Orienting periodic organic-inorganic nanoscale domains through one-step electrodeposition.
Identifieur interne : 001232 ( Main/Exploration ); précédent : 001231; suivant : 001233Orienting periodic organic-inorganic nanoscale domains through one-step electrodeposition.
Auteurs : RBID : pubmed:21142087English descriptors
- KwdEn :
- Bicyclo Compounds, Heterocyclic (chemistry), Electroplating (methods), Inorganic Chemicals (chemistry), Nanostructures (chemistry), Organic Chemicals (chemistry), Polymers (chemistry), Polystyrenes (chemistry), Pyrenes (chemistry), Scattering, Small Angle, Semiconductors, Tin Compounds (chemistry), X-Ray Diffraction, Zinc Oxide (chemistry).
- MESH :
- chemical , chemistry : Bicyclo Compounds, Heterocyclic, Inorganic Chemicals, Organic Chemicals, Polymers, Polystyrenes, Pyrenes, Tin Compounds, Zinc Oxide.
- chemistry : Nanostructures.
- methods : Electroplating.
- Scattering, Small Angle, Semiconductors, X-Ray Diffraction.
Abstract
One of the challenges in the synthesis of hybrid materials with nanoscale structure is to precisely control morphology across length scales. Using a one-step electrodeposition process on indium tin oxide (ITO) substrates followed by annealing, we report here the preparation of materials with preferentially oriented lamellar domains of electron donor surfactants and the semiconductor ZnO. We found that either increasing the concentration of surfactant or the water to dimethyl sulfoxide ratio of solutions used resulted in the suppression of bloomlike morphologies and enhanced the density of periodic domains on ITO substrates. Furthermore, by modifying the surface of the ITO substrate with the conductive polymer blend poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate), we were able to alter the orientation of these electrodeposited lamellar domains to be perpendicular to the substrate. The long-range orientation achieved was characterized by 2D grazing incidence small-angle X-ray scattering. This high degree of orientation in electronically active hybrids with alternating nanoscale p-type and n-type domains is of potential interest in photovoltaics or thermoelectric materials.
DOI: 10.1021/nn102697r
PubMed: 21142087
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Orienting periodic organic-inorganic nanoscale domains through one-step electrodeposition.</title><author><name sortKey="Herman, David J" uniqKey="Herman D">David J Herman</name><affiliation wicri:level="1"><nlm:affiliation>Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208</wicri:regionArea></affiliation></author><author><name sortKey="Goldberger, Joshua E" uniqKey="Goldberger J">Joshua E Goldberger</name></author><author><name sortKey="Chao, Stephen" uniqKey="Chao S">Stephen Chao</name></author><author><name sortKey="Martin, Daniel T" uniqKey="Martin D">Daniel T Martin</name></author><author><name sortKey="Stupp, Samuel I" uniqKey="Stupp S">Samuel I Stupp</name></author></titleStmt><publicationStmt><date when="2011">2011</date><idno type="doi">10.1021/nn102697r</idno><idno type="RBID">pubmed:21142087</idno><idno type="pmid">21142087</idno><idno type="wicri:Area/Main/Corpus">001662</idno><idno type="wicri:Area/Main/Curation">001662</idno><idno type="wicri:Area/Main/Exploration">001232</idno></publicationStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bicyclo Compounds, Heterocyclic (chemistry)</term><term>Electroplating (methods)</term><term>Inorganic Chemicals (chemistry)</term><term>Nanostructures (chemistry)</term><term>Organic Chemicals (chemistry)</term><term>Polymers (chemistry)</term><term>Polystyrenes (chemistry)</term><term>Pyrenes (chemistry)</term><term>Scattering, Small Angle</term><term>Semiconductors</term><term>Tin Compounds (chemistry)</term><term>X-Ray Diffraction</term><term>Zinc Oxide (chemistry)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Bicyclo Compounds, Heterocyclic</term><term>Inorganic Chemicals</term><term>Organic Chemicals</term><term>Polymers</term><term>Polystyrenes</term><term>Pyrenes</term><term>Tin Compounds</term><term>Zinc Oxide</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Nanostructures</term></keywords><keywords scheme="MESH" qualifier="methods" xml:lang="en"><term>Electroplating</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Scattering, Small Angle</term><term>Semiconductors</term><term>X-Ray Diffraction</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">One of the challenges in the synthesis of hybrid materials with nanoscale structure is to precisely control morphology across length scales. Using a one-step electrodeposition process on indium tin oxide (ITO) substrates followed by annealing, we report here the preparation of materials with preferentially oriented lamellar domains of electron donor surfactants and the semiconductor ZnO. We found that either increasing the concentration of surfactant or the water to dimethyl sulfoxide ratio of solutions used resulted in the suppression of bloomlike morphologies and enhanced the density of periodic domains on ITO substrates. Furthermore, by modifying the surface of the ITO substrate with the conductive polymer blend poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate), we were able to alter the orientation of these electrodeposited lamellar domains to be perpendicular to the substrate. The long-range orientation achieved was characterized by 2D grazing incidence small-angle X-ray scattering. This high degree of orientation in electronically active hybrids with alternating nanoscale p-type and n-type domains is of potential interest in photovoltaics or thermoelectric materials.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="MEDLINE"><PMID Version="1">21142087</PMID><DateCreated><Year>2011</Year><Month>01</Month><Day>25</Day></DateCreated><DateCompleted><Year>2011</Year><Month>04</Month><Day>26</Day></DateCompleted><DateRevised><Year>2013</Year><Month>11</Month><Day>21</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1936-086X</ISSN><JournalIssue CitedMedium="Internet"><Volume>5</Volume><Issue>1</Issue><PubDate><Year>2011</Year><Month>Jan</Month><Day>25</Day></PubDate></JournalIssue><Title>ACS nano</Title><ISOAbbreviation>ACS Nano</ISOAbbreviation></Journal><ArticleTitle>Orienting periodic organic-inorganic nanoscale domains through one-step electrodeposition.</ArticleTitle><Pagination><MedlinePgn>565-73</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1021/nn102697r</ELocationID><Abstract><AbstractText>One of the challenges in the synthesis of hybrid materials with nanoscale structure is to precisely control morphology across length scales. Using a one-step electrodeposition process on indium tin oxide (ITO) substrates followed by annealing, we report here the preparation of materials with preferentially oriented lamellar domains of electron donor surfactants and the semiconductor ZnO. We found that either increasing the concentration of surfactant or the water to dimethyl sulfoxide ratio of solutions used resulted in the suppression of bloomlike morphologies and enhanced the density of periodic domains on ITO substrates. Furthermore, by modifying the surface of the ITO substrate with the conductive polymer blend poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate), we were able to alter the orientation of these electrodeposited lamellar domains to be perpendicular to the substrate. The long-range orientation achieved was characterized by 2D grazing incidence small-angle X-ray scattering. This high degree of orientation in electronically active hybrids with alternating nanoscale p-type and n-type domains is of potential interest in photovoltaics or thermoelectric materials.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Herman</LastName><ForeName>David J</ForeName><Initials>DJ</Initials><Affiliation>Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States.</Affiliation></Author><Author ValidYN="Y"><LastName>Goldberger</LastName><ForeName>Joshua E</ForeName><Initials>JE</Initials></Author><Author ValidYN="Y"><LastName>Chao</LastName><ForeName>Stephen</ForeName><Initials>S</Initials></Author><Author ValidYN="Y"><LastName>Martin</LastName><ForeName>Daniel T</ForeName><Initials>DT</Initials></Author><Author ValidYN="Y"><LastName>Stupp</LastName><ForeName>Samuel I</ForeName><Initials>SI</Initials></Author></AuthorList><Language>eng</Language><GrantList CompleteYN="Y"><Grant><GrantID>F32 EB007131-03</GrantID><Acronym>EB</Acronym><Agency>NIBIB NIH HHS</Agency><Country>United States</Country></Grant><Grant><GrantID>F32EB007131</GrantID><Acronym>EB</Acronym><Agency>NIBIB NIH HHS</Agency><Country>United States</Country></Grant></GrantList><PublicationTypeList><PublicationType>Journal Article</PublicationType><PublicationType>Research Support, N.I.H., Extramural</PublicationType><PublicationType>Research Support, Non-U.S. Gov't</PublicationType><PublicationType>Research Support, U.S. Gov't, Non-P.H.S.</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2010</Year><Month>12</Month><Day>13</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>ACS Nano</MedlineTA><NlmUniqueID>101313589</NlmUniqueID><ISSNLinking>1936-0851</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Bicyclo Compounds, Heterocyclic</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Inorganic Chemicals</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Organic Chemicals</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Polymers</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Polystyrenes</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Pyrenes</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Tin Compounds</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>poly(3,4-ethylene dioxythiophene)</NameOfSubstance></Chemical><Chemical><RegistryNumber>28210-41-5</RegistryNumber><NameOfSubstance>polystyrene sulfonic acid</NameOfSubstance></Chemical><Chemical><RegistryNumber>3443-45-6</RegistryNumber><NameOfSubstance>1-pyrenebutyrate</NameOfSubstance></Chemical><Chemical><RegistryNumber>71243-84-0</RegistryNumber><NameOfSubstance>indium tin oxide</NameOfSubstance></Chemical><Chemical><RegistryNumber>SOI2LOH54Z</RegistryNumber><NameOfSubstance>Zinc Oxide</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><CommentsCorrectionsList><CommentsCorrections RefType="Cites"><RefSource>Nano Lett. 2007 Apr;7(4):1003-9</RefSource><PMID Version="1">17358092</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Chem Commun (Camb). 2007 Sep 21;(35):3655-7</RefSource><PMID Version="1">17728884</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Nano Lett. 2007 May;7(5):1165-71</RefSource><PMID Version="1">17447823</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Nat Mater. 2005 Jun;4(6):455-9</RefSource><PMID Version="1">15895100</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Chem Commun (Camb). 2007 Jan 14;(2):159-61</RefSource><PMID Version="1">17180232</PMID></CommentsCorrections></CommentsCorrectionsList><MeshHeadingList><MeshHeading><DescriptorName MajorTopicYN="N">Bicyclo Compounds, Heterocyclic</DescriptorName><QualifierName MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Electroplating</DescriptorName><QualifierName MajorTopicYN="Y">methods</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Inorganic Chemicals</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Nanostructures</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Organic Chemicals</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Polymers</DescriptorName><QualifierName MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Polystyrenes</DescriptorName><QualifierName MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Pyrenes</DescriptorName><QualifierName MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Scattering, Small Angle</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Semiconductors</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Tin Compounds</DescriptorName><QualifierName MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">X-Ray Diffraction</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Zinc Oxide</DescriptorName><QualifierName MajorTopicYN="N">chemistry</QualifierName></MeshHeading></MeshHeadingList><OtherID Source="NLM">NIHMS258263</OtherID><OtherID Source="NLM">PMC3127581</OtherID></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="aheadofprint"><Year>2010</Year><Month>12</Month><Day>13</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2010</Year><Month>12</Month><Day>15</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2010</Year><Month>12</Month><Day>15</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2011</Year><Month>4</Month><Day>27</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1021/nn102697r</ArticleId><ArticleId IdType="pubmed">21142087</ArticleId><ArticleId IdType="pmc">PMC3127581</ArticleId><ArticleId 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