Pore space partition and charge separation in cage-within-cage indium-organic frameworks with high CO2 uptake.
Identifieur interne : 001812 ( Main/Exploration ); précédent : 001811; suivant : 001813Pore space partition and charge separation in cage-within-cage indium-organic frameworks with high CO2 uptake.
Auteurs : RBID : pubmed:21080641Abstract
The integration of negatively charged single-metal building blocks {In(CO2)4} and positively charged trimeric clusters {In3O} leads to three unique cage-within-cage-based porous materials, which exhibit not only high hydrothermal, thermal, and photochemical stability but also attractive structural features contributing to a very high CO2 uptake capacity of up to 119.8 L/L at 273 K and 1 atm.
DOI: 10.1021/ja106903p
PubMed: 21080641
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Le document en format XML
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<author><name sortKey="Zheng, Shou Tian" uniqKey="Zheng S">Shou-Tian Zheng</name>
<affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry and Biochemistry, California State University, Long Beach, California 90840, USA.</nlm:affiliation>
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<author><name sortKey="Bu, Julia T" uniqKey="Bu J">Julia T Bu</name>
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<author><name sortKey="Li, Yufei" uniqKey="Li Y">Yufei Li</name>
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<author><name sortKey="Wu, Tao" uniqKey="Wu T">Tao Wu</name>
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<author><name sortKey="Zuo, Fan" uniqKey="Zuo F">Fan Zuo</name>
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<author><name sortKey="Feng, Pingyun" uniqKey="Feng P">Pingyun Feng</name>
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<author><name sortKey="Bu, Xianhui" uniqKey="Bu X">Xianhui Bu</name>
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<front><div type="abstract" xml:lang="en">The integration of negatively charged single-metal building blocks {In(CO2)4} and positively charged trimeric clusters {In3O} leads to three unique cage-within-cage-based porous materials, which exhibit not only high hydrothermal, thermal, and photochemical stability but also attractive structural features contributing to a very high CO2 uptake capacity of up to 119.8 L/L at 273 K and 1 atm.</div>
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<Abstract><AbstractText>The integration of negatively charged single-metal building blocks {In(CO2)4} and positively charged trimeric clusters {In3O} leads to three unique cage-within-cage-based porous materials, which exhibit not only high hydrothermal, thermal, and photochemical stability but also attractive structural features contributing to a very high CO2 uptake capacity of up to 119.8 L/L at 273 K and 1 atm.</AbstractText>
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