CuInS₂ nanocrystals/PEDOT:PSS composite counter electrode for dye-sensitized solar cells.
Identifieur interne : 000F22 ( Main/Exploration ); précédent : 000F21; suivant : 000F23CuInS₂ nanocrystals/PEDOT:PSS composite counter electrode for dye-sensitized solar cells.
Auteurs : RBID : pubmed:23075280English descriptors
- KwdEn :
- Coloring Agents (chemistry), Copper (chemistry), Crystallization (methods), Electric Power Supplies, Electrodes, Equipment Design, Equipment Failure Analysis, Indium (chemistry), Metal Nanoparticles (chemistry), Metal Nanoparticles (ultrastructure), Particle Size, Polystyrenes (chemistry), Selenium (chemistry), Solar Energy, Thiophenes (chemistry).
- MESH :
- chemical , chemistry : Coloring Agents, Copper, Indium, Polystyrenes, Selenium, Thiophenes.
- chemistry : Metal Nanoparticles.
- methods : Crystallization.
- ultrastructure : Metal Nanoparticles.
- Electric Power Supplies, Electrodes, Equipment Design, Equipment Failure Analysis, Particle Size, Solar Energy.
Abstract
An inorganic/organic nanocomposite comprised of CuInS(2) nanocrystals and poly(styrenesulfonate)-doped poly(3,4-ethylenedioxythiophene) (CIS/PEDOT:PSS) was explored as a promising candidate for the counter electrode (CE) in dye-sensitized solar cells (DSCs). Cyclic voltammetry measurements confirmed that this composite electrode exhibited better catalytic activity compared with pristine CuInS₂ or PEDOT:PSS electrode. Electrochemical impedance spectroscopy revealed that the composite film constitutes a three-dimensional catalytic network. The DSC using this composite CE can yield 6.50% photoelectric conversion efficiency, which is comparable to that of the conventional platinum CE (6.51%) and better than that of the pristine CuInS₂ (5.45%) or PEDOT:PSS (3.22%) electrode.
DOI: 10.1021/am3018338
PubMed: 23075280
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Cyclic voltammetry measurements confirmed that this composite electrode exhibited better catalytic activity compared with pristine CuInS₂ or PEDOT:PSS electrode. Electrochemical impedance spectroscopy revealed that the composite film constitutes a three-dimensional catalytic network. The DSC using this composite CE can yield 6.50% photoelectric conversion efficiency, which is comparable to that of the conventional platinum CE (6.51%) and better than that of the pristine CuInS₂ (5.45%) or PEDOT:PSS (3.22%) electrode.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="MEDLINE"><PMID Version="1">23075280</PMID><DateCreated><Year>2012</Year><Month>11</Month><Day>28</Day></DateCreated><DateCompleted><Year>2013</Year><Month>05</Month><Day>30</Day></DateCompleted><DateRevised><Year>2013</Year><Month>11</Month><Day>21</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1944-8252</ISSN><JournalIssue CitedMedium="Internet"><Volume>4</Volume><Issue>11</Issue><PubDate><Year>2012</Year><Month>Nov</Month></PubDate></JournalIssue><Title>ACS applied materials & interfaces</Title><ISOAbbreviation>ACS Appl Mater Interfaces</ISOAbbreviation></Journal><ArticleTitle>CuInS₂ nanocrystals/PEDOT:PSS composite counter electrode for dye-sensitized solar cells.</ArticleTitle><Pagination><MedlinePgn>6242-6</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1021/am3018338</ELocationID><Abstract><AbstractText>An inorganic/organic nanocomposite comprised of CuInS(2) nanocrystals and poly(styrenesulfonate)-doped poly(3,4-ethylenedioxythiophene) (CIS/PEDOT:PSS) was explored as a promising candidate for the counter electrode (CE) in dye-sensitized solar cells (DSCs). Cyclic voltammetry measurements confirmed that this composite electrode exhibited better catalytic activity compared with pristine CuInS₂ or PEDOT:PSS electrode. Electrochemical impedance spectroscopy revealed that the composite film constitutes a three-dimensional catalytic network. The DSC using this composite CE can yield 6.50% photoelectric conversion efficiency, which is comparable to that of the conventional platinum CE (6.51%) and better than that of the pristine CuInS₂ (5.45%) or PEDOT:PSS (3.22%) electrode.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Zhang</LastName><ForeName>Zhongyi</ForeName><Initials>Z</Initials><Affiliation>Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, People's Republic of China.</Affiliation></Author><Author ValidYN="Y"><LastName>Zhang</LastName><ForeName>Xiaoying</ForeName><Initials>X</Initials></Author><Author ValidYN="Y"><LastName>Xu</LastName><ForeName>Hongxia</ForeName><Initials>H</Initials></Author><Author ValidYN="Y"><LastName>Liu</LastName><ForeName>Zhihong</ForeName><Initials>Z</Initials></Author><Author ValidYN="Y"><LastName>Pang</LastName><ForeName>Shuping</ForeName><Initials>S</Initials></Author><Author ValidYN="Y"><LastName>Zhou</LastName><ForeName>Xinhong</ForeName><Initials>X</Initials></Author><Author ValidYN="Y"><LastName>Dong</LastName><ForeName>Shanmu</ForeName><Initials>S</Initials></Author><Author ValidYN="Y"><LastName>Chen</LastName><ForeName>Xiao</ForeName><Initials>X</Initials></Author><Author ValidYN="Y"><LastName>Cui</LastName><ForeName>Guanglei</ForeName><Initials>G</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType><PublicationType>Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2012</Year><Month>10</Month><Day>26</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>ACS Appl Mater Interfaces</MedlineTA><NlmUniqueID>101504991</NlmUniqueID><ISSNLinking>1944-8244</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Coloring Agents</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Polystyrenes</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Thiophenes</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>copper indium diselenide</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)</NameOfSubstance></Chemical><Chemical><RegistryNumber>045A6V3VFX</RegistryNumber><NameOfSubstance>Indium</NameOfSubstance></Chemical><Chemical><RegistryNumber>789U1901C5</RegistryNumber><NameOfSubstance>Copper</NameOfSubstance></Chemical><Chemical><RegistryNumber>H6241UJ22B</RegistryNumber><NameOfSubstance>Selenium</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName MajorTopicYN="N">Coloring Agents</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Copper</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Crystallization</DescriptorName><QualifierName MajorTopicYN="N">methods</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="Y">Electric Power Supplies</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="Y">Electrodes</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Equipment Design</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Equipment Failure Analysis</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Indium</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Metal Nanoparticles</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName><QualifierName MajorTopicYN="N">ultrastructure</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Particle Size</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Polystyrenes</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Selenium</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="Y">Solar Energy</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Thiophenes</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName></MeshHeading></MeshHeadingList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="aheadofprint"><Year>2012</Year><Month>10</Month><Day>26</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2012</Year><Month>10</Month><Day>19</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2012</Year><Month>10</Month><Day>19</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2013</Year><Month>6</Month><Day>1</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1021/am3018338</ArticleId><ArticleId IdType="pubmed">23075280</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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