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Syntheses, structure and properties of three-dimensional pillared-layer Ag(I)-Ln(III) heterometallic coordination polymers based on mixed isonicotinate and hemimellitate ligands

Identifieur interne : 000395 ( Chine/Analysis ); précédent : 000394; suivant : 000396

Syntheses, structure and properties of three-dimensional pillared-layer Ag(I)-Ln(III) heterometallic coordination polymers based on mixed isonicotinate and hemimellitate ligands

Auteurs : RBID : Pascal:12-0448070

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English descriptors

Abstract

Three pillared-layer 4d-4f Ag(I)-Ln(III) heterometallic coordination polymers (HCPs), formulated as [Ln2Ag(hma)2(ina)(H2O)2]n nH20 [Ln=La(1), Pr(2), Nd(3); Hina=isonicotinic acid, H3hma=hemimellitic acid], have been synthesized under hydrothermal conditions. Single-crystal and powder X-ray diffractions confirm that they are isostructural, which features a three-dimensional (3D) pillared-layer heterometallic structure built upon the strictly alternate arrangement of lanthanide-organic layers and [Ag(ina)] pillars. The layers and pillars are connected to each other by Ln-0 and Ag-O coordination bonds. The photoluminescent property of the Nd derivative (3) has also been investigated.

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Pascal:12-0448070

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<title xml:lang="en" level="a">Syntheses, structure and properties of three-dimensional pillared-layer Ag(I)-Ln(III) heterometallic coordination polymers based on mixed isonicotinate and hemimellitate ligands</title>
<author>
<name>XINFA LI</name>
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<s1>Department of Chemistry, Zunyi Normal College</s1>
<s2>Zunyi 563002</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
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<country>République populaire de Chine</country>
<wicri:noRegion>Zunyi 563002</wicri:noRegion>
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<author>
<name>RONG CAO</name>
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<s1>State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences</s1>
<s2>Fuzhou 350002</s2>
<s3>CHN</s3>
<sZ>2 aut.</sZ>
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<country>République populaire de Chine</country>
<wicri:noRegion>Fuzhou 350002</wicri:noRegion>
</affiliation>
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<term>III-V compound</term>
<term>III-V semiconductors</term>
<term>Indium arsenides</term>
<term>Isonicotinic acid derivatives</term>
<term>Lamellar structure</term>
<term>Ligands</term>
<term>Molecular structure</term>
<term>Monocrystals</term>
<term>Photoluminescence</term>
<term>Pillared structure</term>
<term>Polychelate</term>
<term>Rare earths</term>
<term>Silver</term>
<term>XRD</term>
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<term>Structure à pilier</term>
<term>Polymère coordination</term>
<term>Structure cristalline</term>
<term>Structure moléculaire</term>
<term>Ligand</term>
<term>Arséniure d'indium</term>
<term>Semiconducteur III-V</term>
<term>Composé III-V</term>
<term>Dérivé de l'acide isonicotinique</term>
<term>Croissance cristalline en solution</term>
<term>Diffraction RX</term>
<term>Structure lamellaire</term>
<term>Lanthanide</term>
<term>Liaison coordination</term>
<term>Argent</term>
<term>Monocristal</term>
<term>Photoluminescence</term>
<term>Substrat polymère</term>
<term>InAs</term>
<term>6166H</term>
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<div type="abstract" xml:lang="en">Three pillared-layer 4d-4f Ag(I)-Ln(III) heterometallic coordination polymers (HCPs), formulated as [Ln
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Ag(hma)
<sub>2</sub>
(ina)(H
<sub>2</sub>
O)
<sub>2</sub>
]
<sub>n</sub>
nH
<sub>2</sub>
0 [Ln=La(1), Pr(2), Nd(3); Hina=isonicotinic acid, H
<sub>3</sub>
hma=hemimellitic acid], have been synthesized under hydrothermal conditions. Single-crystal and powder X-ray diffractions confirm that they are isostructural, which features a three-dimensional (3D) pillared-layer heterometallic structure built upon the strictly alternate arrangement of lanthanide-organic layers and [Ag(ina)] pillars. The layers and pillars are connected to each other by Ln-0 and Ag-O coordination bonds. The photoluminescent property of the Nd derivative (3) has also been investigated.</div>
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<s1>Syntheses, structure and properties of three-dimensional pillared-layer Ag(I)-Ln(III) heterometallic coordination polymers based on mixed isonicotinate and hemimellitate ligands</s1>
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<s1>Department of Chemistry, Zunyi Normal College</s1>
<s2>Zunyi 563002</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
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<s1>State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences</s1>
<s2>Fuzhou 350002</s2>
<s3>CHN</s3>
<sZ>2 aut.</sZ>
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<s0>Three pillared-layer 4d-4f Ag(I)-Ln(III) heterometallic coordination polymers (HCPs), formulated as [Ln
<sub>2</sub>
Ag(hma)
<sub>2</sub>
(ina)(H
<sub>2</sub>
O)
<sub>2</sub>
]
<sub>n</sub>
nH
<sub>2</sub>
0 [Ln=La(1), Pr(2), Nd(3); Hina=isonicotinic acid, H
<sub>3</sub>
hma=hemimellitic acid], have been synthesized under hydrothermal conditions. Single-crystal and powder X-ray diffractions confirm that they are isostructural, which features a three-dimensional (3D) pillared-layer heterometallic structure built upon the strictly alternate arrangement of lanthanide-organic layers and [Ag(ina)] pillars. The layers and pillars are connected to each other by Ln-0 and Ag-O coordination bonds. The photoluminescent property of the Nd derivative (3) has also been investigated.</s0>
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<s0>Structure à pilier</s0>
<s5>01</s5>
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<s5>02</s5>
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<s5>02</s5>
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<s5>02</s5>
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<s0>Structure cristalline</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG">
<s0>Crystal structure</s0>
<s5>03</s5>
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<s5>04</s5>
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<s5>04</s5>
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<s5>05</s5>
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<s0>Indium arsenides</s0>
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<s5>06</s5>
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<s5>07</s5>
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<s5>07</s5>
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<s0>Composé III-V</s0>
<s5>08</s5>
</fC03>
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<s5>08</s5>
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<s0>Compuesto III-V</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Dérivé de l'acide isonicotinique</s0>
<s2>FR</s2>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Isonicotinic acid derivatives</s0>
<s2>FR</s2>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Croissance cristalline en solution</s0>
<s5>10</s5>
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<s0>Crystal growth from solutions</s0>
<s5>10</s5>
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<s5>11</s5>
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<s5>11</s5>
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<s0>Structure lamellaire</s0>
<s5>12</s5>
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<fC03 i1="12" i2="X" l="ENG">
<s0>Lamellar structure</s0>
<s5>12</s5>
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<s0>Estructura lamelar</s0>
<s5>12</s5>
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<s2>NC</s2>
<s5>13</s5>
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<fC03 i1="13" i2="3" l="ENG">
<s0>Rare earths</s0>
<s2>NC</s2>
<s5>13</s5>
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<fC03 i1="14" i2="X" l="FRE">
<s0>Liaison coordination</s0>
<s5>14</s5>
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<s0>Coordination bond</s0>
<s5>14</s5>
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<s0>Enlace coordinación</s0>
<s5>14</s5>
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<s0>Argent</s0>
<s2>NC</s2>
<s5>15</s5>
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<s2>NC</s2>
<s5>15</s5>
</fC03>
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<s0>Monocristal</s0>
<s5>16</s5>
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<s5>16</s5>
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<fC03 i1="17" i2="3" l="FRE">
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<s5>29</s5>
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<s0>Photoluminescence</s0>
<s5>29</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>Substrat polymère</s0>
<s4>INC</s4>
<s5>46</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE">
<s0>InAs</s0>
<s4>INC</s4>
<s5>47</s5>
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<fC03 i1="20" i2="3" l="FRE">
<s0>6166H</s0>
<s4>INC</s4>
<s5>65</s5>
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<s5>66</s5>
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<s0>8105L</s0>
<s4>INC</s4>
<s5>67</s5>
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<s0>8110D</s0>
<s4>INC</s4>
<s5>72</s5>
</fC03>
<fN21>
<s1>345</s1>
</fN21>
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