed by 5.5 wt % of gas and 17.8 wt % of solid). Water content mainly explains the differences(mass yield and oxygen content) between oils from fast pyrolysis and direct liquefaction. Nevertheless, there are also somedifferences in organic composition: levoglucosane is a main component in pyro-oil, whereas levulinic acid is a main component in liq-oil. Finally, gas formed during direct liquefaction is mainly composed of CO2 (more than 99 wt %), whereas gas from fastpyrolysis is a mixture of CO, CO2, H2, CH4, and light hydrocarbons.</abstract>
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